摘要:
It is an object of the present invention to provide a cathode active material capable of reducing degradation in an operation voltage and capacity as compared conventionally when used for a lithium ion secondary battery, and a method for manufacturing the same. The cathode active material contains a composite oxide of lithium and a transition metal (s), wherein a reduction loss of TLC in the composite oxide is 20 to 60%. Also, the composite oxide has a particle diameter of 0.5 to 100 μm, and is preferably fluorinated. The method for manufacturing the cathode active material includes the step of fluorinating the cathode active material. The composite oxide has a particle diameter of 0.5 to 100 μm. The fluorinating step is to fluorinate the composite oxide in a reaction vessel under conditions where fluorine gas partial pressure is 1 to 200 kPa, a reaction time is 10 minutes to 10 days, and a reaction temperature is −10 to 200° C.
摘要:
A high power lithium-ion secondary battery having an increased capacity and capable of maintaining high discharge voltage and repeating charging/discharging high current. A lithium-ion secondary battery having; an electrode group formed by laminating or winding a negative electrode layer and a positive electrode layer so as to interpose a separator made of synthetic resin, the negative electrode layer containing a material capable of intercalating/deintercalating lithium-ion, and a positive electrode layer including a lithium-containing metallic oxide; and a non-aqueous electrolyte containing lithium salt, where the electrode group is immersed. The positive electrode material unit contains a fluorinated lithium-containing metallic oxide as a main material, and the separator possesses a hydrophilic group. Further, the positive electrode material preferably contains a main material including LiNixCoyMnzO2, where 0.4≦x≦1, 0≦y≦0.2, 0≦z 0.2, x+y+z=1.
摘要翻译:一种高功率锂离子二次电池,其具有增加的容量并且能够保持高放电电压并且重复充电/放电高电流。 一种锂离子二次电池,具有: 通过层叠或卷绕负极层和正极层形成的电极组,以便插入由合成树脂制成的隔板,所述负极层含有能够嵌入/脱嵌锂离子的材料,以及包括 含锂金属氧化物; 和含有锂盐的非水电解质,浸渍电极组。 正极材料单元包含含氟的含锂金属氧化物作为主要材料,隔膜具有亲水性基团。 此外,正极材料优选含有包含LiNixCoyMnzO 2的主要材料,其中0.4≤x≤1,0<= y <= 0.2,0 <= z 0.2,x + y + z = 1。
摘要:
Single-crystal silicon carbide is obtained, which finds a wide variety of applications including semiconductors, and an etching method for single-crystal silicon carbide is provided, by which nitrogen trifluoride plasma is used in single-crystal silicon carbide to obtain a smooth surface. In order to obtain single-crystal silicon carbide having the smoothness (surface roughness) within 150 nm and the material, nitrogen trifluoride-containing gas is subjected to plasma excitation to obtain single-crystal silicon carbide with a smooth surface. It is preferable that the pressure of nitrogen trifluoride gas is in the range of 0.5 to 10 Pa. It is also preferable that the flow rate of the nitrogen trifluoride gas is in the range of 5 to 15 sccm.
摘要:
Achieved is a ceramic carbon composite material and a ceramic-coated ceramic carbon composite material which are lighter than ceramics and excellent in at least one of properties including oxidation resistance, resistance to dust generation, heat conductivity, electrical conductivity, strength, and denseness. The ceramic carbon composite material is a ceramic carbon composite material in which an interfacial layer of a ceramic is formed between carbon particles of or containing graphite. The ceramic carbon composite material can be produced by forming a green body from ceramic-coated powder in which the surfaces of carbon particles of or containing graphite are coated with individual ceramic layers and sintering the green body.
摘要:
A carbon electrode for producing gaseous nitrogen trifluoride comprising a dense texture with an average pore size of 0.5 μm or less is provided. The carbon electrode contains a carbonaceous material, and 3 to 10 wt % of at least one selected from magnesium fluoride and aluminum fluoride which have a melting point not lower than the baking temperature of the carbonaceous material.
摘要:
The present invention provides an electrolytic anode for use in electrolytically synthesizing a fluorine-containing substance by using an electrolytic bath containing a fluoride ion including: an electroconductive substrate having a sure including an electroconductive carbonaceous material; and an electroconductive carbonaceous film having a diamond structure, the electroconductive carbonaceous film coating a part of the electroconductive carbonaceous substrate, and a method for electrolytically synthesizing a fluorine-containing substance using the electrolytic anode.
摘要:
A carbon electrode is disclosed comprising a porous carbon block and having a flexural strength of at least 50 MPa and exhibiting, on a linear sweep voltammogram obtained by subjecting the carbon electrode to potential sweep in concentrated sulfuric acid at 25.degree. C., a peak having a maximum current density at a potential of at level 1.2 V. This carbon electrode is substantially free from the danger of destruction and the danger of local breakage and partial coming-off and can advantageously be used as an anode not only for stably conducting the electrolysis of an HF-containing molten salt but also for producing a desired electrolysis product with high purity.
摘要:
The problem of the present invention is to provide, in high current-low energy type ion implantation apparatuses, a graphite member for a beam line inner member of an ion implantation apparatus, which graphite member can markedly reduce particles incorporated in a wafer surface. This problem can be solved by the graphite member of the present invention, which is a graphite member for a beam line inner member of an ion implantation apparatus, which member having a bulk density of not less than 1.80 Mg/m3 and an electric resistivity of not more than 9.5 μΩ·m. Preferably, the R value obtained by dividing D band intensity at 1370 cm−1 by G band intensity at 1570 cm−1 in the Raman spectrum of a spontaneous fracture surface of the graphite member is not more than 0.20.
摘要:
A purification method for a carbon material containing carbon nanotubes is provided, which satisfies the following requirements: The method should prevent carbon nanotubes from being damaged, broken or flocculated; the method should be capable of removing the catalyst metal and carbon components other than the carbon nanotubes; and the method should be applicable to not only multi-walled carbon nanotubes but also single-walled carbon nanotubes which will undergo significant structural changes when heated to 1400° C. or higher temperatures. The method is characterized by including a carbon material preparation process for preparing a carbon material containing carbon nanotubes by an arc discharge method, using an anode made of a material containing at least carbon and a catalyst metal; and a halogen treatment process for bringing the carbon material into contact with a gas containing a halogen and/or halogen compound.
摘要:
The problem of the present invention is to provide, in high current-low energy type ion implantation apparatuses, a graphite member for a beam line inner member of an ion implantation apparatus, which graphite member can markedly reduce particles incorporated in a wafer surface. This problem can be solved by the graphite member of the present invention, which is a graphite member for a beam line inner member of an ion implantation apparatus, which member having a bulk density of not less than 1.80 Mg/m3 and an electric resistivity of not more than 9.5 μΩ·m. Preferably, the R value obtained by dividing D band intensity at 1370 cm−1 by G band intensity at 1570 cm−1 in the Raman spectrum of a spontaneous fracture surface of the graphite member is not more than 0.20.