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公开(公告)号：US10147968B2
公开(公告)日：2018-12-04
申请号：US14954816
申请日：2015-11-30
IPC分类号： H01M10/0562 , H01M10/0525 , C03B23/037 , C03B17/06 , C03B33/023 , C03B23/24 , C03C3/19 , C03C3/32 , C03C4/18
摘要： A standalone lithium ion-conductive solid electrolyte including a freestanding inorganic vitreous sheet of sulfide-based lithium ion conducting glass is capable of high performance in a lithium metal battery by providing a high degree of lithium ion conductivity while being highly resistant to the initiation and/or propagation of lithium dendrites. Such an electrolyte is also itself manufacturable, and readily adaptable for battery cell and cell component manufacture, in a cost-effective, scalable manner.
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公开(公告)号：US20170346060A1
公开(公告)日：2017-11-30
申请号：US15487364
申请日：2017-04-13
IPC分类号： H01M2/16 , H01G11/58 , H01M4/13 , H01M4/36 , H01G11/06 , H01M4/62 , H01G11/52 , H01M10/052 , H01M8/065 , H01M6/34 , H01M4/587 , H01M10/0562 , H01M10/36 , H01M12/08 , H01M4/02
CPC分类号： H01M2/1673 , H01G11/06 , H01G11/52 , H01G11/58 , H01M2/1686 , H01M4/13 , H01M4/366 , H01M4/587 , H01M4/628 , H01M6/34 , H01M8/065 , H01M10/052 , H01M10/0562 , H01M10/36 , H01M12/08 , H01M2004/027 , H01M2300/0085 , Y02E60/122 , Y02E60/128 , Y02E60/13
摘要： Active metal and active metal intercalation electrode structures and battery cells having ionically conductive protective architecture including an active metal (e.g., lithium) conductive impervious layer separated from the electrode (anode) by a porous separator impregnated with a non-aqueous electrolyte (anolyte). This protective architecture prevents the active metal from deleterious reaction with the environment on the other (cathode) side of the impervious layer, which may include aqueous or non-aqueous liquid electrolytes (catholytes) and/or a variety electrochemically active materials, including liquid, solid and gaseous oxidizers. Safety additives and designs that facilitate manufacture are also provided.
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公开(公告)号：US20170331156A1
公开(公告)日：2017-11-16
申请号：US15592102
申请日：2017-05-10
发明人： Steven J. Visco , Vitaliy Nimon , Ian Wogan , Yevgeniy S. Nimon , Lutgard C. De Jonghe , Bruce D. Katz
IPC分类号： H01M10/0585 , H01M4/38 , H01M10/0525 , H01M10/0562
CPC分类号： H01M10/0585 , H01M4/0407 , H01M4/1395 , H01M4/382 , H01M10/052 , H01M10/0525 , H01M10/0562 , H01M2300/0068
摘要： Solid-state laminate electrode assemblies and various methods for making the solid-state laminate electrode assemblies involve a lithium metal layer reactively bonded to a lithium ion conducting sulfide glass layer. During manufacture, highly reactive surfaces of the lithium metal layer and the lithium ion conducting sulfide glass layer are maintained in its substantially unpassivated state until they have been reactively bonded.
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公开(公告)号：US20170214055A1
公开(公告)日：2017-07-27
申请号：US15423458
申请日：2017-02-02
发明人： Steven J. Visco , Yevgeniy S. Nimon
IPC分类号： H01M4/62 , H01M2/16 , H01M4/38 , H01M10/0525 , H01M10/0562
CPC分类号： H01M4/628 , H01M2/1646 , H01M2/1653 , H01M2/1686 , H01M4/04 , H01M4/382 , H01M4/405 , H01M6/04 , H01M6/34 , H01M8/1016 , H01M10/0525 , H01M10/0562 , H01M10/058 , H01M10/24 , H01M10/36 , H01M10/38 , H01M12/06 , H01M12/08 , H01M16/00 , H01M16/003 , H01M2300/0071 , H01M2300/0094 , Y02E60/124 , Y02P70/54 , Y10T29/49108 , Y10T29/4911 , Y10T29/49115
摘要： Alkali (or other active) metal battery and other electrochemical cells incorporating active metal anodes together with aqueous cathode/electrolyte systems. The battery cells have a highly ionically conductive protective membrane adjacent to the alkali metal anode that effectively isolates (de-couples) the alkali metal electrode from solvent, electrolyte processing and/or cathode environments, and at the same time allows ion transport in and out of these environments. Isolation of the anode from other components of a battery cell or other electrochemical cell in this way allows the use of virtually any solvent, electrolyte and/or cathode material in conjunction with the anode. Also, optimization of electrolytes or cathode-side solvent systems may be done without impacting anode stability or performance. In particular, Li/water, Li/air and Li/metal hydride cells, components, configurations and fabrication techniques are provided.
