Elastomeric copolymers of ethylene with propylene and process for their preparation
    36.
    发明授权
    Elastomeric copolymers of ethylene with propylene and process for their preparation 失效
    乙烯与丙烯的弹性共聚物及其制备方法

    公开(公告)号:US06448351B1

    公开(公告)日:2002-09-10

    申请号:US09707645

    申请日:2000-11-07

    IPC分类号: C08F442

    摘要: Amorphous copolymers of ethylene with propylene, and optionally with minor amounts of polyenes, have the following characteristics: (A) the % content by mole of propylene in the copolymer (%P) and the triads ratio EPE/(EPE+PPE+PPP) satisfy the following relationship: 0.01%P+EPE/(E?E+PPE+PPP)≧1 (B) less than 2% of the CH2 groups in the chain are in sequences (CH2)n, wherein n is an even number. These copolymers are obtainable by operating in the presence of particular metallocene catalysts having two fluorenyl groups joined together through a bridging group.

    摘要翻译: 乙烯与丙烯和任选少量多烯的无定形共聚物具有以下特征:(A)共聚物中的丙烯含量%(%P)和三元组比EPE /(EPE + PPE + PPP) 满足以下关系:(B)链中少于2%的CH 2基团为(CH 2)n序列,其中n为偶数。这些共聚物可通过在具有两个芴基 团体通过桥接组合在一起。

    Bituminous compositions modified with polyolefinic materials
    37.
    发明授权
    Bituminous compositions modified with polyolefinic materials 失效
    用聚烯烃材料改性的沥青组合物

    公开(公告)号:US06284820B1

    公开(公告)日:2001-09-04

    申请号:US08900035

    申请日:1997-07-24

    IPC分类号: C08J9500

    摘要: The present invention relates to bituminous compositions, particularly suitable for paving and building waterproofing, comprising a bitumen and a copolymer of ethylene with propylene and/or other alpha-olefins and optionally with smaller proportion of a diene or polyene. The copolymer is besides characterized by a very low crystallinity, intrinsic viscosity higher than 1.5 dl/g and by a content of propylene units or of the alpha-olefin in form of triads comprised between 4 and 50% of the propylene or of the alpha-olefin, with at least 70% of said triads having isotactic structure.

    摘要翻译: 本发明涉及沥青组合物,特别适用于铺路和建筑防水,其包含沥青和乙烯与丙烯和/或其它α-烯烃以及任选地较少比例的二烯或多烯的共聚物。 该共聚物的特征在于非常低的结晶度,特性粘度高于1.5dl / g,丙烯单元或三元组形式的α-烯烃含量在丙烯或α-烯烃的4-50%之间, 烯烃,其中至少70%的所述三单元组具有全同立构结构。

    Catalysts and processes for the polymerization of olefins
    40.
    发明授权
    Catalysts and processes for the polymerization of olefins 失效
    催化剂和烯烃聚合方法

    公开(公告)号:US5849653A

    公开(公告)日:1998-12-15

    申请号:US503948

    申请日:1995-07-19

    摘要: Catalysts for the polymerization of olefins are disclosed, which comprise the reaction product of: (A) a bridged and/or substituted cyclopentadienyl compound of titanium, zirconium or hafnium; (B) an organometallic aluminum compound of the formula (II): Al(CH.sub.2 --CR.sup.4 R.sup.5 R.sup.6).sub.w R.sup.7.sub.y H.sub.z(II) wherein in the (CH.sub.2 --CR.sup.4 R.sup.5 R.sup.6) groups, which are the same or different, R.sup.4 is an alkyl, alkenyl or arylalkyl group having from 1 to 10 carbon atoms, R.sup.5 is an alkyl, alkenyl, aryl, arylalkyl or alkylaryl group having from 3 to 50 carbon atoms which is different from a straight alkyl or alkenyl group and, optionally, R.sup.4 and R.sup.5 fused together can form a ring having from 4 to 6 carbon atoms, R.sup.6 is hydrogen or an alkyl, alkenyl or arylalkyl group having from 1 to 10 carbon atoms, the R.sup.7 substituents, same or different, are alkyl, alkenyl, aryl, arylalkyl or alkylaryl radicals containing from 1 to 10 carbon atoms and, optionally, can contain Si or Ge atoms, w is 1, 2 or 3, z is 0 or 1, y=3-w-z; and (C) water. The molar ratio aluminum/water is comprised between 1:1 and 100:1. These catalysts show an improved activity with respect to known catalysts wherein an aluminum compound different from those of the above formula is used.

    摘要翻译: 公开了用于烯烃聚合的催化剂,其包含以下反应产物:(A)钛,锆或铪的桥连和/或取代的环戊二烯基化合物; (B)式(II)的有机金属铝化合物:Al(CH2-CR4R5R6)wR7yHz(Ⅱ)其中在相同或不同的(CH2-CR4R5R6)基团中,R4是烷基,烯基或芳基烷基 具有1至10个碳原子,R 5是具有3至50个碳原子的烷基,烯基,芳基,芳基烷基或烷基芳基,其不同于直链烷基或烯基,并且任选地,R 4和R 5稠合在一起可以形成 具有4至6个碳原子的环,R 6是氢或具有1至10个碳原子的烷基,链烯基或芳基烷基,相同或不同的R 7取代基是含1个碳原子的烷基,烯基,芳基,芳烷基或烷芳基 至10个碳原子,并且任选地可以含有Si或Ge原子,w是1,2或3,z是0或1,y = 3-wz; 和(C)水。 铝/水的摩尔比为1:1至100:1。 这些催化剂相对于已知的催化剂显示出改善的活性,其中使用与上式不同的铝化合物。