N-phenyltetrahydroindazoles, their preparation, and their use as crop
protection agents

    公开(公告)号:US5939558A

    公开(公告)日:1999-08-17

    申请号:US793124

    申请日:1997-02-18

    IPC分类号: C07D231/56 A01N43/56

    CPC分类号: A01N43/56

    摘要: N-Phenyltetrahydroindazoles of formula (I), where R.sub.1 is H or C.sub.1-4 -alkyl; R.sup.2 is halogen, C.sub.1-4 -alkyl or C.sub.1-4 -haloalkyl; R.sup.3 is H or halogen; R.sup.4 is NO.sub.2, halogen, C.sub.1-4 -alkyl or C.sub.1-4 -haloalkyl; R.sup.5 is --XR.sup.6 ; X is --O--, --S--, --SO-- or --SO.sub.2 --; R.sup.6 is --Alk--R.sup.7 ; Alk is a substituted or unsubstituted methylene, ethylene, propylene, butylene or pentamethylene chain, where one chain member can carry a spiro-linked 2- to 5-membered C chain or where 2 ring members can be bridged via a C.sub.1-5 -alkylene chain; R.sup.7 is CN, SCN, halogen or --YR.sup.11, where Y is --O--, --S--, --SO-- or --SO.sub.2 --; R.sup.10 is H, OH, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.3 -C.sub.5 -cycloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.3 -C.sub.5 -cycloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkylthio, --NH--R.sup.12, --N(C.sub.1 -C.sub.4 -alkyl)--R.sup.12, --N(C.sub.3 -C.sub.4 -alkenyl)-R.sup.12, --N(C.sub.3 -C.sub.4 -alkynyl)-R.sup.12, pyrrolidin-1-yl, piperid-1-yl, morpholin-4-yl, azepan-1-yl, (i) unsubstituted or substituted phenyl, benzyl, phenoxy or benzyloxy; R.sup.11 is C.sub.1-6 -alkyl, C.sub.1-6 -haloalkyl or C.sub.1-6 -cycloalkyl; R.sup.12 is H, OH, C.sub.1-4 -alkyl, C.sub.3-4 -alkenyl, C.sub.3-4 -alkynyl, C.sub.3-6 -cycloalkyl, C.sub.1-4 -alkoxy, C.sub.3-4 -alkenyloxy, C.sub.3-4 -alkenyloxy, C.sub.3-4 -alkynyloxy, or substituted or unsubstituted phenyl or benzyl; and the agriculturally utilizable salts of formula (I), with the provisoes that the simultaneous meaning of R.sup.6 as dihalomethyl, R.sup.2 and R.sup.4 as chlorine and R.sup.3 as halogen is excluded; the simultaneous meaning of X as oxygen and R.sup.7 as --OR.sup.11 or C.sub.1 -C.sub.6 -alkylthio is excluded; Alk must not carry a spiro-linked three-membered ring if R.sup.7 is halogen and R.sup.11 is not C.sub.1-6 -alkyl if R.sup.1 is H, R.sup.2 is C.sub.1-4 -haloalkyl, R.sup.3 is F, R.sup.4 is halogen and R.sup.7 is --R.sup.11. Use: as herbicides; for desiccating/defoliating plants.

    Fluoro-pyridine-2,3-dicarboxylic anhydrides which are intermediates for
herbicidal pyridine-2,3-dicarboximides
    32.
    发明授权
    Fluoro-pyridine-2,3-dicarboxylic anhydrides which are intermediates for herbicidal pyridine-2,3-dicarboximides 失效
    氟 - 吡啶-2,3-二羧酸酐,它们是除草吡啶-2,3-二甲酰亚胺的中间体

