公开(公告)号：US09553268B2

公开(公告)日：2017-01-24

申请号：US14378564

申请日：2013-02-13

申请人： Massachusetts Institute of Technology ,  Eni S.p.A.

发明人： Miles C. Barr ,  Karen K. Gleason ,  Chiara Carbonera ,  Riccardo Po ,  Vladimir Bulovic

IPC分类号： H01L51/00 ,  C08G61/12 ,  H01L51/44 ,  H01B1/12 ,  B82Y10/00 ,  H01L51/56 ,  H01L51/42

CPC分类号： H01L51/0021 ,  B82Y10/00 ,  C08G61/126 ,  C08G2261/3223 ,  C08G2261/3247 ,  C08G2261/70 ,  C08G2261/91 ,  C08G2261/95 ,  H01B1/127 ,  H01L51/0037 ,  H01L51/0046 ,  H01L51/0056 ,  H01L51/424 ,  H01L51/44 ,  H01L51/441 ,  H01L51/56 ,  H01L2251/308 ,  Y02E10/549

摘要： The present invention generally relates to cathode buffer materials and devices and methods comprising the cathode buffer materials.

摘要翻译： 本发明一般涉及阴极缓冲材料和包括阴极缓冲材料的装置和方法。

公开(公告)号：US20160369181A1

公开(公告)日：2016-12-22

申请号：US14902204

申请日：2014-07-04

申请人： ENI S.p.A.

发明人： Giuseppe BELLUSSI ,  Vincenzo PICCOLO ,  Alberto MALANDRINO ,  Valentina FABIO ,  Giacomo Fernando RISPOLI

IPC分类号： C10G65/00

CPC分类号： C10G65/00 ,  C10G7/00 ,  C10G7/06 ,  C10G45/02 ,  C10G47/26 ,  C10G49/12 ,  C10G65/12 ,  C10G65/14 ,  C10G65/16 ,  C10G2300/202 ,  C10G2300/308

摘要： Process for the refining of crude oil comprising at least one atmospheric distillation unit for separating the various fractions, a sub-atmospheric distillation unit, a conversion unit of the heavy fractions obtained, a unit for enhancing the quality of some of the fractions obtained by actions on the chemical composition of their constituents and a unit for the removal of undesired components, characterized in that the sub-atmospheric distillation residue is sent to one of the conversion units, said conversion unit comprises at least one hydroconversion reactor in slurry phase, into which hydrogen or a mixture of hydrogen and ¾ S, is fed, in the presence of a suitable dispersed hydrogenation catalyst with dimensions ranging from 1 nanometer to 30 microns.

摘要翻译： 用于精炼原油的方法包括至少一个用于分离各种馏分的常压蒸馏装置，亚常压蒸馏装置，所得重馏分的转化装置，用于提高通过动作获得的一些馏分的质量的装置 关于其组分的化学组成和用于除去不期望的组分的单元，其特征在于，将所述次大气压蒸馏残余物送入一个转化单元，所述转化单元包含至少一个浆料相中的加氢转化反应器，其中 氢或氢和¾S的混合物在适当的分散氢化催化剂的存在下进料，其尺寸范围为1纳米至30微米。

公开(公告)号：US09488038B2

公开(公告)日：2016-11-08

申请号：US13704479

申请日：2011-06-10

申请人： Giambattista De Ghetto ,  Paolo Andreussi

发明人： Giambattista De Ghetto ,  Paolo Andreussi

IPC分类号： E21B15/04 ,  B63C7/00 ,  E21B43/01 ,  E02B15/08 ,  E02B17/00 ,  E02D23/00 ,  E21B43/36

CPC分类号： E21B43/0122 ,  E21B43/36

摘要： The present invention relates to equipment for the conveying and recovery of hydrocarbons from an underwater well for the extraction of hydrocarbons under uncontrolled release conditions, comprising a chamber (23) for the separation of the hydrocarbon stream leaving the well, into a heavy phase (23a) and a light phase (23b), means (15,16,17,24,25,26) being envisaged, in connection with the separation chamber (23), for conveying the heavy phase (23a) and light phase (23b) towards the surface, characterized in that it comprises a directioning body (18) of the hydrocarbon stream, having a substantially cylindrical shape, or as a truncated paraboloid with both ends open, wherein a first end is an inlet of the hydrocarbon stream leaving the well, and a second end, distal with respect to the inlet of the hydrocarbon stream (20), is in fluid connection with the separation chamber (23) with the interpositioning of a perforated spherical cap (22).

