摘要:
The invention relates to elasthane fibers which are protected against harmful environmental influences, particularly sunlight and combustion gases, by a synergistic stabilizer combination of(a) highly alkylated, phenolic antioxidants corresponding to the following formula ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 are C.sub.1 -C.sub.3 alkyl radicals, in addition to which R.sup.3 may be C.sub.4 -C.sub.6 alkyl radicalsand(b) oligomeric, (cyclo)aliphatic phosphorous acid esters (oligomeric phosphites) obtained by reaction of pentaerythritol, perhydrobisphenol A and, optionally, a mono- alcohol with monomeric trialkyl or triaryl phosphites.
摘要:
In the production of elasthane threads by solution spinning of polyurea polyurethanes by conventional spinning processes, excellent stabilization against light and noxious gases are obtained if at least one component of the system to be spun contains tertiary amino groups and the substances used as antioxidizing agents are phenols of the kind which do not form colored nitro compounds.
摘要:
New block copolymers containing(a) a block of from 5 to 100 parts by weight polymerized, basic, nitrogen-containing aromatic vinyl compounds and from 0 to 95 parts by weight polymerized, nitrogen-free aromatic vinyl compounds and(b) a block of polymerized C.sub.4 -C.sub.6 dienes containing 25 to 95% lateral double bonds which are completely or partly reacted with alkylmercaptans.are suitable for improved suspension developers.
摘要:
The present invention relates to aqueous dispersions of graft polymers or graft copolymers containing as the graft base an aqueous polyurethane dispersion optionally containing block polyisocyanates in dispersed form as crosslinker and, as the graft covering, a polymer or a copolymer of ethylenically unsaturated monomers, characterized in that the graft covering is a polymer of ethylenically unsaturated perfluoroalkyl monomers having a molecular weight above 367 or a copolymer of perfluoroalkyl monomers such as these with comonomers free from perfluoroalkyl groups.The present invention also relates to a process for producing these dispersions and to their use as hydrophobizing and oleophobizing agents for textiles.
摘要:
The present invention relates to a process for the production of emulsions containing graft copolymers of ethylenically unsaturated perfluoroalkyl monomers on acrylate dispersions and to the use thereof as hydrophobicizing and oleophobicizing agents.
摘要:
The invention relates to a process for the production of a chemically uniform acrylonitrile vinyl chloride copolymer in an aqueous emulsion in the presence of a redox catalyst and with a fluctuating concentration of at least one iron salt in the reaction medium wherein the polymerization reaction is carried out at a pH value of from 2 to 6 in the presence of a mixture of an iron salt and a complex former, the complex former having certain apparent stability constants of the iron-II-complex and of the iron-III-complex.
摘要:
A two-phase bead polymer having an average bead diameter of from 10.mu. to 150.mu. comprising(A) 88% to 99.5% by weight of a polymer of polymerized units of at least one methacrylic acid ester containing from 1 to 10 carbon atoms in the aliphatic, saturated alcohol component; and(B) 0.5% to 12% by weight of a polyurethane which has been obtained from (1) at least one dihydroxy compound, (2) a diisocyanate from the group comprising (a) aliphatic diisocyanates having a branched carbon skeleton of 7 to 26 carbon atoms, (b) cycloaliphatic diisocyanates and (c) aliphatic or cycloaliphatic diisocyanates modified by radical graft copolymerization with vinyl monomers, (3) an aliphatic or cycloaliphatic diamine and (4) a monofunctional chain terminator.
摘要:
The present invention relates to a process for the preparation of carbonic acid esters of polyester-polyols by transesterifying the polyols with carbonic acid aryl esters at elevated temperatures under vacuum in the presence of a catalyst. The reaction conditions are controlled to avoid the formation of by-products and the chain extension of the polyester-polyols. The present invention is also concerned with the polyester carbonic acid esters so formed, their use in producing polycarbonate block copolymers and the copolymers so produced. The copolymers may be produced by transesterifying the polyester carbonic acid esters with bisphenols and subjecting the bis-hydroxyaryl carbonates so formed to normal polycarbonate synthesis such as interfacial or melt polycondensation.
摘要:
The invention relates to a process for the production of chemically uniform copolymers of acrylonitrile and vinyl chloride and, optionally, other copolymerizable ethylenically unsaturated compounds, by the method of emulsion polymerization in the presence of an anion active emulsifier and a non-ionic emulsifier.
摘要:
A process for identifying manufactured articles in which a marking agent such as a homo- or copolymer of polymerizable ethylenically unsatured monomers is applied to the articles. Said homo- or copolymer contains at least one group which can be split off to form a low molecular weight compound such as an amine or phenol, which can be converted into dyes, said dyes being used to identify the manufactured articles.