公开(公告)号：US4789721A

公开(公告)日：1988-12-06

申请号：US78310

申请日：1987-07-27

Applicant: Harold G. Waddill ,  Jiang-Jen Lin ,  George P. Speranza

Inventor： Harold G. Waddill ,  Jiang-Jen Lin ,  George P. Speranza

IPC: C08G59/54 ,  C08G59/44

CPC classification number: C08G59/54

Abstract: Carboxylic acid-polyetherpolyamine reaction products which contain as the principle reaction component, an amidoamine having the formula: ##STR1## where R=polyether segment as previously defined.Z=dicarboxylic acid of structure given in Examples 2 and obtained by reacting a polyoxypropylene and/or polyoxyethylene diamine with an aromatic dicarboxylic acid in molar proportions such that at least about 1.0 to 1.2 mole equivalents of amine are provided in the reaction mixture of each mole equivalent of carboxylic acid present in the reaction mixture. The amidoamines exhibit improved properties which allow for a rapid curing system even under ambient conditions and useful applications include coatings, adhesives, encapsulations, laminates and composite fabrications.

Abstract translation: 含有作为主要反应组分的羧酸 - 聚醚多胺反应产物，具有下式的酰氨基胺：其中R =如前所定义的聚醚链段。 Z =实施例2中给出的结构的二羧酸，其通过使聚氧丙烯和/或聚氧乙烯二胺与芳族二羧酸反应得到的摩尔比例使得在每摩尔的反应混合物中提供至少约1.0至1.2摩尔当量的胺 相当于反应混合物中存在的羧酸。 酰氨基胺表现出改进的性能，即使在环境条件下也能快速固化，并且有用的应用包括涂料，粘合剂，包封物，层压材料和复合制品。

公开(公告)号：US4720573A

公开(公告)日：1988-01-19

申请号：US891094

申请日：1986-07-31

Applicant: Jiang-Jen Lin

Inventor： Jiang-Jen Lin

IPC: C07C237/00 ,  C07C103/66

CPC classification number: C07C237/00

Abstract: A process for the synthesis of glutamic acid intermediate from an acrylate, amide and syngas by reacting them in the presence of a catalyst comprising a cobalt-containing compound, a bis-phosphine ligand and a solvent at a pressure of at least 500 psi and a temperature of at least 50.degree. C. and thereafter extracting the glutamic acid.

Abstract translation: 通过使它们在包含含钴化合物，双膦配体和溶剂的催化剂存在下，在至少500psi的压力下反应从丙烯酸酯，酰胺和合成气中合成谷氨酸中间体的方法， 温度至少为50℃，然后提取谷氨酸。

公开(公告)号：US4620949A

公开(公告)日：1986-11-04

申请号：US720229

申请日：1985-04-05

Applicant: Jiang-Jen Lin

Inventor： Jiang-Jen Lin

IPC: C07D207/26 ,  C07D207/263 ,  C07D207/27 ,  C07D223/10 ,  C08G69/02 ,  C07D401/06 ,  C07D403/06

CPC classification number: C07D207/263 ,  C07D207/27 ,  C07D223/10 ,  C08G69/02

Abstract: Amino acid derivatives are synthesized by reacting paraformaldehyde, cyclic amides and synthesis gas with a bimetallic catalyst comprising a rhodium-containing compound and a cobalt-containing compound, optionally in the presence of a solvent at a pressure of at least 500 psi and a temperature of at least 50.degree. C. The novel amino acid products may be hydrolyzed to amino dicarboxylic acids or used as monomers to polyamides.

Abstract translation: 氨基酸衍生物通过使多聚甲醛，环状酰胺和合成气与包含含铑化合物和含钴化合物的双金属催化剂反应，任选在溶剂存在下，在至少500psi的压力和 至少50℃。新的氨基酸产物可以水解成氨基二羧酸或用作聚酰胺的单体。

公开(公告)号：US4533742A

公开(公告)日：1985-08-06

申请号：US576509

申请日：1984-02-02

Applicant: Jiang-Jen Lin ,  John F. Knifton

Inventor： Jiang-Jen Lin ,  John F. Knifton

IPC: B01J31/00 ,  B01J31/20 ,  B01J31/24 ,  C07B61/00 ,  C07D307/20

CPC classification number: C07D307/20

Abstract: A process is disclosed for preparing products such as 2-hydroxytetrahydrofuran which comprises contacting unsaturated compounds such as allyl alcohol with carbon monoxide and hydrogen in the presence of a rhodium carbonyl catalyst and a ketone solvent system. Allyl alcohol conversions of 100% and selectivities to 2-hydroxytetrahydrofuran of 96% are achievable under certain conditions. Preferred ketone solvents are acetophenone and 2-undecanone. 2-Hydroxytetrahydrofuran is an important precursor to manufacture of 1,4-butanediol.

