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    Hyperbranched polybenzazoles via an A3+ B2 polymerization
    31.
    发明授权
    Hyperbranched polybenzazoles via an A3+ B2 polymerization 有权
    超支化聚苯并唑通过A3 + B2聚合

    公开(公告)号：US07790831B1

    公开(公告)日：2010-09-07

    申请号：US11472214

    申请日：2006-06-15

    申请人： Loon-Seng Tan ,  David H. Wang ,  Jong-Beom Baek

    发明人： Loon-Seng Tan ,  David H. Wang ,  Jong-Beom Baek

    IPC分类号： C08G63/06

    CPC分类号： C08G83/005 ,  C08G73/22

    摘要： In accordance with the present invention there are provided hyperbranched benzobisazole polymers having repeating units of the formulas: and hyperbranched bibenzazole polymers having repeating units of the formulas: wherein Q is —S— or —NH—; the terminal groups X and Y are COOH and respectively, with their total number (X+Y) equals n+1, where n=degree of polymerization. The ratio X:Y can be controlled by varying the stoichiometric ratio of trimesic acid (A3 monomer) and 2,5-diamino-1,4-dimercaptobenzene dihydrochloride (B2 monomer) from 1:1 to 1.1.35.

    摘要翻译： 根据本发明，提供了具有下式重复单元的超支化苯并二唑聚合物：具有下式重复单元的超支化双苯并唑聚合物：其中Q是-S-或-NH-; 端基X和Y分别为COOH，它们的总数（X + Y）分别等于n + 1，其中n =聚合度。 比例X：Y可以通过将1,3次苯三酸（A3单体）和2,5-二氨基-1,4-二巯基苯二盐酸盐（B2单体）的化学计量比从1：1变化到1.1.35来控制。

    Hyperbranched polyimide-based hybrid material
    32.
    发明授权
    Hyperbranched polyimide-based hybrid material 有权
    超支化聚酰亚胺类杂化材料

    公开(公告)号：US07771521B2

    公开(公告)日：2010-08-10

    申请号：US11680187

    申请日：2007-02-28

    申请人： Yasuharu Yamada ,  Tomoyuki Suzuki

    发明人： Yasuharu Yamada ,  Tomoyuki Suzuki

    IPC分类号： C08L79/08 ,  B01D53/22 ,  B01D71/06 ,  B01D71/64 ,  H01L21/312

    CPC分类号： C08G83/005 ,  C08G73/10 ,  C08K3/20 ,  C08L79/08

    摘要： It is an object of the present invention to provide a polyimide-based hybrid material which is industrially and advantageously utilized because of having better gas permeability, electric characteristics, heat resistance, mechanical strength, and the like as compared with the conventional polyimide-based hybrid materials, while keeping chemical resistance, forming characteristics (process characteristics), and the like inherently possessed by polyimide. Provided is a hyperbranched polyimide-based hybrid material constituted of an organic-inorganic polymer hybrid, wherein the organic-inorganic polymer hybrid has a hyperbranched polyimide moiety and an inorganic oxide moiety which are combining each other via covalent bond and constituting a composite structure.

    摘要翻译： 本发明的目的是提供一种与传统的聚酰亚胺类杂化物相比具有更好的气体渗透性，电特性，耐热性，机械强度等在工业上有利地使用的聚酰亚胺类杂化材料 材料，同时保持聚酰亚胺固有的耐化学性，成型特性（工艺特性）等。 提供一种由有机 - 无机聚合物杂化物构成的超支化聚酰亚胺系混合材料，其中有机 - 无机聚合物杂化物具有通过共价键彼此结合并构成复合结构的超支化聚酰亚胺部分和无机氧化物部分。

    Multi-branched polymer
    33.
    发明授权
    Multi-branched polymer 有权
    多支化聚合物

    公开(公告)号：US07732549B2

    公开(公告)日：2010-06-08

    申请号：US10595974

    申请日：2004-11-25

    申请人： Koichiro Aoyagi ,  Takeshi Niitani

    发明人： Koichiro Aoyagi ,  Takeshi Niitani

    IPC分类号： C08F4/06 ,  C08F12/16 ,  C08F20/22

    CPC分类号： C08F12/16 ,  C08F4/06 ,  C08G83/005

    摘要： The aim of the present invention is to provide a multi-branched polymer, in which branch terminals can be easily modified and which have a high degree of branching and narrow dispersion. By polymerizing a compound having 2 or more polymerization-initiation sites and polymerizable unsaturated bonds with a living radical polymerization method using a metal catalyst, it is possible to produce a multi-branched polymer with narrow dispersion and a high degree of branching and having repeating units represented by the formula (I): wherein R1 to R3 each independently represents hydrogen or a hydrocarbon group, R1 may be bonded to R3 to form a ring; X represents a connecting group having a valence of 3 or higher; Y may be the same or different and each represents a functional group which may have a halogen atom at a terminal thereof; and a is an integer of 2 or larger.

