公开(公告)号：US3676512A

公开(公告)日：1972-07-11

申请号：US3676512D

申请日：1971-01-22

Applicant: SNAM PROGETTI

Inventor： ARRIGHETTI SERGIO ,  VAJNA EUGENIO ,  CESCA SEBASTIANO

IPC: C08F210/00 ,  C07C1/00 ,  C07C1/32 ,  C07C2/50 ,  C07C13/28 ,  C07C13/43 ,  C07C35/29 ,  C07C45/69 ,  C07C47/445 ,  C07C67/00 ,  C08F36/00 ,  C08F210/16 ,  C07C5/24

CPC classification number: C07C47/445 ,  C07C1/326 ,  C07C2/50 ,  C07C13/42 ,  C07C13/43 ,  C07C35/29 ,  C07C45/69 ,  C07C2601/10 ,  C07C2601/14 ,  C07C2601/16 ,  C07C2602/42

Abstract: There are provided novel triene hydrocarbons, having at least two conjugated double bonds, and being of the general formula IN WHICH A is a radical consisting of a ring containing an endomethylene group; B may be both a linear alkadiene radical and a substituted and unsubstituted alkene or cycloalkene radical; Ro may be hydrogen, an aryl or an alkyl radical, n is a number ranging from 0 to 3; and m is 0 or 1. If n is not 0, m is 0; if n is 0, m is 0 or 1.

Abstract translation: 提供了具有至少两个共轭双键的新型三烯烃，并具有通式为A，其中A是由含有内亚甲基的环组成的基团; B可以是线性链二烯基团和取代和未取代的烯烃或环烯烃基团; Ro可以是氢，芳基或烷基，n是0-3的数; m为0或1.如果n不为0，则m为0; 如果n为0，m为0或1。

公开(公告)号：US3646105A

公开(公告)日：1972-02-29

申请号：US3646105D

申请日：1969-12-18

Applicant: SNAM PROGETTI

Inventor： CESCA SEBASTIANO ,  ROGGERO ARNALDO ,  PRIOLA ALDO ,  CINELLI ERMANNO

IPC: C07C1/32 ,  C07C13/32 ,  C07C13/68 ,  C07C13/28

CPC classification number: C07C13/68 ,  C07C1/328 ,  C07C13/32 ,  C07C2601/10 ,  C07C2602/42 ,  C07C2603/86

Abstract: NEW TERMONOMERS ARE DISCLOSED WHICH ARE REPRESENTED BY THE FORMULA:

A-(CH2)N)-

WHEREIN A IS A RADICAL INCLUDING AT LEAST ONE RING HAVING AN ENDOMETHYLENE GROUP, B IS A CYCLODIENE RADICAL AND N IS 0-5.

公开(公告)号：US3676510A

公开(公告)日：1972-07-11

申请号：US3676510D

申请日：1971-01-22

Applicant: SNAM PROGETTI

Inventor： ARRIGHETTI SERGIO ,  VAJNA EUGENIO ,  CESCA SEBASTIANO

IPC: C07C13/43 ,  C07C5/24

CPC classification number: C07C13/43 ,  C07C2602/42

Abstract: Triene hydrocarbons containing two conjugated double bonds, represented by the formula:
WHEREIN R1, R2, R3, R4, R and R'' may be hydrogen, alkyl or aryl radicals, and which may be prepared through a Diels-Alder reaction between a cyclopentadiene and (a) a dihalide-alkenyl compound, followed by dehydrohalogenation with basic agents, or (b) esters of fumaric or maleic acid, followed by reaction with a Grignard''s reagent and then by dehydration of the alcohol, are disclosed.

Abstract translation: 含有两个共轭双键的三烯烃，由下式表示：

公开(公告)号：US3668156A

公开(公告)日：1972-06-06

申请号：US3668156D

申请日：1970-04-23

Applicant: SNAM PROGETTI

Inventor： CORRADINI GIORGIO ,  GHETTI GIUSEPPE ,  CESCA SEBASTIANO ,  ROGGERO ARNALDO

IPC: C08F210/00 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L23/16 ,  C08L33/00 ,  C08L33/02 ,  C08L101/00 ,  C08F17/00

CPC classification number: C08F210/00 ,  C08K3/04 ,  C08K3/06 ,  C08K3/22 ,  C08K5/0025 ,  C08K5/09 ,  C08L23/16 ,  C08L53/02 ,  C08L91/00 ,  C08L2312/00 ,  C08L2666/04

Abstract: A terpolymer-diene composition that is readily curable with conventional vulcanizing agents is provided by preparing a mixture of diene polymer or copolymer with an olefinic terpolymer which includes at least one GROUP DIRECTLY BOUND TO TWO CARBON ATOMS, EACH OF WHICH IS CHARACTERIZED BY ETHYLENIC UNSATURATION, WHEREIN R1 is a hydrocarbon radical.

