公开(公告)号：US07649052B2

公开(公告)日：2010-01-19

申请号：US11596503

申请日：2005-05-04

Applicant: Paola Massari ,  Jean News ,  Marco Ciarafoni

Inventor： Paola Massari ,  Jean News ,  Marco Ciarafoni

IPC: C08L23/00 ,  C08L23/16 ,  C08L23/10 ,  C08F297/08

CPC classification number: C08L23/12 ,  C08L23/06 ,  C08L23/0807 ,  C08L23/10 ,  C08L23/14 ,  C08L23/16 ,  C08L2205/02 ,  C08L2314/02 ,  C08L2666/06

Abstract: A heterophasic polyolefin composition comprising: (A) 50-0% of a crystalline propylene polymer; (B) 5-20% of a first elastomeric copolymer of ethylene with at least a C3-C8 α-olefin comonomer; and (C) 10-45% of a second elastomeric copolymer of ethylene with at least a C3-C8 α-olefin comonomer; wherein the ratio between the ethylene content of the fraction insoluble in xylene at room temperature (C2xif) multiplied by the weight percentage of the fraction insoluble in xylene at room temperature (% XIF) and the ethylene content of the fraction soluble in xylene at room temperature (C2xsf) multiplied by the weight percentage of fraction soluble in xylene at room temperature (% SXF) satisfies the following relation (I): C 2 ⁢ xif × % ⁢ XIF C 2 ⁢ xsf × % ⁢ SXF > 0.01 ⁢ x + 0.261 , wherein x is the total amount of ethylene.

Abstract translation: 多相聚烯烃组合物，其包含：（A）50-0％的结晶丙烯聚合物; （B）5-20％的乙烯与至少一种C 3 -C 8α-烯烃共聚单体的第一弹性体共聚物; 和（C）10-45％的乙烯与至少一种C 3 -C 8α-烯烃共聚单体的第二弹性体共聚物; 其中在室温下不溶于二甲苯的级分的乙烯含量（C2×10）乘以在室温下不溶于二甲苯的级分的重量百分比（％XIF）和在室温下可溶于二甲苯的级分的乙烯含量之比 （C2xsf）乘以在室温下可溶于二甲苯的馏分的重量百分比（％SXF）满足以下关系式（I）：C 2 xif x％XIF C 2 xsf x％SXF> 0.01x + 0.261 ，其中x是乙烯的总量。

公开(公告)号：US20090304968A1

公开(公告)日：2009-12-10

申请号：US11919094

申请日：2006-03-24

Applicant: Roberto De Palo ,  Mario Riccini

Inventor： Roberto De Palo ,  Mario Riccini

IPC: B32B1/08 ,  C08K3/26 ,  C08K3/34

CPC classification number: B32B1/08 ,  B32B3/30 ,  B32B27/08 ,  B32B27/20 ,  B32B27/32 ,  B32B2250/242 ,  B32B2264/104 ,  B32B2270/00 ,  B32B2307/54 ,  B32B2307/546 ,  B32B2307/558 ,  B32B2419/00 ,  B32B2597/00 ,  C08L23/10 ,  C08L23/16 ,  C08L2207/02 ,  Y10T428/13 ,  Y10T428/1303 ,  Y10T428/1352 ,  Y10T428/1359 ,  Y10T428/139 ,  Y10T428/1393 ,  C08L2666/06

Abstract: A single- or multilayer threaded pipe, wherein at least one layer is produced from a polyolefin composition comprising (percentages express on the basis of the sum of components (A) and (B)): (A) 65-90 wt % of a heterophasic polypropylene composition comprising (percentages expressed on the basis of the polypropylene composition): (1) 65-95 wt % of a propylene polymer selected from propylene homopolymer and co- and terpolymers of propylene with a comonomer selected from ethylene, a C4-C10 alpha-olefin and a mixture thereof, said polymer containing 0.1-10 wt % of comonomer units, being insoluble in xylene at 25° C. in an amount over 85 wt %, having a polydispersity index ranging from 4 to 13 and an intrinsic viscosity ([η]1) value of over 2.2 dl/g; and (2) 5-35 wt % of an olefin polymer of ethylene with propylene or a C4-C10 alpha-olefin having an ethylene content ranging from 15 to 85 wt % and an intrinsic viscosity of the fraction soluble in xylene ([η]2) of at least 1.4 dl/g; wherein the ratio of the intrinsic viscosity value of propylene polymer (1) to that of olefin polymer (2) ([η]/[η]2) ranges from 0.45 to 1.6; and (B) 10-35 wt % of a at least one filler selected among calcium carbonate, talc, wollastonite or mixtures thereof.