摘要翻译： 本发明涉及用于在不受控制的释放条件下从水下井输送和回收碳氢化合物用于提取烃的设备，包括用于将离开井的烃流分离的室（23）进入重相（23a ）和轻相（23b），与分离室（23）结合设想的用于输送重相（23a）和轻相（23b）的装置（15,16,17,24,25,26） 其特征在于，其包括具有基本上圆柱形形状的烃流的取向体（18），或者两端开放的截顶抛物面，其中第一端是离开井的烃流的入口 ，并且相对于烃流（20）的入口远端的第二端通过插入穿孔的球形盖（22）与分离室（23）流体连接。

公开(公告)号：US20160264782A1

公开(公告)日：2016-09-15

申请号：US15036277

申请日：2014-11-14

申请人： ENI S.P.A. ,  CNRS (CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE)

发明人： Paolo BIAGINI ,  Riccardo PO' ,  Jean RONCALI ,  Dora DEMETER

IPC分类号： C09B23/10 ,  H01G9/20

CPC分类号： C09B23/102 ,  C09B23/105 ,  C09B57/00 ,  H01G9/2027 ,  H01G9/2059 ,  H01G9/2063 ,  H01L51/0037 ,  H01L51/0064 ,  Y02E10/542 ,  Y02E10/549

摘要： Organic dye for a dye-sensitized solar cell (DSSC) comprising at least one electron-acceptor unit and at least one π-conjugated unit. Said organic dye is particularly useful in a dye-sensitized photoelectric transformation element which, in its turn, can be used in a dye-sensitized solar cell (DSSC).

公开(公告)号：US20160245508A1

公开(公告)日：2016-08-25

申请号：US15025835

申请日：2014-10-02

申请人： ENI S.P.A.

发明人： Felicia MASSETTI ,  Maria Ilaria PISTELLI ,  Medardo PINTI

IPC分类号： F23G7/00 ,  F23G5/44 ,  F23G5/04 ,  C02F11/10 ,  F23G5/027

CPC分类号： F23G7/001 ,  C02F11/06 ,  C02F11/10 ,  C10J3/005 ,  C10J3/60 ,  C10J2200/158 ,  C10J2300/1246 ,  F23G5/006 ,  F23G5/027 ,  F23G5/0273 ,  F23G5/04 ,  F23G5/20 ,  F23G5/46 ,  F23G2201/101 ,  F23G2201/302 ,  F23G2201/303 ,  F23G2201/40 ,  F23G2203/211 ,  F23G2206/10 ,  F23G2209/12 ,  F23G2900/50001 ,  F23G2900/50201 ,  F23G2900/50204 ,  F23G2900/52001 ,  F23G2900/52002 ,  F23G2900/54402 ,  Y02W10/40

摘要： The present invention relates to reaction equipment for the treatment of organic and/or inorganic waste of refineries or petrochemical plants comprising: •—a drying and pyrolysis device (4) which rotates around its longitudinal, tilted rotation axis (A), •—a gasification device (6) which rotates around its longitudinal, horizontal rotation axis (B), •—a combustion device (14) comprising a burner (13) having a longitudinal horizontal axis (C), •—at least one settling chamber (15) for the collection of intermediate solid residues and the accumulation of intermediate gaseous reaction products, •—at least one outlet duct of the gaseous end-products (16), at least one outlet duct of the solid end-products (7), and at least one inlet duct of the feedstock (2) •—said combustion device (14), drying and pyrolysis device (4), gasification device (6) are physically separated and positioned on three different levels, •—the longitudinal rotation axis (A) of the drying and pyrolysis device (4) is tilted with respect to both the longitudinal rotation axis (B) of the gasification device (6) and also with respect to the longitudinal axis (C) of the combustion device (14), •—the longitudinal rotation axis (B) of the gasification device (6) is parallel to the longitudinal axis (C) of the combustion device (14), •—the combustion device (14) is in fluid communication with the drying and pyrolysis device (4), •—the drying and pyrolysis device (4) comprises, in its interior, a first indirect heat exchange device (3) in which the combustion fumes coming from the combustion device (14) flow, •—at least one settling chamber (15) in fluid communication with said drying and pyrolysis device (4) and with said gasification device (6) and with said combustion device (14), •—conveying means (5) are positioned in the settling chamber (15) and put the drying and pyrolysis device (4) in fluid communication with the gasification device, •—it comprises a second heat exchange device (12) in fluid communication with the first indirect heat exchange device (3) and the combustion device (14), •—it comprises means for the suction of the intermediate gaseous reaction products, said means being positioned in the settling chamber (15).