    摘要翻译： 本发明的目的是提供一种多支化聚合物，其中分支端子可以容易地改性并且具有高度的支化度和窄的分散性。 通过使用金属催化剂通过活性自由基聚合法聚合具有2个以上聚合引发部位和聚合性不饱和键的化合物，可以制造具有窄分散性和高支化度的重复单元的多支链聚合物 由式（I）表示：其中R 1至R 3各自独立地表示氢或烃基，R 1可以与R 3结合形成环; X表示3价以上的连接基， Y可以相同或不同，表示可以在其末端具有卤素原子的官能团; a为2以上的整数。

    Hyperbranched polymer and method for producing the same
    35.
    发明申请
    Hyperbranched polymer and method for producing the same 有权
    超支化聚合物及其制备方法

    公开(公告)号：US20100048845A1

    公开(公告)日：2010-02-25

    申请号：US12310543

    申请日：2007-08-29

    申请人： Kei Yasui ,  Masaaki Ozawa ,  Akihiro Tanaka ,  Hiroki Takemoto

    发明人： Kei Yasui ,  Masaaki Ozawa ,  Akihiro Tanaka ,  Hiroki Takemoto

    IPC分类号： C08F128/02

    CPC分类号： C08F2/38 ,  C08F8/00 ,  C08F8/22 ,  C08F8/26 ,  C08F8/30 ,  C08F8/32 ,  C08F8/44 ,  C08G83/005 ,  C08F112/14

    摘要： Disclosed is a novel optically stable hyperbranched polymer whose molecular terminal can be derivatized with various compounds; and a method for producing such a polymer. Specifically disclosed is a hyperbranched polymer having a structure represented by Formula (1) wherein a halogen atom is at a molecular terminal. The hyperbranched polymer can be obtained by substituting the molecular terminal dithiocarbamate group of a hyperbranched polymer having a dithiocarbamate group at a molecular terminal, which is obtained by living radical polymerization of a dithiocarbamate compound having a vinyl group structure, with a halogen atom. Also disclosed is a hyperbranched polymer wherein an amino group or an ammonium group is at a molecular terminal instead of a halogen atom.

    摘要翻译： 公开了一种新型光学稳定的超支化聚合物，其分子末端可以用各种化合物衍生化; 和这种聚合物的制造方法。 具体公开了具有由式（1）表示的结构的超支化聚合物，其中卤素原子在分子末端。 超支化聚合物可以通过在具有乙烯基结构的二硫代氨基甲酸酯化合物的活性自由基聚合与卤素原子的分子末端取代具有二硫代氨基甲酸酯基团的超支化聚合物的分子末端二硫代氨基甲酸酯基团来获得。 还公开了一种超支化聚合物，其中氨基或铵基位于分子末端而不是卤素原子。

    METHOD AND FORMULA FOR FORMING HYPER-BRANCHED POLYMER
    37.
    发明申请
    METHOD AND FORMULA FOR FORMING HYPER-BRANCHED POLYMER 有权
    形成高分子量聚合物的方法和方法

    公开(公告)号：US20100022716A1

    公开(公告)日：2010-01-28

    申请号：US12334334

    申请日：2008-12-12

    申请人： Jing-Pin Pan ,  Tsung-Hsiung Wang

    发明人： Jing-Pin Pan ,  Tsung-Hsiung Wang

    IPC分类号： C08G73/10 ,  C08G77/00 ,  C08L33/24

    CPC分类号： C08G73/12 ,  C08G83/005 ,  C08L79/085

    摘要： The invention provides hyper-branched polymer manufactured by adding a bismaleimide and a barbituric acid into a Brönsted base solution and reacting the mixture at 20 to 100° C. The formation may further include maleimide monomer and/or multi-maleimide monomer to modify the hyper-branched polymer properties. In addition, the barbituric acid is added to the reaction in a batch not initially charged with other reactants in a one-pot.