Abstract translation: 通过制备二烯聚合物或共聚物与烯属三元共聚物的混合物可以提供易于用常规硫化剂固化的三元共聚物 - 二烯组合物，该烯烃三元共聚物包括至少一个直接连接到两个碳原子的组，每个二氧化碳单元由乙烯不均匀性表征， 其中R1是烃基。

公开(公告)号：US3654246A

公开(公告)日：1972-04-04

申请号：US3654246D

申请日：1968-08-06

Applicant: SNAM PROGETTI

Inventor： MARCONI WALTER ,  ROGGERO ARNALDO ,  CESCA SEBASTIANO

IPC: C08F279/02 ,  C08F10/00 ,  C08F210/00 ,  C08F17/00

CPC classification number: C08F210/00 ,  C08F10/00 ,  C08F4/00

Abstract: NOVEL VULCANIZABLE AMORPHOUS TERPOLYMERS ARE DISCLOSED WHICH COMPRISE TWO ALPHA-OLEFINS AND A POLYENE CONTAINING AN ALKYLIDENE GROUP CONJUGATED WITH A DOUBLE BOND OF A RING WHICH IS A MEMBER OF AN ENDOCYCLIC SYSTEM. THE PROCESS FOR PREPARING THESE TERPOLYMERS IS ALSO DISCLOSED.

公开(公告)号：US3896097A

公开(公告)日：1975-07-22

申请号：US35208473

申请日：1973-04-17

Applicant: SNAM PROGETTI

Inventor： PRIOLA ALDO ,  CESCA SEBASTIANO ,  FERRARIS GIUSEPPE

IPC: C08F4/00 ,  C08F4/24 ,  C08F4/42 ,  C08F10/00 ,  C08F210/12 ,  C08D1/26 ,  C08D3/04 ,  C08F3/14

CPC classification number: C08F10/00 ,  C08F4/14

Abstract: A method is disclosed for the polymerization of isobutylene and, in particular, the copolymerization of isobutylene and isoprene, by contacting the monomers with a catalyst system constituted by (a) an organoaluminum compound (e.g., Al(C2H5)2Cl) and (b) an oxide or anhydride of an element belonging to Group VI B or VII B of the periodic system (e.g., SO2), in a liquid reaction medium, wherein the molar ratio of compound (b) to compound (a) is less than 1, at a temperature in the range of about -40* to +15*C.

公开(公告)号：US3657204A

公开(公告)日：1972-04-18

申请号：US3657204D

申请日：1969-12-18

Applicant: SNAM PROGETTI

Inventor： CESCA SEBASTIANO ,  ROGGERO ARNALDO ,  CINELLI ERMANNO

IPC: C08F10/00 ,  C08F210/00 ,  C08F5/00

CPC classification number: C08F210/00 ,  C08F10/00 ,  C08F4/00

Abstract: A NEW AMORPHOUS OLEFINIC TERPOLYMER THAT IS READILY CURABLE, AND WHICH MAY BE PREPARED BY POLYMERIZING A MIXTURE OF TWO DIFFERENT ALPHA-OLEFINS HAVING UP TO TEN CARBON ATOMS AND A POLYCYCLIC POLYENE REPRESENTED BY THE FORMULA A-(CH2)N-B WHEREIN A IS A RADICAL COMPRISING AT LEAST ONE RING HAVING AN ENDROMETHYLENE GROUP, B IS A CYCLODIENE RADICAL AND N IS 0 TO 5, IS DISCLOSED.

