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93 条记录 (耗时 0.035 秒)

    Hybrid organic-inorganic nanocomposites and methods of preparation
    32.
    发明授权
    Hybrid organic-inorganic nanocomposites and methods of preparation 有权
    混合有机 - 无机纳米复合材料及其制备方法

    公开(公告)号：US6017632A

    公开(公告)日：2000-01-25

    申请号：US137518

    申请日：1998-08-20

    申请人： Thomas J. Pinnavaia ,  Tie Lan

    发明人： Thomas J. Pinnavaia ,  Tie Lan

    IPC分类号： C08K9/08 ,  B23B5/16 ,  C08K3/34

    CPC分类号： C08K9/08 ,  Y10T428/2991 ,  Y10T428/2993 ,  Y10T428/2998

    摘要： The present invention relates to particulate concentrate compositions formed by intercalation of a polymer polymerizing component into the galleries of a layered inorganic cation exchange composition initially in proton exchanged form and to the use of the particulate concentrates for the preparation of cured polymer-inorganic nanolayer hybrid composite compositions. The polymer polymerizing component comprising the particulate concentrate contains a basic group for reaction with the protons of the inorganic cation exchanger. Also, the polymer polymerizing component contains a functional group for polymerization reaction with a polymer precursor, a mixture of polymer precursors, or a polymer melt which is introduced into the galleries of the inorganic cation exchanger and reacts with the polymer polymerizing component to form a cured polymer-inorganic nanolayer hybrid composite. In the most preferred embodiment of the invention the layered inorganic composition is selected from the family of 2:1 layered silicate cation exchangers.

    摘要翻译： 本发明涉及通过将聚合物聚合组分嵌入最初质子交换形式的层状无机阳离子交换组合物的凝结物中形成的颗粒状浓缩物组合物以及使用颗粒浓缩物制备固化的聚合物 - 无机纳米层混合复合材料 组合物。 包含颗粒浓缩物的聚合物聚合组分含有用于与无机阳离子交换剂的质子反应的碱性基团。 此外，聚合物聚合组分含有用于与聚合物前体，聚合物前体的混合物或聚合物熔体的聚合反应的官能团，其被引入无机阳离子交换剂的凝结物中并与聚合物聚合组分反应以形成固化 聚合物 - 无机纳米层混合复合材料。 在本发明的最优选实施方案中，层状无机组合物选自2:1层状硅酸盐阳离子交换剂族。

    Porous inorganic oxide materials prepared by non-ionic surfactant templating route
    33.
    发明授权
    Porous inorganic oxide materials prepared by non-ionic surfactant templating route 失效
    通过非离子表面活性剂模板法制备的多孔无机氧化物材料

    公开(公告)号：US5622684A

    公开(公告)日：1997-04-22

    申请号：US465770

    申请日：1995-06-06

    申请人： Thomas J. Pinnavaia ,  Stephen A. Bagshaw

    发明人： Thomas J. Pinnavaia ,  Stephen A. Bagshaw

    IPC分类号： C01B37/00 ,  C01B37/02 ,  C01F7/36 ,  C01B39/04

    CPC分类号： C01B37/02 ,  C01B37/00 ,  C01B37/005 ,  C01F7/36 ,  C01P2002/04 ,  C01P2002/72 ,  C01P2004/62 ,  C01P2006/12 ,  C01P2006/16

    摘要： A method for the preparation of new quasi-crystalline, porous inorganic oxide materials possessing uniform framework-confined mesopores in the range 2.0-10.0 nm and large elementary particle size of more than 500.0 nm. The method uses an interaction between various nonionic polyethylene oxide based surfactants (N.degree.) and neutral inorganic oxide precursors (I.sunburst.) at ambient reaction temperatures. The materials formed exhibit semi-ordered arrays of well defined pores owing to the specific mechanism of self-assembly, large pore wall thicknesses of at least 2.0 nm producing highly stable materials and large particle sizes incorporating large numbers of pores. This (N.degree. I.degree.) templating approach introduces several new concepts to mesostructure synthesis. The application of the low-cost, non-toxic and biodegradable surfactants and ambient reaction temperatures, introduces environmentally clean synthetic techniques to the formation of mesostructures. Recovery of the template can be achieved through solvent extraction where the solvent may be water or ethanol.

