Abstract:
A process for producing coke that may include: heating a coker feedstock to a coking temperature to produce a heated coker feedstock; feeding the heated coker feedstock to a coking drum; feeding a coking additive, such as at least one hydroconversion or hydrocracking catalyst, to the coking drum; and subjecting the heated coker feedstock to thermal cracking in the coking drum to crack a portion of the coker feedstock to produce a cracked vapor product and produce a coke product.
Abstract:
A process for the oxidative dehydrogenation of ethane is disclosed. The process may include: contacting an ethane feed and an oxygen-containing gas in the presence of an oxidative dehydrogenation catalyst in an oxidative dehydrogenation reaction zone under conditions to oxidatively dehydrogenate at least a portion of the ethane to produce a product stream comprising ethylene, carbon oxides, water, and unreacted oxygen and ethane, wherein an oxygen concentration in the product stream is at least 0.1 mol %; contacting the product stream with an oxygen elimination catalyst in an oxygen elimination reaction zone to combust at least a portion of the oxygen; recovering from the oxygen elimination reaction zone an effluent having a reduced oxygen content; separating water from the effluent; separating carbon oxides and any non-condensable gas(es) from the ethylene and the unreacted ethane; and separating the ethylene from the unreacted ethane.
Abstract:
Disclosed herein is a method of controlling the air to fuel ratio in a burner containing a venturi assembly. The venturi includes an air inlet, a primary fuel inlet with a converging section, a throat portion downstream from the converging section, a diverging section downstream from the throat portion, an outlet, and a secondary gas inlet disposed downstream from the converging section and upstream from the outlet. The method comprises introducing fuel into the fuel inlet, receiving air through the air inlet by inspiration, and feeding a gas through the secondary gas inlet, the flow rate and content of the gas fed through the secondary gas inlet being selected to result in a desired air to fuel ratio through the outlet. A method of firing a heater, a burner, a furnace and firing control systems also are disclosed.
Abstract:
A process for conversion of methanol to olefins (MTO), including: contacting methanol and air in a methanol-to-olefins reactor; recovering an effluent from the methanol-to-olefins reactor comprising methanol, ethylene, and nitrogen oxides; separating the effluent via one or more reactive distillation and/or distillation stages using a hydrocarbon absorbent to recover a first fraction comprising ethylene and a second fraction comprising methane; wherein the separating comprises operating the one or more extractive distillation and/or distillation stages at temperatures and pressures sufficient to prevent any substantial conversion of nitrogen oxides to N2O3.
Abstract translation:一种将甲醇转化为烯烃(MTO)的方法,包括:将甲醇与空气在甲醇 - 烯烃反应器中接触; 回收包含甲醇,乙烯和氮氧化物的甲醇至烯烃反应器的流出物; 通过一个或多个反应蒸馏和/或蒸馏步骤使用烃吸收剂分离出流出物以回收包含乙烯的第一馏分和包含甲烷的第二馏分; 其中所述分离包括在足以防止氮氧化物大量转化为N 2 O 3的温度和压力下操作所述一个或多个萃取蒸馏和/或蒸馏级。
Abstract:
A pressure swing adsorption (PSA) system using two or more valves for controlling the flow of gases entering or exiting a bed of adsorbents is disclosed, where the two or more valves are opened sequentially (i.e., in at least two actions separated by a delay in time). The sequential opening of the valves may increase the degree to which adsorbed species are purged from the bed, and also facilitates more rapid execution of certain time steps of the PSA cycle, thus increasing adsorbent productivity The sequential opening of the valves may also allow for verification of valve operation by measuring either the absolute value, the slope (derivative) or the rate of change of derivative of the pressure, either in the adsorbent bed, in the downstream manifold, or in a volume of gas held in a buffer vessel.
Abstract:
An improved process for the production of olefins, and in particular for separation of olefins produced by a dehydrogenation process from paraffin feed stocks, is provided. A high pressure product splitter is used to separate olefins produced in a dehydrogenation plant from residual paraffin feed stocks. The use of a high pressure splitter to separate olefin products from paraffin feed stocks allows for recovery of a high purity olefin product with lower energy consumption compared to prior art processes. The process is particularly suited to separation of propylene from propane.
Abstract:
Disclosed is a process for the production of C2 to C3 olefins via the catalytic cracking of feedstocks including C4 and heavier olefins in an integrated reaction/regeneration system.
Abstract:
Processes for upgrading resid hydrocarbon feeds are disclosed. The upgrading processes may include: hydrocracking a resid in a first reaction stage to form a first stage effluent; hydrocracking a deasphalted oil fraction in a second reaction stage to form a second stage effluent; fractionating the first stage effluent and the second stage effluent to recover at least one distillate hydrocarbon fraction and a resid hydrocarbon fraction; feeding the resid hydrocarbon fraction to a solvent deasphalting unit to provide an asphaltene fraction and the deasphalted oil fraction.
Abstract:
A process for the production of propylene, the process including: fractionating a hydrocarbon stream comprising n-butenes, isobutylene, and paraffins into at least two fractions including a light C4 fraction comprising isobutylene and a heavy C4 fraction comprising n-butenes and paraffins; contacting at least a portion of the heavy C4 fraction with a metathesis catalyst to form a metathesis product comprising ethylene, propylene, C4+ olefins, and paraffins; fractionating the metathesis product into at least four fractions including an ethylene fraction, a propylene fraction, a C4 fraction comprising C4 olefins and paraffins, and a C5+ fraction; cracking the light C4 fraction and the C5+ fraction to produce a cracking product comprising ethylene, propylene, and heavier hydrocarbons; and fractionating the cracking product into at least two fractions including a light fraction comprising propylene and a fraction comprising C5 to C6 hydrocarbons.
Abstract:
A method and system for providing heat to a chemical conversion process is advantageously employed in the production of olefin by the catalytic dehydrogenation of a corresponding hydrocarbon. The catalytic dehydrogenation process employs diluent steam operating at a steam to oil ratio which can be 1.0 or below and relatively low steam superheater furnace temperature. The process and system are advantageously employed for the production of styrene by the catalytic dehydrogenation of ethylbenzene.