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公开(公告)号：US08642718B2
公开(公告)日：2014-02-04
申请号：US11912929
申请日：2006-05-18
申请人： Teruo Kamura , Motoharu Takeuchi , Masahiro Johno
发明人： Teruo Kamura , Motoharu Takeuchi , Masahiro Johno
IPC分类号： C08G75/04
摘要： A curable composition containing an inorganic compound A having sulfur atom and/or selenium atom, a compound B represented by the following formula 1: wherein m is an integer from 0 to 4, and n is an integer from 0 to 2, and a compound C selected from the group consisting of disulfide compounds which are other than the compound B and have one or more disulfide linkages Inorganic compound A is contained in an amount from 1 to 50 parts by weight and compound B is contained in an amount from 50 to 99 parts by weight when a total of inorganic compound A and compound B is taken as 100 parts by weight. Compound C is contained in an amount from 1 to 20 parts by weight based on 100 parts by weight in total of inorganic compound A and compound B.
摘要翻译： 含有具有硫原子和/或硒原子的无机化合物A的固化性组合物，下式1表示的化合物B：其中，m为0〜4的整数，n为0〜2的整数， C选自不同于化合物B并且具有一个或多个二硫键的二硫化物化合物的组。无机化合物A的含量为1至50重量份，化合物B的含量为50至99 当将无机化合物A和化合物B的总计作为100重量份时，重量份。 化合物C的含量相对于无机化合物A和化合物B的100重量份为1〜20重量份。
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公开(公告)号：US07691555B2
公开(公告)日：2010-04-06
申请号：US10563868
申请日：2004-08-04
CPC分类号： C09D181/02 , C08G75/08 , C08K5/45 , Y10S430/121
摘要： There are provided a photocurable composition capable of being readily cured by irradiation of ultraviolet rays and a cured product of the photocurable composition, as well as a coating composition and a coating film obtained from the coating composition. The cured product exhibits a high refractive index, a less discoloration and an excellent transparency. The present invention relates to a photocurable composition comprising (A) an episulfide compound containing a thiirane ring; and (B) a photo-base generator represented by the general formula (1): wherein Ar is phenyl, etc.; R is an alkyl group, etc.; —A+ is an ammonium ion; and X− is a borate anion, etc., and a coating composition comprising the photocurable composition and (C) a modified silicone oil, as well as a cured product and a coating film obtained from these compositions.
摘要翻译： 提供了能够通过照射紫外线而容易地固化的光固化性组合物和光固化性组合物的固化物，以及由涂料组合物得到的涂料组合物和涂膜。 固化产物具有高的折射率，较少的变色和优异的透明度。 本发明涉及一种光固化组合物，其包含（A）含有硫杂环戊烯环的环硫化合物; 和（B）由通式（1）表示的光碱发生剂：其中Ar是苯基等; R是烷基等; -A +是铵离子; 和X-是硼酸根阴离子等，以及包含该可光固化组合物和（C）改性硅油的涂料组合物，以及由这些组合物获得的固化产物和涂膜。
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33.发明授权Process for producing a novel resin for optical materials having excellent color tone and transparency 有权具有优异的色调和透明度的光学材料用新型树脂的制造方法公开(公告)号：US06201061B1
公开(公告)日：2001-03-13
申请号：US09268784
申请日：1999-03-16
IPC分类号： C08K534
摘要： A process for producing a resin used for preparing an optical material. The process comprises curing a composition comprising an ultraviolet light absorbent and an epithio compound by polymerization in the presence of a catalyst, wherein the ultraviolet light absorbent and the catalyst are in amounts, each expressed as parts by weight per 100 parts by weight of the total amount of the epithio compound, which satisfy both of the following relationships (a) and (b): (a) 0.001≦ultraviolet light absorbent≦1,000, and (b) 0.001≦catalyst≦5,000. The process prevents coloration and clouding of optical material for a lens obtained by polymerization of an epithio compound caused by addition of an ultraviolet light absorbent.