Abstract translation: 公开了一种制备诸如2-羟基四氢呋喃的产物的方法，该方法包括在羰基铑催化剂和酮溶剂体系的存在下使不饱和化合物如烯丙醇与一氧化碳和氢气接触。 100％的烯丙醇转化率和96％的2-羟基四氢呋喃的选择性在某些条件下是可以实现的。 优选的酮溶剂是苯乙酮和2-十一烷酮。 2-羟基四氢呋喃是制备1,4-丁二醇的重要前体。

公开(公告)号：US4451679A

公开(公告)日：1984-05-29

申请号：US435812

申请日：1982-10-21

Applicant: John F. Knifton ,  Jiang-Jen Lin ,  Robert A. Grigsby, Jr. ,  Walter H. Brader, Jr.

Inventor： John F. Knifton ,  Jiang-Jen Lin ,  Robert A. Grigsby, Jr. ,  Walter H. Brader, Jr.

IPC: C07C27/20 ,  B01J31/00 ,  B01J31/28 ,  C07B61/00 ,  C07C27/00 ,  C07C27/22 ,  C07C29/157 ,  C07C29/16 ,  C07C31/125 ,  C07C45/00 ,  C07C45/50 ,  C07C67/00

CPC classification number: B01J31/0268 ,  B01J31/0239 ,  B01J31/0284 ,  B01J31/0288 ,  B01J31/04 ,  B01J31/20 ,  B01J31/2208 ,  B01J31/28 ,  B01J31/30 ,  C07C29/16 ,  C07C31/125 ,  C07C45/50 ,  B01J2231/321 ,  B01J2531/0211 ,  B01J2531/821 ,  B01J31/2234

Abstract: This invention concerns a process of preparing alcohols and aldehydes which comprises the steps of contacting a mixture of terminal and/or internal olefins and synthesis gas with a catalyst system comprising a ruthenium-containing compound dispersed in a low melting quaternary phosphonium or ammonium base or salt and heating said resultant reaction mixture under a pressure of 100 psi or greater at a temperature of at least 50.degree. C. for a sufficient time to produce said alcohols and aldehydes.

Abstract translation: 本发明涉及一种制备醇和醛的方法，其包括以下步骤：使末端和/或内部烯烃和合成气的混合物与包含分散在低熔点季铵或铵碱或盐中的含钌化合物的催化剂体系相接触 并在100psi或更大的压力下在至少50℃的温度下加热所得的反应混合物足够的时间以产生所述的醇和醛。

公开(公告)号：US4371724A

公开(公告)日：1983-02-01

申请号：US224199

申请日：1981-01-08

Applicant: Jiang-Jen Lin ,  John F. Knifton

Inventor： Jiang-Jen Lin ,  John F. Knifton

IPC: B01J23/46 ,  B01J27/08 ,  B01J31/02 ,  B01J31/18 ,  B01J31/20 ,  B01J31/22 ,  B01J31/30 ,  C07C29/32 ,  C07C27/00

CPC classification number: C07C29/32 ,  B01J23/46 ,  B01J27/08 ,  B01J31/0239 ,  B01J31/0268 ,  B01J31/30 ,  B01J2531/821 ,  B01J31/20 ,  B01J31/2234 ,  Y02P20/52

Abstract: Ethanol is prepared by contacting methanol, hydrogen and carbon monoxide with a catalyst system comprising a ruthenium compound, a quaternary phosphonium or ammonium base or salt and a cobalt compound such as cobalt iodide in the presence of a non-polar, substantially inert, oxygenated hydrocarbon solvent.

Abstract translation: 乙醇是通过使甲醇，氢气和一氧化碳与包含钌化合物，季鏻或铵碱或盐的钴催化剂体系和钴化合物如碘化钴在非极性基本惰性的含氧烃 溶剂。

公开(公告)号：US4366259A

公开(公告)日：1982-12-28

申请号：US316195

申请日：1981-10-29

Applicant: John F. Knifton ,  Jiang-Jen Lin

Inventor： John F. Knifton ,  Jiang-Jen Lin

IPC: C07C27/06 ,  C07C67/36 ,  C07C69/12 ,  B01J31/00 ,  B01J31/02 ,  B01J31/16 ,  B01J31/20 ,  B01J31/24 ,  C07B61/00 ,  C07C27/00 ,  C07C29/15 ,  C07C29/151 ,  C07C29/157 ,  C07C31/02 ,  C07C31/04 ,  C07C31/08 ,  C07C31/10 ,  C07C31/12 ,  C07C51/00 ,  C07C51/10 ,  C07C53/08 ,  C07C53/122 ,  C07C67/00 ,  C07C69/003 ,  C07C69/22

CPC classification number: B01J31/2404 ,  B01J31/0268 ,  B01J31/20 ,  C07C29/1512 ,  C07C29/1514 ,  C07C29/157 ,  C07C31/04 ,  C07C31/08 ,  C07C31/10 ,  C07C31/12 ,  C07C51/10 ,  C07C67/36 ,  B01J2531/0208 ,  B01J2531/72 ,  B01J2531/74 ,  Y02P20/52

Abstract: This invention concerns a process of making acetic acid and propionic acid and their esters which comprises contacting a mixture of CO and H.sub.2 with a catalyst system comprising a ruthenium-containing compound and a cobalt halide dispersed in a low melting quaternary phosphonium or ammonium base or salt at a temperature of at least about 150.degree. C. and at a pressure of about 500 psig or greater.