公开(公告)号：US09353125B2

公开(公告)日：2016-05-31

申请号：US14237538

申请日：2012-08-01

申请人： Giuliana Schimperna ,  Gabriele Bianchi

发明人： Giuliana Schimperna ,  Gabriele Bianchi

IPC分类号： C07D495/04 ,  C07D413/14 ,  C07D417/14 ,  C07D409/14 ,  C07D519/00

CPC分类号： C07D417/14 ,  C07D409/14 ,  C07D413/14 ,  C07D495/04 ,  C07D519/00

摘要： Process for the preparation of a benzohetero[1,3]diazole compound disubstituted with heteroaryl groups which comprises reacting at least one benzohetero[1,3]diazole compound disubstituted with at least one heteroaryl compound. Said benzohetero[1,3]diazole compound disubstituted with heteroaryl groups can be advantageously used in the construction of luminescent solar concentrators (LSC). Furthermore, said benzohetero[1,3]diazole compound disubstituted with heteroaryl groups can be advantageously used in the construction of photovoltaic devices such as, for example, photovoltaic cells, photovoltaic modules, solar cells, solar modules, on both a rigid and flexible support. Said benzohetero[1,3]diazole compound disubstituted with heteroaryl groups can also be advantageously used as a precursor of monomeric units in the preparation of semiconductor polymers.

摘要翻译： 制备用杂芳基二取代的苯并[1,3]二唑化合物的方法，该方法包括使至少一种被至少一个杂芳基化合物二取代的苯并[1,3]二唑化合物反应。 用杂芳基二取代的所述苯并[1,3]二唑化合物可有利地用于发光太阳能集中器（LSC）的构建。 此外，用杂芳基二取代的所述苯并[1,3]二唑化合物可有利地用于在刚性和柔性载体上构建光伏器件，例如光伏电池，光伏模块，太阳能电池，太阳能电池组件 。 用杂芳基二取代的所述苯并[1,3]二唑化合物也可有利地用作半导体聚合物制备中单体单元的前体。

公开(公告)号：US09328109B2

公开(公告)日：2016-05-03

申请号：US14759328

申请日：2014-01-13

申请人： ENI S.p.A.

发明人： Gabriele Bianchi ,  Riccardo Po'

IPC分类号： C07D417/14

CPC分类号： C07D417/14

摘要： Process for the preparation of a benzohetero-[1,3]diazole compound disubstituted with brominated heteroaryl groups which comprises reacting at least one dihalogenated benzohetero[1,3]diazole compound with at least one brominated heteroaryl compound. Said benzohetero[1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used in the synthesis of compounds useful in the construction of solar concentrators (LSCs—“Luminescent Solar Concentrators”). Furthermore, said benzohetero[1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used in the synthesis of photoactive polymers useful in the construction of photovoltaic devices (or solar devices) such as, for example, photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), on both rigid or flexible supports. Furthermore, said benzohetero[1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used as precursor of monomeric units in the synthesis of semiconductor polymers.

摘要翻译： 制备用溴化杂芳基二取代的苯并[13]二唑化合物的方法，其包括使至少一种二卤代苯并[1,3]二唑化合物与至少一种溴化杂芳基化合物反应。 用溴化杂芳基二取代的所述苯并[1,3]二唑化合物可有利地用于合成可用于太阳能聚光器（LSCs-“发光太阳能集中器”）的构建中的化合物。 此外，用溴化杂芳基二取代的所述苯并[1,3]二噻唑化合物可有利地用于合成可用于构建光伏器件（或太阳能器件）的光聚合物，例如光伏电池（或太阳能电池 ），光伏模块（或太阳能模块），在刚性或柔性支撑件上。 此外，用溴化杂芳基二取代的所述苯并[1,3]二唑化合物可有利地用作半导体聚合物合成中单体单元的前体。

公开(公告)号：US20160068760A1

公开(公告)日：2016-03-10

申请号：US14783985

申请日：2013-04-22

申请人： ENI S.p.A.