摘要翻译： 用于制备光学材料的树脂的制造方法。 该方法包括在催化剂存在下，通过聚合固化包含紫外线吸收剂和环硫化合物的组合物，其中紫外光吸收剂和催化剂的量各自表示为每100重量份总重量的重量份数 满足以下两个关系（a）和（b）的环氧化合物的量：（a）0.001 <=紫外线吸收剂<= 1,000，和（b）0.001 <=催化剂<= 5,000。 该方法可防止通过加入紫外线吸收剂而引起的环氧化合物的聚合获得的透镜的光学材料的着色和混浊。
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34.发明申请COMPOSITION FOR USE IN OPTICAL MATERIAL WITH HIGH REFRACTIVE INDEX AND HIGH STRENGTH 有权用于具有高折射率和高强度的光学材料的组合物公开(公告)号：US20120142889A1
公开(公告)日：2012-06-07
申请号：US13319857
申请日：2010-05-10
IPC分类号： C08G75/08
摘要： A composition for use in an optical material is disclosed which is capable of providing an optical material satisfying a high refractive index (ne is 1.73 or more), a high strength (an elongation is 10% or more in a three-point bending test and drilling resistance is good), and a high thermostability (a softening point measured by TMA is 70° C. or higher). The optical material such as a lens for two-point frame spectacles is formed by polymerizing and curing a composition for use in an optical resin material containing (a) an inorganic compound having a sulfur atom and/or a selenium atom, (b) an episulfide compound, and (c) a xylylenedithiol compound.
摘要翻译： 公开了一种用于光学材料的组合物，其能够提供满足高折射率（ne为1.73以上）的光学材料，高强度（在三点弯曲试验中为10％以上的伸长率， 耐钻孔性好），高热稳定性（TMA测定的软化点为70℃以上）。 通过聚合和固化用于包含（a）具有硫原子和/或硒原子的无机化合物的光学树脂材料的组合物，形成用于两点框架眼镜的光学材料，（b） 环硫化合物，和（c）亚二甲苯基二硫醇化合物。
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35.发明授权Light control plastic lens, coated sheet-like light control element for the lens production, and a production method for light control plastic lens 有权光控塑料透镜，用于镜片生产的涂层片状光控元件，以及光控塑料透镜的制造方法公开(公告)号：US07350917B2
公开(公告)日：2008-04-01
申请号：US11041337
申请日：2005-01-25
申请人： Ryozo Kawai , Yoshiyuki Aoki , Kyohei Takakuwa , Mitsuhiko Masumoto , Toshizumi Hirota , Motoharu Takeuchi
发明人： Ryozo Kawai , Yoshiyuki Aoki , Kyohei Takakuwa , Mitsuhiko Masumoto , Toshizumi Hirota , Motoharu Takeuchi
IPC分类号： G02C7/10
CPC分类号： G02C7/12 , B29C39/025 , B29C41/20 , B29C53/04 , B29C70/70 , B29C2791/001 , B29D11/0073 , B29K2105/0002 , G02B5/23 , G02B5/305
摘要： A light control plastic lens, a sheet-like light control element, and a production method for light control plastic lenses are provided. More specifically, a light control plastic lens, such as a high index polarizing property and/or a photochromic plastic lens that is made by cast polymerization is provided. Also provided is a sheet-like light control element for use in the production of the lenses, as well as a production method of such light control plastic lenses. The light control plastic lens has a sheet-like light control element including at least a light control sheet. In particular, the light control plastic lens has a sheet-like light control element, a curable resin layer laminated on at least one surface of the sheet-like light control element, and a polymerizable lens resin layer laminated at least on the curable resin layer.
摘要翻译： 提供了光控塑料透镜，片状光控制元件和用于光控制塑料透镜的制造方法。 更具体地，提供了通过浇铸聚合制成的光控塑料透镜，例如高折射率偏振性质和/或光致变色塑料透镜。 还提供了用于制造透镜的片状光控制元件以及这种光控塑料透镜的制造方法。 光控塑料透镜具有至少包括光控板的片状光控制元件。 特别地，光控塑料透镜具有片状光控制元件，层叠在片状光控制元件的至少一个表面上的固化树脂层和至少层叠在固化树脂层上的聚合透镜树脂层 。
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公开(公告)号：US20050187413A1
公开(公告)日：2005-08-25
申请号：US11058354
申请日：2005-02-16
IPC分类号： C07C319/02 , C07C319/20 , C07C321/14 , C07C327/22 , C07C321/00
CPC分类号： C07C327/22 , C07C319/20 , C07C321/14
摘要： A vicinal dithiol is produced by the reaction of an episulfide compound having at least one thiirane ring in its molecule and a thiocarboxylic S-acid.
摘要翻译： 通过其分子中具有至少一个硫烷环的环硫化合物与硫代羧酸S-酸的反应产生连位二硫醇。
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37.发明申请Enic compounds, sulfur-containing polyenic compound, sulfur-containing polythiol compound, high refractive index photocurable composition and cured product thereof 有权烯化合物，含硫多元素化合物，含硫多硫醇化合物，高折射率光固化性组合物及其固化物公开(公告)号：US20050154073A1
公开(公告)日：2005-07-14
申请号：US11000997
申请日：2004-12-02
CPC分类号： C08K5/0025 , C08K5/37
摘要： A composition containing 3,3′-thiobis(propane-1,2-dithiol) and one or more enic compounds which composition is photocurable and can give a cured product having a high refractive index and adequate hardness.