    公开(公告)号:US5840904A

    公开(公告)日:1998-11-24

    申请号:US863540

    申请日:1997-05-27

    摘要: Pyridine-2,3-dicarboximides of the general formula I ##STR1## where R.sup.1 is hydrogen, alkoxy or unsubstituted or substituted alkyl, cycloalkyl, alkenyl or alkynyl and R.sup.2, R.sup.3 and R.sup.4 are identical or different and are each hydrogen, halogen, cyano, unsubstituted or substituted alkyl, benzyl, cycloalkyl, alkenyl, alkynyl, alkoxy, phenoxy or phenylthio, a 5-membered or 6-membered heterocyclic radical having one or two hetero atoms selected from the group consisting of oxygen, sulfur and nitrogen, or unsubstituted or substituted phenyl, with the proviso that a) R.sup.2 is fluorine and R.sup.3 and R.sup.4 have the abovementioned general meanings or b) R.sup.3 is fluorine, chlorine, C.sub.1 -C.sub.3 -alkoxy, C.sub.2 -C.sub.5 -alkenyloxy, C.sub.2 -C.sub.5 -alkynyloxy, trifluoromathyl or cyano and R.sup.2 and R.sup.4 have the abovementioned general meanings or c) R.sup.4 is halogen or C.sub.1 -C.sub.3 -alkoxy, C.sub.2 -C.sub.5 -alkenyloxy or C.sub.2 -C.sub.5 alky-nyloxy and R.sup.2 and R.sup.3 have the abovementioned general meanings, with the exception of 5-chloropyridine-2,3-dicarboximide, and the environmentally compatible salts thereof.

    摘要翻译: 通式I的吡啶-2,3-二羧酰亚胺其中R1是氢,烷氧基或未取代或取代的烷基,环烷基,烯基或炔基,R2,R3和R4相同或不同,各自为氢,卤素, 氰基,未取代或取代的烷基,苄基,环烷基,烯基,炔基,烷氧基,苯氧基或苯硫基,具有一个或两个选自氧,硫和氮的杂原子的5元或6元杂环基,或 未取代或取代的苯基,条件是a)R2是氟,R3和R4具有上述一般含义或b)R3是氟,氯,C1-C3-烷氧基,C2-C5-烯氧基,C2-C5-炔氧基, 三氟甲基或氰基,R2和R4具有上述一般含义或c)R 4是卤素或C 1 -C 3 - 烷氧基,C 2 -C 5 - 烯氧基或C 2 -C 5烷氧基,R 2和R 3具有上述一般含义, 5-氯吡啶-2,3-二甲酰亚胺,和环境 其相容的盐。

    Substituted 2-phenylpyridines
    33.
    发明授权
    Substituted 2-phenylpyridines 失效
    取代的2-苯基吡啶

    公开(公告)号:US5783522A

    公开(公告)日:1998-07-21

    申请号:US592355

    申请日:1996-01-11

    摘要: Substituted 2-phenylpyridines I ##STR1## R.sup.1,R.sup.3 =H, halogen, alkyl, haloalkyl, alkoxyalkyl, alkoxy, alkoxyalkoxy, OH, haloalkoxy, alkylcarbonyloxy, haloalkylcarbonyloxy, SH, alkylthio, alkylsulfinyl, alkylsulfonyl, haloalkylthio, haloalkylsulfinyl, haloalkylsulfonyl, CHO, CN, CO.sub.2 H, alkoxycarbonyl, alkoxyalkoxycarbonyl, haloalkoxycarbonyl, alkylcarbonyl, haloalkylcarbonyl, alkoxyalkylcarbonyl, CONH.sub.2, alkyl-aminocarbonyl, dialkylaminocarbonyl, pyrrolidinyl-carbonyl piperidylcarbonyl, morpholinylcarbonyl, NO.sub.2, NH.sub.2, alkylamino, dialkylamino, pyrrolidinyl, piperidinyl, morpholinyl, alkylcarbonylamino, haloalkylcarbonylamino, alkylsulfonylamino; R.sup.2 =halogen, CN, NO.sub.2, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio; or R.sup.1 +R.sup.2 or R.sup.2 +R.sup.3 =trimethylene or tetramethylene chain;R.sup.4 =halogen, alkyl, haloalkyl, alkoxyalkyl, alkoxy, alkoxyalkoxy, OH, haloalkoxy, alkylcarbonyloxy, haloalkylcarbonyloxy, SH, alkylthio, alkylsulfinyl, alkylsulfonyl, haloalkylthio, haloalkylsulfinyl, haloalkylsulfonyl, CHO, CN, CO.sub.2 H, alkoxycarbonyl, alkoxyalkoxycarbonyl, haloalkoxycarbonyl, alkylcarbonyl, haloalkylcarbonyl, alkoxyalkylcarbonyl, NO.sub.2, NH.sub.2, alkylamino, dialkylamino, pyrrolidinyl, piperidinyl, morpholinyl, alkylcarbonylamino, haloalkylcarbonylamino, alkylsulfonylamino; R.sup.5 =hydrogen or halogen; R.sup.6 =halogen, CN, NO.sub.2, OH, CF.sub.3, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkoxy; R.sup.7 =various radicals; and the N-oxides of I and the agriculturally utilizable salts of I where these exist, excepting those compounds I where R.sup.2 is C.sub.1 -C.sub.4 -alkoxy and R.sup.1 and/or R.sup.3 is carboxyl or the salt, ester or amide thereof.