公开(公告)号：US3591648A

公开(公告)日：1971-07-06

申请号：US3591648D

申请日：1968-03-11

Applicant: SNAM PROGETTI

Inventor： MARCONI WALTER ,  CESCA SEBASTIANO ,  ROGGERO ARNALDO

IPC: C07C2/50 ,  C07C13/465 ,  C07C13/547 ,  C07C13/61 ,  C07C35/27 ,  C08F210/00 ,  C07C13/28

CPC classification number: C07C35/27 ,  C07C2/50 ,  C07C13/465 ,  C07C13/547 ,  C07C13/61 ,  C07C2602/24 ,  C07C2603/14 ,  C07C2603/68 ,  C08F210/00

Abstract: A PROCESS FOR THE MANUFACTURE OF ORTHOCONDENSED POLYCYCLIC POLYENE CONDENSATION PRODUCTS WHICH COMPRISES CONDENSING A CONJUGATED DIENE COMPOUND AND A FULVENE DERIVATIVE AT A TEMPERATURE BETWEEN 100 TO 250* C., THE MOLE-RATIO OF DIENE/FULVENE BEING AT LEAST ONE IS DISCLOSED.

公开(公告)号：US3903061A

公开(公告)日：1975-09-02

申请号：US36918373

申请日：1973-06-12

Applicant: SNAM PROGETTI

Inventor： CESCA SEBASTIANO ,  GHETTI GIUSEPPE ,  VAJNA EUGENIO ,  BRUZZONE MARIO ,  CINELLI ERMANNO

IPC: C08F4/00 ,  C08F4/60 ,  C08F4/619 ,  C08F210/00 ,  C08F210/16 ,  C08L21/00 ,  C08F17/00 ,  C08F1/34

CPC classification number: C08F210/00 ,  C08L21/00 ,  C08L2666/06

Abstract: Vulcanizable olefin tetrapolymers are described which are comprised of ethylene, an alpha-olefin having at least three carbon atoms, at least one conventional terpolymer such as endoand exo-dicyclopentadiene, and a minor amount of a polycyclic polyene represented by the formula A-(CH2)n-B, wherein A is a radical consisting of or containing at least one cyclohexane ring with or without an endomethylene bridge, B is a cyclodiene radical and n is a number ranging from 0 to 5.

Abstract translation: 描述了由乙烯，具有至少三个碳原子的α-烯烃，至少一种常规三元共聚物如内 - 和二 - 二环戊二烯组成的可硫化烯烃四元共聚物和少量由式A- （CH2）nB，其中A是具有或不具有至少一个环己烷环或具有内亚甲基桥的基团，B是环二烯基，n是0至5的数。

公开(公告)号：US3892712A

公开(公告)日：1975-07-01

申请号：US27593672

申请日：1972-07-28

Applicant: SNAM PROGETTI

Inventor： ARRIGHETTI SERGIO ,  CESCA SEBASTIANO ,  GHETTI GIUSEPPE ,  VAJNA EUGENIO

IPC: C08F8/00 ,  C08F8/32 ,  C08F8/34 ,  C08F15/40 ,  C08F27/18

CPC classification number: C08F8/34 ,  C08F210/18 ,  C08F8/00

Abstract: A method is described whereby olefin terpolymers, consisting of ethylene, an alpha olefin and a polyene having in the molecule, in addition to the double bond participating in the formation of the macromolecule, at least one conjugated double bond system, are stabilied against oxidative aging without destroying their characteristic high vulcanization rate by reacting them with a dienophilic agent represented by one of the following formulae:

WHEREIN R and R6 may be an alkyl, alkenyl, cycloalkyl, aryl or aralkyl radical having up to 8 carbon atoms, R1, R2, R3, R4 and R5 may be hydrogen or alkyl, aryl, cycloalkyl or aralkyl radicals having up to 8 carbon atoms, the R1-R2 and R-R pairs may be divalent radicals forming condensed rings.

Abstract translation: 描述了一种方法，其中由乙烯，α-烯烃和分子内具有多键的烯烃三元共聚物除了参与高分子形成的双键之外，还具有至少一个共轭双键体系，以抵抗氧化老化 通过使它们与由下式表示的二亲性剂反应而破坏它们的特征性高硫化速率：WHEREIN R和R 6可以是具有至多8个碳原子的烷基，烯基，环烷基，芳基或芳烷基，R 1，R 2， R3，R4和R5可以是氢或具有至多8个碳原子的烷基，芳基，环烷基或芳烷基，R1-R2和RR对可以是形成稠环的二价基团。