摘要:
CRUDE AMORPHOUS POLYOLEFINS, BY-PRODUCTS OF POLYOLEFIN PRODUCTION, CONTAIN QUANTITIES OF CATALYST RESIDUES INCLUDING DISCOLORING AGENTS SUCH THAT THE CRUDE MATERIAL IS DARK, HIGHLY VISCOUS-TO-SOLIDS, FLAMMABLE AND CORROSIVE WASTE. BY TREATING THE CRUDE PRODUCT IN A LIQUID TWOPHASE PURIFICATION PROCESS, THE AMORPHOUS POLYOLEFIN IS SEPARATED AND RECOVERED AS A USABLE, SAFE-TO-HANDLE, ESSENTIALLY COLOR FREE, MATERIAL. THE CATALYST RESIDUE ALSO IS RECOVERED.
摘要:
TITANIUM TRICHLORIDE FOR USE AS CATALYST COMPONENT IN STEREOREGULAR OLEFIN POLYMERIZATION IS PREPARED BY GRADUAL ADDITION OF A SOLUTION OF TITANIUM TETRACHLORIDE IN INERT DILUENT TO A SOLUTION OF TRIALKYL ALUMINUM IN INERT DILUENT. THE MIXTURE IS PREPARED AND HELD AT A TEMPERATURE BELOW -30*C. AND MOST ADVANTAGEOUSLY BELOW -50*C. UNTIL ADDITION IS COMPLETE, IS THEREAFTER GRADUALLY WARMED UP TO NOT ABOVE 80*C. UNTIL CONVERSION TO TICL3 IS COMPLETE, AND IS THEN HEATED TO AN ELEVATED TEMPERATURE AT WHICH THE TICL3 IS CONVERTED TO THE VIOLET FORM.
摘要:
THE IMPROVEMENT IN A PROCESS FOR RECOVERING DEASHING SOLVENT FROM A MIXTURE OF A SOLVENT CONTAINING CATALYST AND POLYMERIC RESIDUES COMPRISES SEPARATING BOTTOMS RECOVERED FROM A VAPORIZATION SYSTEM IN A HEAT TREATMENT ZONE IN THE ABSENCE OF FLUX MEDIUM AT TEMPERATURES OF ABOVE ABOUT 300*F. WITH AGITATION INTO RESIDUE AND SOLVENT, REMOVING THE RESIDUE TO STORAGE AND RECOVERING FROM THE ZONE THE SOLVENT WHICH CONTAINS SUBSTANTIALLY ALL OF THE SOLVENT IN THE BOTTOMS FED TO THE ZONE. THE RESIDUE CONTAINS A PREDOMINANT AMOUNT OF AMORPHOUS POLYMERIC MATERIALS WHICH IS OF COMMERCIAL VALUE.