    摘要翻译: PCT No.PCT / EP94 / 02263 371日期1996年1月11日 102(e)日期1996年1月11日PCT提交1994年7月11日PCT公布。 公开号WO95 / 02580 日期1995年1月26日取代的2-苯基吡啶I R1,R3 = H,卤素,烷基,卤代烷基,烷氧基烷基,烷氧基,烷氧基烷氧基,OH,卤代烷氧基,烷基羰基氧基,卤代烷基羰氧基,SH,烷硫基,烷基亚磺酰基,烷基磺酰基,卤代烷硫基, 卤代烷基亚磺酰基,卤代烷基磺酰基,CHO,CN,CO 2 H,烷氧基羰基,烷氧基烷氧基羰基,卤代烷氧基羰基,烷基羰基,卤代烷基羰基,烷氧基烷基羰基,CONH 2,烷基氨基羰基,二烷基氨基羰基,吡咯烷基 - 羰基哌啶基羰基,吗啉基羰基,NO 2,NH 2,烷基氨基,二烷基氨基,吡咯烷基,哌啶基,吗啉基 ,烷基羰基氨基,卤代烷基羰基氨基,烷基磺酰基氨基; R 2 =卤素,CN,NO 2,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,卤代烷硫基; 或R1 + R2或R2 + R3 =三亚甲基或四亚甲基链; R 4 =卤素,烷基,卤代烷基,烷氧基烷基,烷氧基,烷氧基烷氧基,OH,卤代烷氧基,烷基羰基氧基,卤代烷基羰氧基,烷硫基,烷基亚磺酰基,烷基磺酰基,卤代烷硫基,卤代烷基亚磺酰基,卤代烷基磺酰基,CHO,CN,CO 2 H,烷氧基羰基,烷氧基烷氧基羰基,卤代烷氧基羰基,烷基羰基, 卤代烷基羰基,烷氧基烷基羰基,NO 2,NH 2,烷基氨基,二烷基氨基,吡咯烷基,哌啶基,吗啉基,烷基羰基氨基,卤代烷基羰基氨基,烷基磺酰基氨基。 R5 =氢或卤素; R6 =卤素,CN,NO2,OH,CF3,C1-C6-烷基,C1-C4-烷氧基; R7 =各种基团; 和I的N-氧化物和其中存在的I的农业上可利用的盐,除了其中R 2是C 1 -C 4 - 烷氧基且R 1和/或R 3是羧基的化合物I或其盐,酯或酰胺。

    Pyridine-2,3-dicarboximides and their use for controlling undesirable
plant growth
    35.
    发明授权
    Pyridine-2,3-dicarboximides and their use for controlling undesirable plant growth 失效
    吡啶-2,3-二甲酰亚胺及其用于控制​​不希望的植物生长的用途