Abstract translation: 单层或多层螺纹管，其中至少一层由聚烯烃组合物制成，所述聚烯烃组合物包含（基于组分（A）和（B）的总和）的百分比）：（A）65-90重量％ 包含（基于聚丙烯组合物表示的百分比）的多相聚丙烯组合物：（1）65-95重量％的丙烯聚合物，其选自丙烯均聚物和丙烯与共聚单体的共聚和三元共聚物，所述共聚单体选自乙烯，C 4 -C 10 α-烯烃及其混合物，所述聚合物含有0.1-10重量％的共聚单体单元，其在25℃下不溶于二甲苯，其量为大于85重量％，多分散指数为4至13，特性粘度 （η1）值超过2.2dl / g; 和（2）5-35重量％的乙烯与丙烯或乙烯含量为15至85重量％的C 4 -C 10α-烯烃的烯烃聚合物和可溶于二甲苯的馏分的特性粘度（η 2）至少为1.4dl / g; 其中丙烯聚合物（1）的特性粘度值与烯烃聚合物（2）的特性粘度值（η/η2）的比例为0.45至1.6; 和（B）10-35重量％的选自碳酸钙，滑石，硅灰石或其混合物的至少一种填料。

公开(公告)号：US20090253868A1

公开(公告)日：2009-10-08

申请号：US11921097

申请日：2006-05-05

Applicant: Paola Massari ,  Marco Ciarafoni ,  Jean News

Inventor： Paola Massari ,  Marco Ciarafoni ,  Jean News

IPC: C08L23/16 ,  C08L23/12 ,  C08L23/06

CPC classification number: C08L23/10 ,  C08L23/14 ,  C08L2205/03 ,  C08L2666/06 ,  C08F210/06 ,  C08F4/6492 ,  C08F4/651 ,  C08F2/001

Abstract: A polypropylene composition comprising 65-77 wt % of a crystalline propylene polymer, 8 to less than 13 wt % of an elastomeric copolymer and 10-23 wt % of polyethylene. The said composition exhibits a flexural modulus value higher than 1300 MPa, stress-whitening resistance values corresponding to a diameter of the whitened area of at most 1.7 cm caused by a ram falling from a 76 cm height and a diameter of the whitened area of at most 1.2 cm caused by a ram falling from a 20 cm height, and a value of Izod impact resistance at 23° C. more than 14 kJ/m2 and the one at −20° C. at least 5 kJ/m2.

Abstract translation: 包含65-77重量％的结晶丙烯聚合物，8至小于13重量％的弹性体共聚物和10-23重量％的聚乙烯的聚丙烯组合物。 所述组合物显示高于1300MPa的弯曲模量值，对应于由高度76厘米的白垩层的直径和白色区域的白度范围 大约1.2厘米，由一个20厘米高的夯锤引起的，在23℃下的悬臂梁式冲击强度值大于14kJ / m 2，而在-20℃下的抗冲击强度值至少为5kJ / m 2。

公开(公告)号：US20090234083A1

公开(公告)日：2009-09-17

申请号：US11989384

申请日：2006-07-18

Applicant: Daniele Bigiavi ,  Giuseppe Penzo

Inventor： Daniele Bigiavi ,  Giuseppe Penzo

IPC: C08F2/04

CPC classification number: C08F10/00 ,  C08F110/08 ,  C08F2/06

Abstract: A solution process for polymerizing one or more α-olefins of formula CH2═CHR, where R is H or an alkyl radical C1-12, to produce a polymer that is soluble in the reaction medium, the process comprising: (a) polymerization in a solution phase of one or more α-olefins in the presence of an organo-aluminum compound and a catalyst system comprising a transition metal compound as the catalyst component; (b) the polymeric solution obtained from step a) is then pressurized and transferred by means of a screw pump to a successive step for removing the unreacted monomers from the polymer; wherein the pumping capacity of said screw pump is kept constant by adding the polymeric solution with water at a feeding point upstream the screw pump.