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35.发明申请PROTECTED LITHIUM ELECTRODES WITH PROTECTIVE MEMBRANE HAVING A GARNET LIKE STRUCTURE AND LITHIUM BATTERY CELLS THEREOF 审中-公开具有保护膜的保护性锂电极，其具有GARNET类结构和锂电池电池公开(公告)号：US20160197326A1
公开(公告)日：2016-07-07
申请号：US14994011
申请日：2016-01-12
CPC分类号： H01M2/1673 , H01M4/382 , H01M6/04 , H01M6/045 , H01M8/08 , H01M12/02 , H01M12/04 , H01M12/06 , Y10T29/49108
摘要： Li/air battery cells are configurable to achieve very high energy density. The cells include a protected a lithium metal or alloy anode and an aqueous catholyte in a cathode compartment. In addition to the aqueous catholyte, components of the cathode compartment include an air cathode (e.g., oxygen electrode) and a variety of other possible elements.
摘要翻译： Li /空气电池单元可配置为实现非常高的能量密度。 电池包括在阴极室中的受保护的锂金属或合金阳极和含水阴极电解液。 除了水性阴极电解液之外，阴极室的部件还包括空气阴极（例如氧气电极）和各种其它可能的元件。
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36.发明授权Protected lithium electrodes having porous ceramic separators, including an integrated structure of porous and dense Li ion conducting garnet solid electrolyte layers 有权具有多孔陶瓷分离器的保护锂电极，包括多孔密实的Li离子导电石榴石固体电解质层的一体结构公开(公告)号：US09368775B2
公开(公告)日：2016-06-14
申请号：US14156267
申请日：2014-01-15
IPC分类号： H01M4/13 , H01M2/16 , H01M4/36 , H01G11/06 , H01G11/52 , H01G11/58 , H01M4/587 , H01M10/052 , H01M10/0562 , H01M8/06 , H01M10/36 , H01M6/34 , H01M12/08
CPC分类号： H01M2/1673 , H01G11/06 , H01G11/52 , H01G11/58 , H01M2/1686 , H01M4/13 , H01M4/366 , H01M4/587 , H01M4/628 , H01M6/34 , H01M8/065 , H01M10/052 , H01M10/0562 , H01M10/36 , H01M12/08 , H01M2004/027 , H01M2300/0085 , Y02E60/122 , Y02E60/128 , Y02E60/13
摘要： Active metal and active metal intercalation electrode structures and battery cells having ionically conductive protective architecture including an active metal (e.g., lithium) conductive impervious layer separated from the electrode (anode) by a porous separator impregnated with a non-aqueous electrolyte (anolyte). This protective architecture prevents the active metal from deleterious reaction with the environment on the other (cathode) side of the impervious layer, which may include aqueous or non-aqueous liquid electrolytes (catholytes) and/or a variety electrochemically active materials, including liquid, solid and gaseous oxidizers. Safety additives and designs that facilitate manufacture are also provided.
摘要翻译： 活性金属和活性金属插入电极结构以及具有离子导电保护结构的电池单元，其包括通过浸渍有非水电解质（阳极电解液）的多孔隔离物与电极（阳极）分离的活性金属（例如锂）导电不渗透层。 这种保护结构防止活性金属与不透水层的另一（阴极）侧的环境有害的反应，其可以包括水性或非水性液体电解质（阴极电解液）和/或各种电化学活性材料，包括液体， 固体和气体氧化剂。 还提供了便于制造的安全性添加剂和设计。
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37.发明授权Advanced lithium ion batteries based on solid state protected lithium electrodes 有权先进的锂离子电池基于固态保护锂电极公开(公告)号：US09362538B2
公开(公告)日：2016-06-07
申请号：US14292699
申请日：2014-05-30
IPC分类号： H01M2/14 , H01M2/16 , H01M6/18 , H01M10/0525 , H01M10/056 , H01M10/0562 , H01M10/0565
CPC分类号： H01M2/145 , H01M2/16 , H01M2/1673 , H01M6/18 , H01M6/181 , H01M6/182 , H01M6/185 , H01M6/187 , H01M6/188 , H01M10/0525 , H01M10/056 , H01M10/0562 , H01M10/0565 , H01M2300/0065 , H01M2300/0071 , H01M2300/008 , H01M2300/0094 , Y02E60/122 , Y02P70/54 , Y10T29/49108 , Y10T29/49115
摘要： Disclosed are ionically conductive membranes for protection of active metal anodes and methods for their fabrication. The membranes may be incorporated in active metal negative electrode (anode) structures and battery cells. In accordance with the invention, the membrane has the desired properties of high overall ionic conductivity and chemical stability towards the anode, the cathode and ambient conditions encountered in battery manufacturing. The membrane is capable of protecting an active metal anode from deleterious reaction with other battery components or ambient conditions while providing a high level of ionic conductivity to facilitate manufacture and/or enhance performance of a battery cell in which the membrane is incorporated.