    公开(公告)号:US5679622A

    公开(公告)日:1997-10-21

    申请号:US361559

    申请日:1994-12-22

    摘要: Pyridine-2,3-dicarboximides of the general formula I ##STR1## where R.sup.1 is hydrogen, alkoxy or unsubstituted or substituted alkyl, cycloalkyl, alkenyl or alkynyl and R.sup.2, R.sup.3 and R.sup.4 are identical or different and are each hydrogen, halogen, cyano, unsubstituted or substituted alkyl, benzyl, cycloalkyl, alkenyl, alkynyl, alkoxy, phenoxy or phenylthio, a 5-membered or 6-membered heterocyclic radical having one or two hetero atoms selected from the group consisting of oxygen, sulfur and nitrogen, or unsubstituted or substituted phenyl, with the proviso that a) R.sup.2 is fluorine and R.sup.3 and R.sup.4 have the abovementioned general meanings or b) R.sup.3 is fluorine, chlorine, C.sub.1 -C.sub.3 -alkoxy, C.sub.2 -C.sub.5 -alkenyloxy, C.sub.2 -C.sub.5 -alkynyloxy, trifluoromethyl or cyano and R.sup.2 and R.sup.4 have the abovementioned general meanings or c) R.sup.4 is halogen or C.sub.1 -C.sub.3 -alkoxy, C.sub.2 -C.sub.5 -alkenyloxy or C.sub.2 -C.sub.5 -alkynyloxy and R.sup.2 and R.sup.3 have the abovementioned general meanings, with the exception of 5-chloropyridine-2,3-dicarboximide, and the environmentally compatible salts thereof.

    摘要翻译: 通式I的吡啶-2,3-二羧酰亚胺其中R1是氢,烷氧基或未取代或取代的烷基,环烷基,烯基或炔基,R2,R3和R4相同或不同,各自为氢,卤素, 氰基,未取代或取代的烷基,苄基,环烷基,烯基,炔基,烷氧基,苯氧基或苯硫基,具有一个或两个选自氧,硫和氮的杂原子的5元或6元杂环基,或 未取代或取代的苯基,条件是a)R2是氟,R3和R4具有上述一般含义或b)R3是氟,氯,C1-C3-烷氧基,C2-C5-烯氧基,C2-C5-炔氧基, 三氟甲基或氰基,R 2和R 4具有上述一般含义或c)R 4是卤素或C 1 -C 3 - 烷氧基,C 2 -C 5 - 烯氧基或C 2 -C 5 - 炔氧基,并且R 2和R 3具有上述一般含义, 5-氯吡啶-2,3-二甲酰亚胺,和环境 其相容的盐。

    Herbicidal N-[pyrimidin-2-ly) aminocarbonyl]-benzenesulfonamides
    37.
    发明授权
    Herbicidal N-[pyrimidin-2-ly) aminocarbonyl]-benzenesulfonamides 失效
    除草剂N- [嘧啶-2-基]氨基羰基] - 苯磺酰胺

    公开(公告)号:US5612286A

    公开(公告)日:1997-03-18

    申请号:US290959

    申请日:1994-08-24

    CPC分类号: C07D521/00 A01N47/36

    摘要: N-[(Pyrimidin-2-yl)aminocarbonyl]benzenesulfonamide of the general formula I ##STR1## where R.sup.1 is methyl or ethyl;R.sup.2 is hydrogen or methyl;R.sup.3 is unsubstituted or substituted alkyl;a group ER.sup.6, in which E is O or S, R.sup.6 being unsubstituted or fluorine-substituted alkyl, with the exception of difluoromethoxy, and, if E is O and at the same time R.sup.5 is trifluoromethyl, R.sup.6 may furthermore be methylsulfonyl, ethylsulfonyl, trifluoromethylsulfonyl, allylsulfonyl or propargylsulfonyl;NO.sub.2 or OH;dialkylaminosulfonyl if R.sup.5 is fluorine;C.sub.1 - or C.sub.2 -alkylsulfonyl which may carry 1 to 3 halogen atoms;R.sup.4 is hydrogen, methyl, ethyl, methoxy, ethoxy, fluorine, chlorine, methylthio, ethylthio or C.sub.1 or C.sub.2 -haloalkoxy; andR.sup.5 is fluorine or trifluoromethyl, and their environmentally compatible salts, processes for their preparation and their use.

