摘要:
Disclosed is a 12CaO.7Al2O3 compound, a 12SrO.7Al2O3 compound, or a mixed crystal compound of 12CaO.7Al2O3 and 12SrO.7Al2O3, which contains a negative hydrogen ion (H−, H2−, H2− at a concentration of 1×1018 cm−3 or more. A negative hydrogen ion comprising a primary component of a hydride ion is incorporated into C12A7 (12CaO.7Al2O3), so that a function of being converted from an insulative material to an electrically conductive material in a sustained manner by means of irradiation with light can be exhibited even in the normal atmosphere at a room temperature. The present invention also provides a solid electrolyte capable of conducting a negative hydrogen ion, and means for releasing a hydride ion from the inside of a solid into a gaseous phase using an electric field.
摘要:
In a solid solution system of Al2O3 and CAO or SrO, it has been difficult to obtain a material having a high electrical conductivity (>10−4 S·cm−) at room temperature.A compound is provided in which electrons at a high concentration are introduced into a 12CaO.7Al2O3 compound, a 12SrO.7Al2O3 compound, or a mixed crystal compound containing 12CaO.7Al2O3 and 12SrO.7Al2O3. The compound formed by substituting all the free oxygen ions with electrons is regarded as an electride compound in which [Ca24Al28O64]4+(4e−) or [Sr24Al28O64]4+(4e−) serves as a cation and electrons serve as anions. When a single crystal or a hydrostatic pressure press molded material of a fine powder thereof is held at approximately 700° C. in an alkaline metal vapor or an alkaline earth metal vapor, melt of a hydrostatic pressure press molded material of a powder is held at approximately 1,600° C. in a carbon crucible, followed by slow cooling for solidification, or a thin film of the compound held at approximately 600° C. is implanted with rare gas ions, a great number of the free oxygen ions can be substituted with electrons.
摘要:
Described are preferred polymerized organic-inorganic processes for producing mixed metal oxide powders suitable for use in the ceramics and related industries. The preferred processes employ a non-chelating polymer such as polyvinyl alcohol or polyalkylene glycol as a carrier and can provide single-phase, mixed oxide powders in high yields at relatively low temperatures.
摘要:
An additive, a mixture incorporating the additive and a method of formulating a mortar incorporating the additive. The additive is based on calcium sulfoaluminate composed of C3AH6 and CAH10 where C=calcium oxide, A=aluminum oxide and H=water. The admixture includes gypsum and calcium hydroxide. The calcium aluminum hydrates are obtained by hydration of high alumina cement particles to eliminate any lack of hydration in the core of the particle. The method involves the preparation of such particles and the mix incorporates the particles to produce a homogeneously hydrated cement additive.
摘要:
Catalyst for steam cracking reactions consisting of pure mayenite having the general formula: 12CaO.7Al2O3 having an X-ray diffraction spectrum as indicated in Table I, obtained with a preparation process comprising the following steps: dissolution of salts containing calcium and aluminum with water; complexing of the dissolved salts by means of polyfunctional organic hydroxyacids; drying of the solution resulting from the complexing in order to obtain a solid precursor product; calcination of the solid precursor product at a temperature ranging from 1300 to 1400null C. for at least two hours.
摘要:
A carbonaceous waste product, preferably containing 30 to 60% mineral substances, 35 to 55% carbonaceous materials, 5 to 20% water, and having a calorific value of 2,000 to 3,500 k cal/kg is fired to produce thermal energy and a combustion residue. The residue is adjusted, if necessary, by addition of mineral containing additives so that it contains 15 to 50% alumina, 15 to 20% silica and 13 to 45% other oxides (mainly iron oxide, manganese oxide and calcium oxide). Sufficient limestone is added to produce a mixture containing 1.8 to 2.2 moles of calcium oxide per mole of silica and 1.1 to 1.3 moles of calcium oxide per mole of alumina. The mixture is then sintered. The total energy requirements of the sintering step are supplied by the energy generated in the firing step. Useful products such as cement and cast stone can be produced from the sintered product.
摘要翻译:焙烧产生热能和燃烧残余物的碳质废物,优选含有30〜60%的矿物质,35〜55%的含碳物质,5〜20%的水,发热量为2,000〜3,500kcal / kg 。 如果需要,通过添加含矿物质的添加剂调节残渣,使其含有15〜50%的氧化铝,15〜20%的二氧化硅和13〜45%的其他氧化物(主要是氧化铁,氧化锰和氧化钙)。 添加足够的石灰石以产生每摩尔二氧化硅含有1.8至2.2摩尔氧化钙和每摩尔氧化铝1.1至1.3摩尔氧化钙的混合物。 然后将混合物烧结。 烧结步骤的总能量需求由在烧制步骤中产生的能量提供。 有用的产品如水泥和铸石可由烧结产品生产。
摘要:
In the making of a mortar or concrete rich in aluminate cement wherein the cement is mixed with water to hydrate and is thereafter permitted to harden, the improvement which comprises adding to the mixture of cement and water an ionic compound containing anions X.sup.n- whereby there are formed mixed crystals of the formula[Ca.sub.2 Al(OH).sub.6 ].sup.- [( m/n)X.sup.n- (1-m) Al(OH).sub.4.sup.- mAl(OH).sub.3 ; aq].sup.-Preferably X is NO.sub.2.sup.-, SO.sub.3.sup.2-, S.sub.2 O.sub.3.sup.2-, Fe(CN).sub.6.sup.3-, PO.sub.4.sup.3-, FE(CN).sub.6.sup.4-, MnO.sub.4 --, ClO.sub.3.sup.- or CrO.sub.4.sup.2-. The mixed crystals are new.
摘要:
1. A METHOD OF RECOVERING ALUMINUM FROM A COMPOSITION CONTAINING AN ALKYL ALUMINUM COMPOUND, SAID METHOD COMPRISING REACTING SAID COMPOSITION WITH AN ANILINE TO FORM AN ALUMINUM ANILIDE, HYDROLYZING SAID ALUMINUM ANILIDE WITH AQUEOUS BASE, AND REACTING THE HYDROLYZED PRODUCT WITH AN ALKALINE EARTH METAL BASE TO PRECIPITATE AN ALKALINE EARTH METAL ALUMINATE IN A RECOVERABLE FORM.