摘要翻译： 公开了用于保护活性金属阳极的离子导电膜及其制造方法。 膜可以结合在活性金属负极（阳极）结构和电池单元中。 根据本发明，膜具有对电池制造中遇到的阳极总体离子导电性和化学稳定性，阴极和环境条件的期望性质。 该膜能够保护活性金属阳极免受与其他电池组分或环境条件的有害反应，同时提供高水平的离子导电性以促进制造和/或增强其中掺入膜的电池单元的性能。
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38.发明申请STANDALONE SULFIDE BASED LITHIUM ION-CONDUCTING GLASS SOLID ELECTROLYTE AND ASSOCIATED STRUCTURES, CELLS AND METHODS 审中-公开基于硅烷的锂离子导电玻璃固体电解质及相关结构，电池和方法公开(公告)号：US20160156065A1
公开(公告)日：2016-06-02
申请号：US14954816
申请日：2015-11-30
IPC分类号： H01M10/0562 , C03B23/037 , C03B17/06 , H01M10/0525
CPC分类号： H01M10/0562 , C03B17/06 , C03B17/064 , C03B17/067 , C03B23/037 , C03B23/245 , C03B33/0235 , C03C3/19 , C03C3/321 , C03C4/18 , H01M10/0525 , H01M2300/0068
摘要： A standalone lithium ion-conductive solid electrolyte including a freestanding inorganic vitreous sheet of sulfide-based lithium ion conducting glass is capable of high performance in a lithium metal battery by providing a high degree of lithium ion conductivity while being highly resistant to the initiation and/or propagation of lithium dendrites. Such an electrolyte is also itself manufacturable, and readily adaptable for battery cell and cell component manufacture, in a cost-effective, scalable manner.
摘要翻译： 包含硫化物系锂离子传导性玻璃的独立无机玻璃片的独立的锂离子传导性固体电解质通过提供高度的锂离子传导性而能够在锂金属电池中具有高性能，同时高度抵抗引发和/ 或锂枝晶的繁殖。 这种电解质本身也是可制造的，并且以成本有效的，可扩展的方式容易地适用于电池单元和电池组件制造。
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39.发明授权Lithium battery cell with protective membrane having a garnet like structure 有权具有保护膜的锂电池，具有类似石榴石的结构公开(公告)号：US09287573B2
公开(公告)日：2016-03-15
申请号：US13938029
申请日：2013-07-09
IPC分类号： H01M10/0562 , H01M6/04 , H01M10/12 , H01M6/18 , H01M8/08 , H01M2/16 , H01M4/38 , H01M12/04 , H01M12/06 , H01M12/02
CPC分类号： H01M2/1673 , H01M4/382 , H01M6/04 , H01M6/045 , H01M8/08 , H01M12/02 , H01M12/04 , H01M12/06 , Y10T29/49108
摘要： Li/air battery cells are configurable to achieve very high energy density. The cells include a protected a lithium metal or alloy anode and an aqueous catholyte in a cathode compartment. In addition to the aqueous catholyte, components of the cathode compartment include an air cathode (e.g., oxygen electrode) and a variety of other possible elements.
摘要翻译： Li /空气电池单元可配置为实现非常高的能量密度。 电池包括在阴极室中的受保护的锂金属或合金阳极和含水阴极电解液。 除了水性阴极电解液之外，阴极室的部件还包括空气阴极（例如氧气电极）和各种其它可能的元件。
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公开(公告)号：US20140335392A1
公开(公告)日：2014-11-13
申请号：US14289502
申请日：2014-05-28
CPC分类号： H01M6/34 , H01M2/1626 , H01M2/1653 , H01M4/06 , H01M4/38 , H01M4/382 , H01M4/405 , H01M4/582 , H01M12/00 , H01M2004/027 , H01M2004/029
摘要： Water activated alkali metal battery cells, protected anode bi-polar electrodes and multi-cell stacks are configurable to achieve very high energy density. The cells, bi-polar electrode and multi-cell stacks include a protected anode and a cathode having a solid phase electro-active component material that is reduced during cell discharge.
摘要翻译： 水活化的碱金属电池，受保护的阳极双极电极和多电池堆可配置以实现非常高的能量密度。 电池，双极电极和多电池堆包括受保护的阳极和具有在电池放电期间减少的固相电活性组分材料的阴极。
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