Abstract translation: 用于聚合一种或多种式CH 2 -CHR的α-烯烃（其中R是H或烷基C1-12）以产生可溶于反应介质的聚合物的溶液方法，该方法包括：（a） 在有机铝化合物存在下的一种或多种α-烯烃的溶液相和包含过渡金属化合物作为催化剂组分的催化剂体系; （b）然后通过螺杆泵将从步骤a）获得的聚合物溶液加压并转移到从聚合物中除去未反应单体的连续步骤; 其中所述螺杆泵的泵送能力通过在螺杆泵上游的进料点处加入聚合物溶液而保持恒定。

公开(公告)号：US20090209714A1

公开(公告)日：2009-08-20

申请号：US11887528

申请日：2006-03-15

Applicant: Giampiero Morini ,  Isabella Camurati ,  Tiziano Dall'Occo ,  Dario Liguori ,  Gianni Vitale

Inventor： Giampiero Morini ,  Isabella Camurati ,  Tiziano Dall'Occo ,  Dario Liguori ,  Gianni Vitale

IPC: C08F4/52 ,  B01J31/12 ,  B01J31/14

CPC classification number: C08F110/02 ,  C08F210/16 ,  C08F4/6565 ,  C08F4/6548 ,  C08F2500/12 ,  C08F210/08

Abstract: Catalyst components for the(co)polymerization of ethylene comprising Ti, Mg, halogen, ORI groups, where RI is a C1-C12 hydrocarbon group optionally containing heteroatoms, having ORI/Ti molar ratio in the range 0.1-1.5, a Mg/Ti molar ratio of less than 8, an amount of titanium, with respect to the total weight of said solid catalyst component, higher than 4% by weight characterized by a specific SS-NMR pattern are particularly useful for preparing narrow MWD crystalline ethylene polymers.

Abstract translation: 含有Ti，Mg，卤素，ORI基团的乙烯（共）聚合的催化剂组分，其中RI是任选含有杂原子的C 1 -C 12烃基，ORI / Ti摩尔比在0.1-1.5范围内，Mg / Ti 摩尔比小于8，相对于所述固体催化剂组分的总重量，钛的量高于4重量％，其特征在于特定的SS-NMR图案，特别适用于制备窄MWD结晶乙烯聚合物。

公开(公告)号：US20090156758A1

公开(公告)日：2009-06-18

申请号：US11992032

申请日：2006-09-15

Applicant: Joachim Pater T.M. ,  Pietro Baita ,  Gabriele Mei ,  Antonio Mazzucco

Inventor： Joachim Pater T.M. ,  Pietro Baita ,  Gabriele Mei ,  Antonio Mazzucco

IPC: C08F2/01 ,  B01J19/24

CPC classification number: B01J8/1827 ,  B01J8/002 ,  B01J8/0035 ,  B01J8/1872 ,  B01J19/2415 ,  B01J2208/00256 ,  B01J2208/00274 ,  B01J2208/0053 ,  B01J2208/00752 ,  B01J2219/00006 ,  B01J2219/00033 ,  B01J2219/0004 ,  C08F10/00 ,  C08F110/02 ,  C08F2/34 ,  C08F2/01 ,  C08F2500/05 ,  C08F2500/12 ,  C08F2500/24

Abstract: A process for the gas-phase polymerization of one or more alpha-olefins in the presence of a polymerization catalyst system, the process comprising: a) contacting in a continuous way a gas comprising one or more of said alpha-olefins with said catalyst system in a gas-phase tubular reactor at a temperature from 30° C. to 130° C. in order to obtain a polymerization degree up to 500 grams per gram of catalyst system; b) feeding in continuous the prepolymer from step a) to a successive gas-phase polymerization reactor; wherein said gas-phase tubular reactor has a length/diameter ratio higher than 100.

