摘要:
A solid polymer electrolyte comprising a composite of (a) a polymeric component which comprises (i) a polymer obtained from at least one compound represented by general formula (IA), (IIA) and/or (IIIA) as described in the specification; or (ii) a polymer obtained from at least one compound having alcoholic hydroxyl groups wherein at least one hydrogen atom of said alcoholic hydroxyl groups is replaced by a unit represented by general formula (X) or (XI) as described in the specification, and (b) at least one electrolyte salt, which has a high ionic conductivity and can be made into a thin film. The present invention is also directed to an electrode comprising the solid polymer electrolyte and an electroactive substance or polarizable material; as well as a process for manufacturing the same. In addition, the present invention is directed to a primary an secondary battery having the solid polymer electrolyte, as well as a process for manufacturing the same. The battery of the present invention has a high capacity, high current density, and, in the case of a secondary battery, has good cyclability. Finally, the present invention is directed to a solid-state electric double layer capacitor comprising the solid polymer electrolyte, as well as a process for manufacturing the same. The electric double layer capacitor has a high output voltage and a large take-out current.
摘要:
Ultracapacitor and supercapacitor designs wherein two discrete metal film current collectors of the prior art, one for each of the cathode and anode, are replaced by a single thin polymer film. The polymer film is typically several microns thick and metallized on both sides. The thickness of the metallization is varied from several hundred to several thousand .ANG.ngstroms depending upon the particular application. This metallization serves as the positive and negative electrodes (current collectors) which are spatially separated by the polymer dielectric film. The resulting reduction of volume increases the volumetric energy density and the reduction of mass increases the gravimetric energy density. The electrolyte solvent/salt system can be selected to provide useful individual cell voltages as high as 5 volts. The voltage is limited only by the electrolytic stability of the solvent and salt. Ultracapacitors fabricated in accordance with the present invention may have energy densities exceeding 10 watt-hours per kilogram and volumetric energy densities exceeding 15 watt-hours per liter. Values which are yet higher are feasible with supercapacitors fabricated in accordance with the present invention.
摘要:
An electric double layer capacitor utilizing an electric double layer formed by the interface of an electrolyte solution and polarizable electrodes, wherein the electrolyte solution comprises a solute dissolved in at least one solvent selected from the group consisting of sulfolane and a derivative thereof.
摘要:
The present invention provides an electric double layer capacitor having a high withstanding voltage, less deterioration, and excellent long-term reliability, especially an effect of suppressing expansion. The present invention relates to an electrolyte solution for an electric double layer capacitor. The solution comprises an electrolyte-salt-dissolving solvent (I) and an electrolyte salt (II). The electrolyte-salt-dissolving solvent (I) contains a fluorine-containing chain ether and a nitrile compound.
摘要:
Super capacitor including a gel electrolyte and manufacturing method thereof are provided. The gel electrolyte is one selected from a group consisting of a P(AN-EG-AN) copolymer, a P(AN-EG) copolymer, a P(EG-AN-EG) copolymer and a combination thereof.
摘要:
A quaternary ammonium salt of the formula (1), a composition containing the quaternary ammonium salt and an organic solvent, and an electrochemical device using the salt wherein R1 and R2 are both methyl and X− is BF4− or N(CF3SO2)2−.
摘要:
To provide an electrolyte solution, which contains an electrolyte compound, a molecular structure of which contains a molecular chain containing a repeating unit of alkylene oxide, and contains quaternary ammonium cations at both terminals of the molecular chain.
摘要:
A flexible supercapacitor and a preparation method thereof are provided. The flexible supercapacitor includes a polymer-based solid electrolyte layer, two active layers respectively disposed on opposite surfaces of the polymer-based solid electrolyte layer, and two electron conducting layers disposed on outer exposed surfaces of the two active layers.
摘要:
The invention relates to a chemically gelled curable resin based on epoxy-amine resins and on ionic liquids. The invention advantageously applies to energy accumulation systems, notably electrochemical systems. The curable composition according to the invention can notably constitute an electrolyte usable in a hybrid or electric vehicle battery.
摘要:
A nonaqueous solvent for an electrical storage device according to the present invention includes fluorine-containing cyclic saturated hydrocarbon having a structure represented by the following general formula (1) in which one or two substituents R are introduced into a cyclohexane ring; a compound having a relative dielectric constant of 25 or higher; and a chain carbonate (in general formula (1), R is represented by CnX2n+1 where n is an integer of 1 or greater, at least one of (2n+1) pieces of X's is F, and the other X's are H).
摘要翻译:根据本发明的蓄电装置用非水溶剂包括其中一个或两个取代基R被引入环己烷环中的具有由以下通式(1)表示的结构的含氟环状饱和烃; 相对介电常数为25以上的化合物, 和链状碳酸酯(通式(1)中,R由C n X 2n + 1表示,其中n为1以上的整数,X 2的(2n + 1)个中的至少一个为F,另外X为H )。