    摘要翻译： 本发明提供了通过将双马来酰亚胺和巴比妥酸加入到布朗斯台德碱溶液中制备的超支化聚合物，并使该混合物在20-100℃下反应。该形成物还可包括马来酰亚胺单体和/或多马来酰亚胺单体以改性超 支链聚合物性质。 此外，将巴比妥酸以一罐不经最初加入其它反应物的批次加入到反应中。

    HYPERBRANCHED MALEIC ANHYDRIDE-DIENE POLYMERS
    38.
    发明申请
    HYPERBRANCHED MALEIC ANHYDRIDE-DIENE POLYMERS 失效
    高分子量非离子表面活性剂聚合物

    公开(公告)号：US20090292092A1

    公开(公告)日：2009-11-26

    申请号：US12503516

    申请日：2009-07-15

    申请人： Stephen Ernest Jacobson ,  Patricia Metzger Cotts

    发明人： Stephen Ernest Jacobson ,  Patricia Metzger Cotts

    IPC分类号： C08F222/06 ,  C08F4/32 ,  C08F4/04 ,  C08F2/00

    CPC分类号： C08F222/06 ,  C08F236/22 ,  C08G83/005 ,  Y10T428/2938 ,  Y10T428/2967 ,  Y10T428/2969 ,  Y10T428/31855 ,  Y10T428/31895 ,  Y10T428/31989

    摘要： A hyperbranched polymer having pendent olefinic groups and comprising polymer units derived from one or more terminally-unsaturated, acyclic aliphatic diene and polymer units derived from maleic anhydride. Optionally, the hyperbranched polymer may further comprise polymer units derived from one or more 1-alkenes and/or a chain transfer agent. A process to prepare the hyperbranched polymer comprises contacting maleic anhydride with at least one terminally unsaturated acyclic aliphatic diene having at least 7 carbon atoms in the presence of an effective amount of a radical initiator in an aprotic solvent under dilute conditions.

    摘要翻译： 具有侧链烯基并且包含衍生自一种或多种末端不饱和的无环脂族二烯的聚合物单元和衍生自马来酸酐的聚合物单元的超支化聚合物。 任选地，超支化聚合物还可包含衍生自一种或多种1-烯烃和/或链转移剂的聚合物单元。 制备超支化聚合物的方法包括在稀释条件下，在有效量的自由基引发剂的存在下，在非质子传递溶剂中使马来酸酐与至少一种具有至少7个碳原子的末端不饱和非环状脂族二烯的接触。

    Carboxylic-acid-terminated hyperbranched poly(benzoxazole) and the star block copolymers therefrom
    39.
    发明授权
    Carboxylic-acid-terminated hyperbranched poly(benzoxazole) and the star block copolymers therefrom 失效
    羧酸封端的超支化聚（苯并恶唑）和其中的星形嵌段共聚物

    公开(公告)号：US07582719B1

    公开(公告)日：2009-09-01

    申请号：US11193990

    申请日：2005-07-28

    申请人： Loon-Seng Tan ,  Jong-Beom Baek

    发明人： Loon-Seng Tan ,  Jong-Beom Baek

    IPC分类号： C08G63/06 ,  C08G63/12 ,  C08G73/06

    CPC分类号： C08G73/18 ,  C08G65/4012 ,  C08G73/22 ,  C08G83/005 ,  C08L2205/05

    摘要： Hyperbranched benzazole polymers having repeating units of the formula: wherein Q is —O—, —S— or —NH—, and the terminal groups R are carboxylic acids with their total number equals n+1. A generic method for preparing the polymers is provided. Also provided are the star block copolymers derived from these hyperbranched benzazole polymers and linear poly(ether-ketones) having the following generic formula where x and y are the numbers of repeat units for each poly(ether-ketone) chain; the placement of the carbonyl moieties in the repeat units of the poly(ether-ketone) chains can be either meta or para to the phenoxy groups; the maximal number of poly(ether-ketone) chains is n+1, where n=number of repeat units for hyperbranched polybenzazole). A general method for synthesizing these star block copolymers is provided.

    摘要翻译： 具有下式的重复单元的超支化苯并唑聚合物：其中Q是-O - ， - S-或-NH-，端基R是总数等于n + 1的羧酸。 提供了制备聚合物的通用方法。 还提供了衍生自这些超支化苯并唑聚合物的星形嵌段共聚物和具有以下通式的线性聚（醚 - 酮），其中x和y是每个聚（醚 - 酮）链的重复单元数; 聚（醚 - 酮）链的重复单元中的羰基部分的位置可以是苯氧基的间位或对位; 聚（醚 - 酮）链的最大数量为n + 1，其中n =超支化聚吲唑的重复单元数）。 提供了合成这些星型嵌段共聚物的一般方法。