Abstract translation: 一种在聚合催化剂体系存在下气相聚合一种或多种α-烯烃的方法，该方法包括：a）以连续的方式使包含一种或多种所述α-烯烃的气体与所述催化剂体系 在气相管式反应器中，在30℃至130℃的温度下，以获得高达500克/克催化剂体系的聚合度; b）将预聚物从步骤a）连续进料到连续的气相聚合反应器; 其中所述气相管式反应器具有高于100的长度/直径比。

公开(公告)号：US20090048403A1

公开(公告)日：2009-02-19

申请号：US12086369

申请日：2006-11-07

Applicant: Enrico Costantini ,  Enrico Masarati

Inventor： Enrico Costantini ,  Enrico Masarati

IPC: C08L23/08 ,  C08L23/14

CPC classification number: B29B17/0042 ,  B29K2023/06 ,  B29K2023/083 ,  B29K2023/12 ,  C08J11/06 ,  C08J2323/02 ,  C08L23/08 ,  C08L23/10 ,  C08L23/14 ,  C08L23/142 ,  C08L23/16 ,  C08L2205/02 ,  Y02W30/62 ,  Y02W30/701 ,  Y10T428/1352 ,  Y10T428/1386 ,  Y10T428/31938 ,  C08L2666/06

Abstract: Polyolefin compositions comprising, by weight: A) 30-80% of a polyolefin component containing not less than 80% of a waste material selected from polyethylene, polypropylene or their mixtures; B) 20-70% of a heterophasic polyolefin composition having flexural modulus equal to or lower than 600 MPa.

Abstract translation: 聚烯烃组合物，其包含：A）30-80％的含有不少于80％的选自聚乙烯，聚丙烯或其混合物的废料的聚烯烃组分; B）具有等于或低于600MPa的挠曲模量的20-70％的异相聚烯烃组合物。

公开(公告)号：US07482411B2

公开(公告)日：2009-01-27

申请号：US10553476

申请日：2004-04-01

Applicant: Guiseppe Penzo ,  Gabriele Mei ,  Gerben Meier

Inventor： Guiseppe Penzo ,  Gabriele Mei ,  Gerben Meier

IPC: C08F2/34 ,  B01J19/24

CPC classification number: B01J8/1827 ,  B01J8/1872 ,  B01J2208/00256 ,  B01J2208/00274 ,  B01J2208/003 ,  C08F10/00 ,  Y10S526/901 ,  Y10S526/918 ,  C08F2/01 ,  C08F2/34

Abstract: A continuous process for the olefin polymerization in a fluidized bed reactor, said process comprising continuously passing a gaseous stream comprising one or more α-olefin monomers through the fluidized bed in the presence of a polymerization catalyst under reactive conditions, withdrawing polymeric product and unreacted fluids from the reactor, cooling part of said unreacted fluids below the dew point to form a two-phase mixture of gas and condensed liquid and reintroducing said two-phase mixture into the reactor, the process being characterized in that said two-phase mixture is reintroduced under the distribution plate of the reactor so that a part of condensed liquid is separated from the gas and is successively fed above the fluidized bed through an external pipe connecting the bottom of the reactor to a point situated above the upper limit of the fluidized bed of polymer particles.

Abstract translation: 在流化床反应器中烯烃聚合的连续方法，所述方法包括在反应条件下，在聚合催化剂存在下连续地通过包含一种或多种α-烯烃单体的气流通过流化床，将聚合物和未反应的流体 将来自反应器的所述未反应流体的一部分冷却至低于露点以形成气体和冷凝液体的两相混合物，并将所述两相混合物重新引入反应器，其特征在于所述两相混合物被重新引入 在反应器的分配板下方，使得一部分冷凝液体与气体分离，并且通过将反应器底部连接到位于流化床上限以上的点的外部管连续地供入流化床上方 聚合物颗粒。

公开(公告)号：US20080182941A1

公开(公告)日：2008-07-31

申请号：US11982705

申请日：2007-11-01

Applicant: Angelo Ferraro ,  Tiziano Dall'Occo ,  Giuliano Cecchin

Inventor： Angelo Ferraro ,  Tiziano Dall'Occo ,  Giuliano Cecchin

IPC: C08F210/00 ,  C08L23/00

CPC classification number: C08L23/0815 ,  C08F10/00 ,  C08F210/00 ,  C08F210/16 ,  C08F255/00 ,  C08F255/02 ,  C08L23/10 ,  C08L23/16 ,  C08L51/06 ,  C08L2314/02 ,  C08F4/6555 ,  C08F4/6494 ,  C08F4/651 ,  C08L2666/06 ,  C08L2666/02 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/08 ,  C08F2500/20 ,  C08F2500/11 ,  C08F210/06 ,  C08F2500/17 ,  C08F2500/04