    摘要翻译： 一种制备新的准晶体，多孔无机氧化物材料的方法，其具有2.0-10.0nm范围内的均匀框架约束的介孔和大于500.0nm的大的基本粒度。 该方法在环境反应温度下使用各种非离子聚环氧乙烷基表面活性剂（N DEG）和中性无机氧化物前体（I + 559）之间的相互作用。 所形成的材料由于具有自组装的特定机理而具有良好限定的孔的半排列，具有至少2.0nm的大孔壁厚度，产生高度稳定的材料并且具有大量的孔的大粒径。 这种（N DEG I DEG）模板方法为介孔结构合成引入了几个新概念。 低成本，无毒和可生物降解的表面活性剂和环境反应温度的应用，引入了环境清洁的合成技术来形成介观结构。 模板的回收可以通过溶剂萃取来实现，其中溶剂可以是水或乙醇。

    Method for the preparation of highly reactive clay composites for the removal of SO.sub.x from flue gas streams
    34.
    发明授权
    Method for the preparation of highly reactive clay composites for the removal of SO.sub.x from flue gas streams 失效
    用于制备用于从烟道气流中除去SO x的高反应性粘土复合材料的方法

    公开(公告)号：US5334564A

    公开(公告)日：1994-08-02

    申请号：US846583

    申请日：1992-03-05

    申请人： Thomas J. Pinnavaia ,  Jayantha Amarasekera

    发明人： Thomas J. Pinnavaia ,  Jayantha Amarasekera

    IPC分类号： B01D53/50 ,  B01J20/12 ,  B01J21/16 ,  B01J37/02 ,  B01J37/03 ,  C01B33/44 ,  B01D53/34 ,  C01B17/60

    CPC分类号： C01B33/44 ,  B01D53/508 ,  B01J20/12 ,  B01J21/16 ,  B01J37/0207 ,  B01J37/031

    摘要： The use of base/clay composites materials as sorbents for the removal of SO.sub.2 and SO.sub.3 (SO.sub.x) from flue gas and other sulfur containing gas streams is described. The base is either an alkaline earth metal carbonate (eg. CaCO.sub.3) or hydroxide (eg. Ca(OH).sub.2) is incorporated onto the clay by precipitating from corresponding metal oxide (eg. CaO) in an aqueous clay slurry. A second metal oxide or oxide precursor, preferably selected from transition metal ions, capable of promoting the oxidation of sulfur dioxide to sulfur trioxide, is incorporated to the base/clay composite during the synthesis in the form of finely divided metal oxide powder, metal oxide sol, water soluble metal salt or as clay-intercalated metal cation. The use of clay as dispersing agent for both the basic oxide and the second metal oxide component decreases the particle agglomeration of base particles and increases the rate of SO.sub.x uptake compared to the bulk bases in current use.

    摘要翻译： 描述了使用碱/粘土复合材料作为吸附剂从烟气和其它含硫气流中除去SO 2和SO 3（SO x）的物质。 碱是碱土金属碳酸盐（例如CaCO 3）或氢氧化物（例如Ca（OH）2）通过在水性粘土浆中从相应的金属氧化物（例如CaO）中沉淀而掺入到粘土上。 能够促进二氧化硫氧化成三氧化硫的第二金属氧化物或氧化物前体，优选选自过渡金属离子，在合成过程中以细分散的金属氧化物粉末，金属氧化物 溶胶，水溶性金属盐或粘土插层金属阳离子。 使用粘土作为碱性氧化物和第二金属氧化物组分的分散剂降低了基础颗粒的颗粒聚集并且增加了当前使用的与本体碱基相比的SO x吸收速率。

    Hydrated lime clay composites for the removal of SO.sub.x from flue gas streams
    35.
    发明授权
    Hydrated lime clay composites for the removal of SO.sub.x from flue gas streams 失效
    用于从烟道气流中去除SO x的熟石灰粘土复合材料

    公开(公告)号：US5298473A

    公开(公告)日：1994-03-29

    申请号：US961367

    申请日：1992-10-15

    申请人： Thomas J. Pinnavaia ,  Jayantha Amarasekera

    发明人： Thomas J. Pinnavaia ,  Jayantha Amarasekera

    IPC分类号： B01D53/50 ,  B01J20/12 ,  B01J21/16 ,  B01J37/02 ,  B01J37/03 ,  C01B33/44

    CPC分类号： B01J21/16 ,  B01D53/508 ,  B01J20/12 ,  B01J37/0207 ,  B01J37/031 ,  C01B33/44

    摘要： The preparation and the use of base/clay composites materials as sorbents for the removal of SO.sub.2 and SO.sub.3 (SO.sub.x) from flue gas and other sulfur containing gas streams is described. The base is either an alkaline earth metal carbonate (e.g. CaCO.sub.3) or hydroxide (e.g. Ca(OH).sub.2) and is incorporated onto the clay by hydrating a dry physical mixture of an alkaline earth metal oxide, a smectite clay and a second metal oxide, or metal oxide precursor to form a powdered composite material. The second metal oxide, preferably selected from transition metal ions, act as an oxidation catalyst for the conversion of sulfur dioxide to sulfur trioxide. The use of clay as dispersing agent for both the basic oxide and the catalytic oxide component decreases the particle agglomeration of base particles and increases the rate of SO.sub.x uptake compared to the bulk bases in current use.

