摘要:
The present disclosure relates to compounds including fluorine or chlorine, and methods for making these compounds. The compounds of the present disclosure are stable and permit long-term storage, while at the same time allowing for safely, easily and reversibly extraction of fluorine and/or chlorine therefrom.
摘要:
The present invention relates to a cesium borosilicate compound, a nonlinear optical crystal of cesium borosilicate, and a preparation method therefor and a use thereof. The cesium borosilicate compound has a chemical formula of Cs2B4SiO9 and a molecular weight of 481.15, and is prepared using a solid phase method. The nonlinear optical crystal of the cesium borosilicate compound has a chemical formula of Cs2B4SiO9 and a molecular weight of 481.15, does not have a center of symmetry, belongs to the tetragonal system with space group I 4 and unit-cell parameters a=6.731(3) Å, c=9.871(9) Å and V=447.2(5) Å3, and has a wide transmittance range. The shortest ultraviolet cutoff edge is smaller than 190 nm, the frequency doubling effect of the crystal is 4.6 KDP, and the crystal is grown by a high-temperature solution spontaneous crystallization method and a flux method. The crystal has advantages of high growth rate, being transparent and inclusion free, low cost having a wide transmittance range, high hardness, good mechanical property, being crack resistant and not prone to deliquescence, being easy to process and store, and the like. The crystal is widely applied to manufacturing of nonlinear optical devices such as frequency doubling generators, frequency up-converters, frequency down-converters or optical parametric oscillators.
摘要:
A method for separating sodium and potassium from an aqueous solution containing such metals, which comprises selectively ion-exchanging sodium and potassium with titania hydrate (TiO.sub.2 .multidot.nH.sub.2 O where n=1 to 2) obtained by treating potassium titanate to remove potassium therefrom, followed by a reaction at a temperature of from 25.degree. to 80.degree. C. to desorb and purify sodium and potassium.
摘要:
A method for removing 99% of the sodium ions from a natural or industrial brine containing dissolved salts of metals of Group 1A of the periodic chart and in which brine sodium ions are not the predominant metal ions by contacting the brine at pH 11 to 12 with an ion exchanger selected from crystalline antimonic acid and polyantimonic acid, and removing from contact with the ion exchanger the brine with greater than 99% of the sodium ions removed.
摘要:
Macroporous cation exchange resins with sulfonic acid functional groups having polymeric hydrous zirconium oxide and polyacrylic acid contained therein are useful in substantially removing sulfate, borate, bicarbonate and/or phosphate ions from alkali metal salt solutions.
摘要:
Method and compositions are provided concerning stable supersaturated aqueous solutions of sparingly soluble inorganic salts. The method involves exceeding the solubility level of a sparingly soluable inorganic salt in water at ambient temperatures in the presence of polyanionic polyelectrolyte having a molecular weight of at least about 900 daltons and an ionic equivalent weight of not greater than about 65 and at least five ionizable groups per molecule. The solubility level may be exceeded by cooling a saturated solution of the sparingly soluble salt, preparing the sparingly soluble salt in situ, or adding a soluble salt having a common ion with the sparingly soluble salt to a concentrated or saturated solution of the sparingly soluble salt.
摘要:
METATHESIS REACTIONS BETWEEN WATER SOLUBLE IONIC COMPOUNDS ARE CARRIED OUT BY MEANS OF A LIQUID EXTRACTION PROCESS USING WATER AND A MIXTURES ORGANIC SOLVENT. THE SEPARATION OF MIXTURES OF WATER SOLUBLE SALTS ARE ALSO CARRIED OUT USING WATER AND A WATER MISCIBLE ORGANIC SOLVENT.
摘要:
Metathesis reactions between water-soluble ionic compounds are carried out by means of a liquid extraction process using water and a water-miscible organic solvent. The separation of mixtures of water-soluble salts are also carried out using water and a water miscible organic solvent.