摘要:
Disclosed herein are compositions, comprising linear polydiorganosiloxanes having enhanced reactivity and their use to prepare polydiorganosiloxane-polyorgano block copolymers.
摘要:
Disclosed herein is a flame retardant composition comprising 20 to 80 weight percent of a polycarbonate; 1 to 20 weight percent of a laser activatable additive; the laser activatable additive being operative to plate the flame retardant composition upon being activated by a laser; and 1 to 20 weight percent of a phosphazene compound; where all weight percents are based on the total weight of the flame retardant composition. Disclosed herein too is a method comprising blending 20 to 80 weight percent of a polycarbonate; 1 to 20 weight percent of a laser activatable additive; the laser activatable additive being operative to plate the flame retardant composition upon being activated by a laser; and 1 to 20 weight percent of a phosphazene compound to produce a flame retardant composition; where all weight percents are based on the total weight of the flame retardant composition; and extruding the flame retardant composition.
摘要:
A composition comprises a first polycarbonate having a limited oxygen index of greater than 26% measured according to ISO 4589 on a 4 mm thick plaque, wherein an article molded from the first polycarbonate has a smoke density after 4 minutes (DS-4) of greater than 600 determined according to ISO 5659-2 on a 3 mm thick plaque at 50 kW/m2; and a second polymer different from the first polycarbonate, the second polymer comprising a poly(carbonate-siloxane) copolymer, a polydialkylsiloxane, or a combination comprising at least one of the foregoing; wherein an article molded from the second polymer has a smoke density after 4 minutes (DS-4) of greater than 600 determined according to ISO 5659-2 on a 3 mm thick plaque at 50 kW/m2; wherein an article molded from the composition has a smoke density after 4 minutes (DS-4) of smaller than 480 determined according to ISO 5659-2 on a 3 mm thick plaque at 50 kW/m2.
摘要翻译:组合物包含在4mm厚的板上根据ISO 4589测量的具有大于26%的有限氧指数的第一聚碳酸酯,其中由第一聚碳酸酯模制的制品在4分钟后具有烟密度(DS-4)较大 超过600根据ISO 5659-2确定,厚度为3毫米,厚度为50千瓦/平方米; 和不同于第一聚碳酸酯的第二聚合物,第二聚合物包含聚(碳酸酯 - 硅氧烷)共聚物,聚二烷基硅氧烷或包含前述的至少一种的组合; 其中由第二聚合物成型的制品在50kW / m 3的3mm厚的板上具有大于600°的根据ISO 5659-2测定的4分钟(DS-4)之后的烟雾浓度; 其中由所述组合物模制的制品在50kW / m 2的3mm厚的板上具有根据ISO 5659-2测定的小于480的4分钟后的烟浓度(DS-4)。
摘要:
Thermoplastic resin polymer compositions having a block of random polysiloxane co- or terpolymer structure, such as substituted phenyl-terminated polysiloxane co- or terpolymers having the general structure: provide improved flame resistance, optical clarity, and better low-temperature impact strength compared to conventional blends, additives, and copolymers. The substituted phenyl terminated polysiloxanes may be used to make various polysiloxane-thermoplastic resin polymer and polymer blends, as well as articles including such polysiloxane-thermoplastic resin polymer and blends.
摘要:
Disclosed herein are methods and compositions polycarbonate blend compositions with improved appearance characteristics and impact characteristics. The resulting compositions, comprising a polycarbonate polymer, a first polysiloxane-polycarbonate copolymer, a second polysiloxane-polycarbonate copolymer, and optionally a color composition, can be used in the manufacture of articles while still retaining advantageous mechanical properties, melt flow properties, and appearance characteristics such as the ability to achieve deep black and bright white colors. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.
摘要:
The invention is directed to phenyl-containing functional polysiloxanes and polycarbonate-polysiloxane copolymer compositions made therefrom having improved optical clarity and better low temperature impact resistance.
摘要:
A polycarbonate polymer or copolymer comprising pendant silylated dihydroxy aromatic compound of the formula (1a); wherein Ga and Gb are each independently C1-12 alkyl, —OSi(C1-12 alkyl)3, C1-12 arylalkyl, or —OSi(C1-12 arylalkyl)3; Za and Zb are each independently a straight or branched C2-18 is alkylene, a C8-18 arylalkylene, or a C8-18 alkylarylene, Xa is a direct bond, a heteroatom-containing group, or a C1-18 organic group, and r and s are each independently 1 or 2 is disclosed.
摘要:
A copolycarbonate composition is provided comprising a blend of a polycarbonate-polysiloxane copolymer and a terephthalate polymer. The blend has a combination of good melt volume rate, good fatigue resistance, and high ductility at low temperatures.
摘要:
Embodiments of the present invention provide various multipolymers and permselective membranes for use with biosensors and other implantable medical devices and prostheses. Embodiments of the present invention may provide structural strength and integrity, and further may control the influx of glucose, oxygen and/or water. Embodiments of the present invention may, for example, minimize or reduce the influx of glucose by minimizing the percentage of hydrophilic segments, which in turn minimizes the percentage of water uptake and the degree of glucose transport.
摘要:
Copolyorganosiloxanecarbonates are prepared by first preparing an oligomeric aromatic polycarbonate, such as an oligomeric bisphenol A polycarbonate, in the presence of a tertiary amine as the only catalyst species; contacting the oligomeric polycarbonate mixture with a polyorganosiloxane bis(aryl)chloroformate, such as the bischloroformate of hydroxy-terminated eugenol polydimethylsiloxane; and introducing phosgene and/or chain termination agent either continuously or in stages. A feature of the process is the presence of dihydroxyaromatic compound in only one charge, at the beginning. The products have excellent physical properties, including transparency.