1-(Norborn-5'-en-2'-yl) or 1-(norborn-2'-yl) substituted 1-alken-3-ols
and alkan-3-ols
    32.
    发明授权
    1-(Norborn-5'-en-2'-yl) or 1-(norborn-2'-yl) substituted 1-alken-3-ols and alkan-3-ols 失效
    1-(降冰片烯-2(40-基)取代的1-烯-3-醇和链烷-3-醇的1-(Norborn-5 {40-烯-2 {40-基)

    公开(公告)号:US4128509A

    公开(公告)日:1978-12-05

    申请号:US528124

    申请日:1974-11-29

    摘要: 1-(Norborn-5'-en-2'-yl) or 1-(norborn-2'-yl) substituted 1-alken-3-ols and alkan-3-ols characterized by the structural formulae ##STR1## wherein R.sup.1 represents hydrogen or methyl, R represents an alkyl with from 1 to 8 carbon atoms, and R.sup.2 and R.sup.3 represent hydrogen or an alkyl with from 1 to 8 carbon atoms, provided that R and R.sup.2 can be --CH.sub.2 --.sub.n wherein n represents the integer 2, 3 or 4. The compounds have very pleasant, lasting floral-woody aromas and are useful as components in fragrance compositions.

    摘要翻译: 1-(降冰片-2'-基) - 1-(降冰片-2'-基)取代的1-烯-3-醇和结构式为“IMAGE”的链烷-3-基,其中R1 表示氢或甲基,R表示具有1至8个碳原子的烷基,R 2和R 3表示氢或具有1至8个碳原子的烷基,条件是R和R 2可以是-CH 2-n,其中n表示整数 该化合物具有非常愉快,持久的花木香味,并且可用作香料组合物中的组分。

    Flavoring with norbornanol derivatives
    35.
    发明授权
    Flavoring with norbornanol derivatives 失效
    用降冰片烷醇衍生物调味

    公开(公告)号:US4089986A

    公开(公告)日:1978-05-16

    申请号:US834399

    申请日:1977-09-19

    摘要: Processes and compositions are described for the use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma and perfume aroma augmenting, enhancing, modifying and imparting compositions and as foodstuff, chewing gum, toothpaste, medicinal product, perfume and perfumed article aroma imparting materials of 3,3-dimethyl-2(3-butenyl) norbornanol-2 (hereinafter referred to as the "norbornanol derivative" having the structure: ##STR1## (which structure is intended to cover both the "endo" and the "exo" isomers thereof) produced by a process which comprises reacting an allylic Grignard reagent having the structure: wherein X is chloro, bromo or iodo with camphene oxide having the structure: ##STR2## by either "exo" camphene oxide or "endo" camphene oxide or a mixture of "exo" and "endo" camphene oxide. Addition of the said norbornanol derivative to consumable materials is indicated to produce:(a) In foodstuffs, foodstuff flavorings, chewing gums, toothpastes and medicinal products, sweet, fruity, berry-like aromas with woody, incense-like, cedarwood-like, tea-like and floral nuances and incense-like and cedarwood-like flavors with rosey, berry and tea-like nuances; and(b) In perfumes, colognes and perfumed articles, sweet, woody, thujone-like aromas with strong fir-balsam, armoise, cedarleaf, piney, earthy and camphoraceous nuances.

    摘要翻译: 描述了用于食品,口香糖,牙膏和药用产品风味和芳香和香料香气的方法和组合物,其增强,增强,改性和赋予组合物以及作为食品,口香糖,牙膏,药用产品,香料和香料制品香气赋予 3,3-二甲基-2(3-丁烯基)降冰片烷醇-2的材料(以下称为“降冰片醇衍生物”,具有以下结构:(该结构旨在涵盖“endo”和“exo 通过包括使具有以下结构的烯丙基格利雅试剂(其中X为氯,溴或碘)与具有以下结构的camp氧化物反应的方法制得的:其异构体:通过“外部”camp oxide或“内 氧化camp oxide oxide or:camp camp camp camp camp camp camp camp camp camp camp camp:::::::::::::::::