摘要翻译： 含有3,3'-硫代双（丙烷-1,2-二硫酚）和一种或多种烯化合物的组合物，其组合物是光固化性的并且可以得到具有高折射率和足够硬度的固化产物。
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38.发明授权Composition for use in optical material with high refractive index and high strength 有权用于具有高折射率和高强度的光学材料的组合物公开(公告)号：US09150694B2
公开(公告)日：2015-10-06
申请号：US13319857
申请日：2010-05-10
摘要： A composition for use in an optical material is disclosed which is capable of providing an optical material satisfying a high refractive index (ne is 1.73 or more), a high strength (an elongation is 10% or more in a three-point bending test and drilling resistance is good), and a high thermostability (a softening point measured by TMA is 70° C. or higher). The optical material such as a lens for two-point frame spectacles is formed by polymerizing and curing a composition for use in an optical resin material containing (a) an inorganic compound having a sulfur atom and/or a selenium atom, (b) an episulfide compound, and (c) a xylylenedithiol compound.
摘要翻译： 公开了一种用于光学材料的组合物，其能够提供满足高折射率（ne为1.73以上）的光学材料，高强度（在三点弯曲试验中为10％以上的伸长率， 耐钻孔性好），高热稳定性（TMA测定的软化点为70℃以上）。 通过聚合和固化用于包含（a）具有硫原子和/或硒原子的无机化合物的光学树脂材料的组合物，形成用于两点框架眼镜的光学材料，（b） 环硫化合物，和（c）亚二甲苯基二硫醇化合物。
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公开(公告)号：US08853346B2
公开(公告)日：2014-10-07
申请号：US13580803
申请日：2011-02-08
申请人： Hitoshi Okazaki , Motoharu Takeuchi
发明人： Hitoshi Okazaki , Motoharu Takeuchi
摘要： The invention relates to a curable composition preferable as a raw material for optical materials such as adhesive agents for optical elements, coating agents for optical elements, resist materials, prisms, optical fibers, information recording substrates, filters and plastic lenses, and more specifically to a curable composition characterized by containing (A) an episulfide compound, and (B) a polymerization catalyst comprising a tetraalkylphosphonium dialkylphosphate represented by the following general formula (1): wherein R1 to R6 are the same or different, an alkyl group having 1 to 8 carbon atoms or an alkyl group having a hydroxyl group and 1 to 8 carbon atoms, and linear, branched or cycloaliphatic.
摘要翻译： 本发明涉及一种优选作为光学材料的原料的光固化性组合物，例如光学元件用粘合剂，光学元件用涂布剂，抗蚀剂材料，棱镜，光纤，信息记录基材，过滤器和塑料透镜，更特别地涉及 一种固化性组合物，其特征在于含有（A）环硫化合物，和（B）包含由以下通式（1）表示的磷酸二烷基鏻四烷基鏻的聚合催化剂：其中R 1至R 6相同或不同， 8个碳原子或具有羟基和1至8个碳原子的烷基，以及直链，支链或脂环族。
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公开(公告)号：US08394920B2
公开(公告)日：2013-03-12
申请号：US12865014
申请日：2009-02-02
申请人： Motoharu Takeuchi , Takashi Aoki
发明人： Motoharu Takeuchi , Takashi Aoki
CPC分类号： C08G75/08
摘要： According to a preferable embodiment of the present invention, a composition for a resin comprising an inorganic compound having a sulfur atom and/or a selenium atom, an episulfide compound, and a mercaptodisulfide compound can be provided. According to another preferable embodiment of the present invention, a composition for a resin having the viscosity thereof decreased to facilitate a cast polymerization operation and thus to improve the tonality of the obtained optical material can be provided. According to still another preferable embodiment of the present invention, an optical material obtained by curing the above-described composition for a resin and having a high refractive index can be provided.
摘要翻译： 根据本发明的优选实施方案，可以提供包含具有硫原子和/或硒原子的无机化合物，环硫化合物和巯基二硫化物化合物的树脂组合物。 根据本发明的另一个优选的实施方式，可以提供粘度降低的树脂组合物，以便于浇铸聚合操作，从而提高所得光学材料的调色性。 根据本发明的另一个优选实施例，可以提供通过固化上述用于树脂的组合物并具有高折射率的光学材料。
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