Abstract:
Curable composition comprising a stable, water dispersible, curable polymer containing a sterically hindered alkoxylated silane group at 0.1 to 75 weight percent of the total composition; a water dispersible or water soluble, hydrolytically stable organometallic catalyst, at 0.1 to 10 weight percent of the total composition; and water at 99.8 to 24.9 weight percent of the total composition are taught herein. These compositions are useful as adhesives, sealants and paints. The compositions have improved properties including solvent resistance, adhesion, hardness, abrasion resistance and mar resistance.Particular catalysts for use herein include dihydroxy bis [2-hydroxypropanato (2-)-O.sup.1,O.sup.2 ] titanate, mixed titanium ortho ester complexes, acetylacetonate chelate, bis(ethyl-3-oxobutanolato-O.sup.1,O.sup.3) bis(2-propanolato) titanium, alkanolamine complex of titanium and mercaptoalcohol, mercaptide or sulfide forms of diorganotins having either a Sn--S or Sn.dbd.S bond.
Abstract:
Aqueous emulsions are disclosed containing organosilicon compounds for the impregnation of inorganic materials, in particular building materials, containing alkoxysilanes and silane surfactants. The emulsions comprise 1-80% by weight of one alkoxy silane, ##STR1## X.dbd.H,cl,Br, I, NH.sub.2, SCN, CN, N.sub.3, NHR, NR, NR.sub.3, --S.sub.x --, aryl or alkenyla.dbd.0 or 1b.dbd.1 or 2and, 1-30% of an organosilicon compound ##STR2##
Abstract:
Improved primer compositions comprise (A) at least one member of a specified group of ethylenically unsaturated organosilicon compounds containing silicon-bonded alkoxy groups, (B) silicone/organic copolymers prepared from esters of ethylenically unsaturated organic acids and organosilicon compounds derived from these acids, (C) organohydrogensiloxane curing agents and (D) a solvent. The improvement resides in the presence in the solvent of an ethylenically unsaturated alcohol containing from 4 to 6 carbon atoms. The alcohol constitutes at least 50 percent by weight of the solvent.
Abstract:
A moisture curable composition comprising (I) a hydrolyzable silyl group-containing vinyl polymer and (II) a combined curing catalyst system of (a) an organic phosphorus-containing compound such as an organic acid phosphate, an organic acid phosphite, or an acid titanium phosphate such as those known as titanate coupling agent and (b) an amine compound. The composition has well balanced pot life and curability and provides a cured product having an excellent appearance, and the curability can be arbitrarily controlled according to the purposes by selecting the ratio of the components (a) and (b).
Abstract:
A component A, including at least one organic silane-group-containing polymer, at least one drying agent, at least one amine having at least one free amino group or latent amino group releasable via hydrolysis, at least one hydrolysable silane without an amino group, and at least one catalyst for crosslinking silane-functional polymers; and including a component B, including between 1 and 75 wt. % water dispersed in a mixture together with filler and/or plasticiser and further additives; and including further additives in component A and/or component B, from the group of fillers; wherein the catalyst is a tin complex having two mercaptide ligands according to formula (V), where ligands L1 independently represent sulfur-coordinated alkyl mercaptides, where ligands L1 include methyl dialkoxysilane groups, methyl dimethoxysilane groups, and ligands L2 independently represent alkyl ligands. The composition allows an exceptionally long pot time and simultaneously very rapid curing and excellent storage stability.
Abstract:
The purpose of the present invention is to provide a thermally conductive moisture-curable resin composition which develops excellent thermal conductivity and peelability after curing. The thermally conductive moisture-curable resin composition contains the following components (A) to (C):
component (A): an organic polymer containing two or more hydrolyzable silyl groups; component (B): a thermally conductive filler; and component (C): a silicone compound having a polar group and/or a polar chain at a terminal or a side chain.
Abstract:
The purpose of the present invention is to provide a thermally conductive moisture-curable resin composition which develops excellent thermal conductivity and peelability after curing. The thermally conductive moisture-curable resin composition contains the following components (A) to (C):
component (A): an organic polymer containing two or more hydrolyzable silyl groups; component (B): a thermally conductive filler; and component (C): a silicone compound having a polar group and/or a polar chain at a terminal or a side chain.
Abstract:
A liquid composition is disclosed. The liquid composition comprises a silicone-acrylate polymer. The silicone-acrylate polymer comprises acrylate-derived monomeric units comprising siloxane moieties, optionally epoxide-functional moieties, and optionally, hydrocarbyl moieties. A method of preparing the silicone-acrylate polymer and the liquid composition is also disclosed.
Abstract:
The invention described herein generally pertains to a composition that includes a silyl-terminated polymer having silyl groups linked to a polymer backbone via triazole. The silyl-terminated polymer is a reaction product of a functionalized polymer backbone and a functionalized silane. The polymer backbone includes a first functional group, which may be one of an azide or an alkyne. The functionalized silane includes a second functional group may also be one of an azide or an alkyne, but is also different from the first functional group. The functionalized polymer backbone is reacted with the functionalized silane in the presence of a metal catalyst.
Abstract:
The invention described herein generally pertains to a composition that includes a silyl-terminated polymer having silyl groups linked to a polymer backbone via triazole. The silyl-terminated polymer is a reaction product of a functionalized polymer backbone and a functionalized silane. The polymer backbone includes a first functional group, which may be one of an azide or an alkyne. The functionalized silane includes a second functional group may also be one of an azide or an alkyne, but is also different from the first functional group. The functionalized polymer backbone is reacted with the functionalized silane in the presence of a metal catalyst.