    摘要翻译： 描述了制备和使用碱/粘土复合材料作为从烟道气和其它含硫气流中除去SO2和SO3（SOx）的吸附剂。 碱是碱土金属碳酸盐（例如CaCO 3）或氢氧化物（例如Ca（OH）2），并且通过将碱土金属氧化物，蒙脱石粘土和第二金属氧化物的干物理混合物 ，或金属氧化物前体以形成粉末状复合材料。 优选选自过渡金属离子的第二金属氧化物用作将二氧化硫转化为三氧化硫的氧化催化剂。 使用粘土作为碱性氧化物和催化氧化物组分的分散剂减少了基础颗粒的颗粒聚集并且增加了当前使用的与本体碱相比的SO x吸收速率。

    Dried metal oxide and clay particle compositions and method for the preparation thereof
    38.
    发明授权
    Dried metal oxide and clay particle compositions and method for the preparation thereof 失效
    干金属氧化物和粘土颗粒组合物及其制备方法

    公开(公告)号：US4981825A

    公开(公告)日：1991-01-01

    申请号：US406094

    申请日：1989-09-12

    申请人： Thomas J. Pinnavaia ,  Ahmad Moini

    发明人： Thomas J. Pinnavaia ,  Ahmad Moini

    IPC分类号： B01J21/16

    CPC分类号： B01J21/16

    摘要： Dried compositions of inorganic metal oxide and clay particles wherein the oxide particles are substantially segregated from each other by the clay particles are described. The compositions have a high surface area and are useful for catalytic gaseous reactions and removal of impurities from gas.

    摘要翻译： 描述了其中氧化物颗粒通过粘土颗粒彼此基本分离的无机金属氧化物和粘土颗粒的干组合物。 该组合物具有高的表面积，可用于催化气体反应和从气体中除去杂质。

    Pillared and delaminated clays containing iron
    39.
    发明授权
    Pillared and delaminated clays containing iron 失效
    含铁的分层和分层粘土

    公开(公告)号：US4665044A

    公开(公告)日：1987-05-12

    申请号：US723661

    申请日：1985-04-16

    申请人： Thomas J. Pinnavaia ,  Ming S. Tzou

    发明人： Thomas J. Pinnavaia ,  Ming S. Tzou

    IPC分类号： B01J21/16 ,  B01J23/26 ,  B01J29/04

    CPC分类号： B01J29/049 ,  B01J21/16 ,  B01J23/26

    摘要： A process for preparing a stable pillared layered lattice clay, comprising the steps of preparing a hydrolyzed solution of ferric ion by reacting a solution of a salt of the said metal with a base at temperatures in the range of 22.degree. to 28.degree. C. and aging the solution within said temperature range to develop the hydrolyzed pillaring agent, contacting an aqueous slurry of a layer lattice clay selected from the group consisting of smectites, vermiculite, and flurohectorite, with said hydrolyzed solution, and recovering the intercalated pillared clay product. The resultant pillared clay product has a unit clay cell containing from 6.1 to 9.8 ferric ions per cell, and has a repeating spacing of from about 22 to 28 Angstroms. The product is particularly useful in catalyzing conversion processes such as the well-known Fischer-Tropsch process.

    摘要翻译： 一种制备稳定的柱状层状晶格粘土的方法，包括以下步骤：通过使所述金属的盐与碱在22至28℃的温度下反应而制备水解的铁离子溶液;和 使所述溶液在所述温度范围内老化以开发水解支撑剂，使选自绿土，蛭石和氟化钙的层状晶格粘土的水性浆料与所述水解溶液接触，并回收插层的柱状粘土产品。 得到的柱状粘土产品具有每单元格含有6.1至9.8个铁离子的单位粘土细胞，并且具有约22至28埃的重复间隔。 该产品特别适用于催化转化过程，如众所周知的费 - 托法。