Abstract translation: 本发明涉及一种制备乙酸和丙酸及其酯的方法，其包括使CO和H 2的混合物与包含钌的化合物和分散在低熔点季铵或铵碱或盐中的卤化钴的催化剂体系接触 在至少约150℃的温度和约500psig或更大的压力下。

公开(公告)号：US4332915A

公开(公告)日：1982-06-01

申请号：US279885

申请日：1981-07-02

Applicant: John F. Knifton ,  Jiang-Jen Lin

Inventor： John F. Knifton ,  Jiang-Jen Lin

IPC: C07C27/06 ,  B01J31/00 ,  B01J31/18 ,  B01J31/28 ,  C07B61/00 ,  C07C27/00 ,  C07C29/15 ,  C07C29/151 ,  C07C29/157 ,  C07C29/16 ,  C07C31/02 ,  C07C67/00 ,  C07C69/003

CPC classification number: C07C29/157 ,  C07C29/1514 ,  Y02P20/52

Abstract: This invention concerns a process of making alkanols and particularly ethanol which comprises contacting a mixture of CO and H.sub.2 at a pressure of 500 psig or greater and at a temperature of at least 150.degree. C. with a catalyst system comprising a ruthenium-containing compound and a cobalt-containing compound dispersed in a low melting quaternary phosphonium or ammonium base or salt.

Abstract translation: 本发明涉及制备链烷醇，特别是乙醇的方法，该方法包括在500psig或更高的压力以及至少150℃的温度下将CO和H 2的混合物与包含含钌化合物的催化剂体系和 分散在低熔点季铵或铵碱或盐中的含钴化合物。

公开(公告)号：US08845931B2

公开(公告)日：2014-09-30

申请号：US13279394

申请日：2011-10-24

Applicant: Jiang-Jen Lin ,  Ying-Nan Chan ,  Wei-Li Lin

Inventor： Jiang-Jen Lin ,  Ying-Nan Chan ,  Wei-Li Lin

IPC: H01B1/02 ,  H01B1/22 ,  B05D5/12

CPC classification number: B05D5/12 ,  B82Y30/00 ,  C09D5/24 ,  H01B1/22 ,  Y10T428/249921

Abstract: A method for preparing a nanometal-polymer composite conductive film includes the steps of (1) mixing a metal oxide with a polymer solution; (2) coating a substrate with a solution resulting from step (1), followed by drying the resultant solution to form a film; (3) performing thermal treatment on the film formed in step (2); and (4) sintering the film thermally treated in step (3). The method dispenses with any reducing agent or dispersing agent but allows nanometallic particles to be formed in situ and thereby reduces surface resistance of the polymer film efficiently.

Abstract translation: 制备纳米金属 - 聚合物复合导电膜的方法包括以下步骤：（1）将金属氧化物与聚合物溶液混合; （2）用步骤（1）得到的溶液涂布基材，然后干燥所得溶液以形成薄膜; （3）对在步骤（2）中形成的膜进行热处理; 和（4）烧结步骤（3）中热处理的薄膜。 该方法分配任何还原剂或分散剂，但允许在原位形成纳米金属颗粒，从而有效降低聚合物膜的表面电阻。

公开(公告)号：US08663381B2

公开(公告)日：2014-03-04

申请号：US12218871

申请日：2008-07-18

Applicant: Jiang-Jen Lin ,  Yi-Fen Lan ,  Yen-Chi Hsu

Inventor： Jiang-Jen Lin ,  Yi-Fen Lan ,  Yen-Chi Hsu

IPC: C04B14/04

CPC classification number: C09B67/0007 ,  C08K3/346 ,  C08K2201/016 ,  C09B67/0002 ,  C09D7/61 ,  C09D7/80 ,  C09D17/002 ,  C09D17/003

Abstract: A pigment is dispersed in a solvent by mixing the pigment nanoparticles with clay in a layered or platelet form and mixing the resultant mixture with the solvent. The method is based on geometric inhomogeneity and mutually exclusive aggregation. The layered or platelet clay having a high aspect ratio is provided to hinder aggregation of the pigment nanoparticles. The pigment nanoparticles can be stably dispersed in a matrix containing an organic solvent and water without aggregation again.

Abstract translation: 通过将颜料纳米颗粒与粘土以分层或片状形式混合将颜料分散在溶剂中，并将所得混合物与溶剂混合。 该方法基于几何不均匀性和互斥聚合。 提供具有高纵横比的层状或血小板粘土以阻碍颜料纳米颗粒的聚集。 颜料纳米颗粒可以稳定地分散在含有有机溶剂和水的基质中，而不再聚集。