Abstract: A polyolefin composition, comprising: (A) from 5 to 95 parts by weight of a crystalline propylene polymer having an isotactic index greater than 80, selected from polypropylene homopolymer and propylene copolymers containing 0.5 to 15 mol % of ethylene and/or an α-olefin having 4 to 10 carbon atoms, and (B) from 5 to 95 parts by weight of an ethylene/α-olefin copolymer containing from 35 to 70% by weight of ethylene, from 30 to 65% by weight of an olefin CH2═CHR, in which R a hydrocarbyl radical with 1-12 carbon atoms, and from 0 to 10% of a polyene characterized by (i) a Molecular Weight Distribution expressed by Mw/Mn of higher than 3, (ii) a content of 2-1 regioinvertions of the α-olefin units of lower than 5% and (iii) a value of Shore A and content by weight of ethylenic units, calculated on the basis of the whole polymer, such that the point defined by such values falls below the curve defined by the following equation: Y=0.0438X2-4.1332X+A where Y is the value of the Shore A, X is the weight percentage of ethylene units in the polymer calculated by NMR and A is 145.

Abstract translation: 一种聚烯烃组合物，其包含：（A）5至95重量份的全同立构指数大于80的结晶丙烯聚合物，其选自聚丙烯均聚物和含有0.5至15摩尔％乙烯和/或α-烯烃的丙烯共聚物， 具有4至10个碳原子的烯烃，和（B）5至95重量份的含有35至70重量％乙烯的乙烯/α-烯烃共聚物，30至65重量％的烯烃CH 2， 其中R 1具有1-12个碳原子的烃基和0至10％的多烯，其特征在于（i）由Mw / Mn表示的分子量分布高于3 ，（ii）α-烯烃单元的2-1区域转换的含量低于5％，（iii）肖氏A值和基于整个聚合物计算的烯属单元的重量含量，使得 由这些值定义的点低于由以下等式定义的曲线：<？in-line-formula description =“In-li “公式”end =“lead”？> Y = 0.0438X <2> -4.1332X + A <？in-line-formula description =“In-line Formulas”end =“tail”？> where Y是肖氏A的值，X是通过NMR计算的聚合物中乙烯单元的重量百分比，A是145。

公开(公告)号：US20080160862A1

公开(公告)日：2008-07-03

申请号：US11792803

申请日：2005-11-07

Applicant: Franco Sartori ,  Gabriella Sartori

Inventor： Franco Sartori ,  Gabriella Sartori

IPC: D04H3/16 ,  C08L23/10

CPC classification number: D04H3/16 ,  C08L23/10 ,  C08L2203/12 ,  C08L2205/02 ,  D01F6/46 ,  Y10T442/681 ,  C08L2666/06

Abstract: A polyolefin composition comprising (parts by weight) (A) 100 parts of a crystalline isotactic propylene polymer resin having a molecular weight distribution ( Mw/ Mn) less than 3, the proportion of inversely inserted propylene units based on 2,1 insertions of a propylene monomer in all propylene insertions, i.e. 2,1 insertions, is as low as 0.5% or less, and a value of the melt flow rate (MFR) from 20 to 60 g/10 min; and (B) 0.1-1 part of a high molecular weight propylene polymer (B) having a value of melt strength from 5 to 40 cN.Fibres prepared from the said composition exhibit a good balance between elasticity and tenacity.

Abstract translation: 一种聚烯烃组合物，其包含（重量份）（A）100份具有分子量分布（ M O / O OYYLE =“）的结晶全同立构丙烯聚合物树脂 小于3的丙烯单体的反向插入丙烯单元的比例，即丙烯单体在所有丙烯插入中的2,1-插入，即2,1-插入时的比例低至0.5 ％以下，熔体流动速率（MFR）的值为20〜60g / 10分钟; 和（B）0.1-1份具有5至40cN的熔体强度值的高分子量丙烯聚合物（B）。 从所述组合物制备的纤维在弹性和韧度之间表现出良好的平衡。