    摘要翻译: PCT No.PCT / EP93 / 00362 Sec。 371日期:1994年8月24日 102(e)日期1994年8月24日PCT提交1993年2月16日PCT公布。 公开号WO93 / 16998 日期1993年9月2日N - 通式Ⅰ的[(嘧啶-2-基)氨基羰基]苯磺酰胺其中R1是甲基或乙基; R2是氢或甲基; R3是未取代或取代的烷基; 其中E是O或S的基团,R6是未取代的或氟取代的烷基,除了二氟甲氧基,并且如果E是O并且同时R5是三氟甲基,则R6还可以是甲基磺酰基,乙基磺酰基, 三氟甲基磺酰基,烯丙基磺酰基或炔丙基磺酰基; NO2或OH; 二烷基氨基磺酰如果R5是氟; 可带有1至3个卤素原子的C 1或C 2 - 烷基磺酰基; R4是氢,甲基,乙基,甲氧基,乙氧基,氟,氯,甲硫基,乙硫基或C1或C2-卤代烷氧基; 并且R 5是氟或三氟甲基,以及它们与环境相容的盐,其制备方法和用途。

    Sulfonylurea derivatives and their use
    38.
    发明授权
    Sulfonylurea derivatives and their use 失效
    磺酰脲衍生物及其用途

    公开(公告)号:US5434124A

    公开(公告)日:1995-07-18

    申请号:US94178

    申请日:1993-08-06

    CPC分类号: C07D521/00

    摘要: Sulfonylurea derivatives of the formula I ##STR1## where R.sup.1 is unsubstituted or substituted alkyl or phenyl; alkenyl or propargyl, alkylamino or dialkylamino; R.sup.2 is hydrogen, halogen, unsubstituted or substituted methyl, methoxy or ethoxy, alkylsulfonyl, nitro or cyano;R.sup.3 is difluoromethoxy, trifluoromethoxy, bromodifluoromethoxy, chlorodifluoromethoxy or fluorine;R.sup.4 is halogen, unsubstituted or halogen-substituted methyl, ethyl, methoxy or ethoxy or is methylamino or dimethylamino;R.sup.5 is hydrogen, alkyl or alkenyl or alkynyl, andZ is CH or N,with the proviso thata) when R.sup.3 is difluoromethoxy, R.sup.1 is not dialkylamino, R.sup.2 is not alkylsulfonyl and R.sup.4 is not methyl or methoxy andb) when R.sup.3 is fluorine and Z is N, R.sup.4 is not alkylamino, and salts thereof are suitable as herbicides.

    摘要翻译: PCT No.PCT / EP92 / 00182 Sec。 371日期:1993年8月6日 102(e)日期1993年8月6日PCT提交1992年1月29日PCT公布。 出版物WO92 / 日期:1992年9月3日。式I烷基或苯基的磺酰脲衍生物; 烯基或炔丙基,烷基氨基或二烷基氨基; R 2为氢,卤素,未取代或取代的甲基,甲氧基或乙氧基,烷基磺酰基,硝基或氰基; R3是二氟甲氧基,三氟甲氧基,溴二氟甲氧基,氯二氟甲氧基或氟; R4是卤素,未取代的或卤素取代的甲基,乙基,甲氧基或乙氧基,或是甲基氨基或二甲基氨基; R5是氢,烷基或烯基或炔基,Z是CH或N,条件是a)当R3是二氟甲氧基时,R1不是二烷基氨基,R2不是烷基磺酰基,R4不是甲基或甲氧基,b)当R3是 氟和Z是N,R 4不是烷基氨基,其盐适合作为除草剂。