发明人： Giuseppe BELMONTE ,  Alberto Maria Antonio MALANDRINO ,  Vincenzo PICCOLO

IPC分类号： C10G7/06 ,  C10G67/02

CPC分类号： C10G7/06 ,  C08L95/00 ,  C10C3/06 ,  C10G7/12 ,  C10G31/06 ,  C10G47/30 ,  C10G49/04 ,  C10G49/12 ,  C10G67/02 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/206 ,  C10G2300/301 ,  C10G2400/16

摘要： The process for treating a hydrocarbon-based heavy residue (1), in particular bituminous residues with a high asphaltene content, comprises the following operations: A) bringing the heavy residue to be treated to a temperature within the range of 325-500° C.; B) subjecting the heavy residue to be treated to a substantially adiabatic expansion in an environment at a pressure equal to or lower than about 0.1 bara, and at a temperature equal to or lower than 450° C., so as to separate, from the heavy residue to be treated, a first less volatile fraction (17) having a boiling point at atmospheric pressure equal to or higher than 540° C. and whose solid and/or anhydrous residue prevalently contains asphaltenes insoluble in pentane and/or other residues insoluble in tetrahydrofuran. It allows a more effective flushing, and also to actuate the process in an extremely simple plant and without centrifugations.

摘要翻译： 用于处理烃类重残渣（1），特别是具有高沥青质含量的沥青残渣的方法包括以下操作：A）将待处理的重残渣置于325-500℃的温度范围内 。 B）将重质残余物在等于或低于约0.1巴的压力和等于或低于450℃的温度的环境中进行基本上绝热的膨胀处理，以便从 待处理的重残余物，其沸点在大气压等于或高于540℃的第一较不挥发性的馏分（17），其固体和/或无水残余物通常含有不溶于戊烷和/或不溶于其的残余物的沥青质 在四氢呋喃中。 它允许更有效的冲洗，并且还可以在非常简单的设备中启动该过程，而不需要离心。

公开(公告)号：US09278339B2

公开(公告)日：2016-03-08

申请号：US13499452

申请日：2010-09-23

申请人： Giuseppe Bellussi ,  Angela Carati ,  Maria Federica Gagliardi ,  Stefano Zanardi ,  Marcello Marella ,  Roberto Scattolin ,  Michele Tomaselli

发明人： Giuseppe Bellussi ,  Angela Carati ,  Maria Federica Gagliardi ,  Stefano Zanardi ,  Marcello Marella ,  Roberto Scattolin ,  Michele Tomaselli

IPC分类号： B01J21/00 ,  B01J23/00 ,  B01J29/00 ,  B01J31/00 ,  B01J27/049 ,  B01J27/051 ,  B01J35/10 ,  B01J37/03 ,  B01J37/20 ,  C10G45/08

CPC分类号： B01J27/0515 ,  B01J23/002 ,  B01J23/883 ,  B01J23/8885 ,  B01J27/049 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/033 ,  B01J37/20 ,  B01J2523/00 ,  C10G45/08 ,  C10G2300/1044 ,  C10G2300/1062 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2400/04 ,  C10G2400/06 ,  B01J2523/31 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/41

摘要： New sulfided metal catalysts are described, containing a metal X selected from Ni, Co and mixtures thereof, a metal Y selected from Mo, W and mixtures thereof, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by the sulfidation of mixed oxide precursors, also new, having general formula (A) XaYbZcOd.pC (A) possibly shaped without a binder, or by sulfidation of mixed oxides having formula (A), in shaped form with a binder, wherein X is selected from Ni, Co and mixtures thereof, Y is selected from Mo, W and mixtures thereof, Z is selected from Si, Al and mixtures thereof, O is oxygen, C is selected from: a nitrogenated compound N, an organic residue deriving from the partial calcination of the nitrogenated compound N, said nitrogenated compound N, when present, being selected from: a) an alkyl ammonium hydroxide having formula (I) RIRIIRIIIRIVNOH (I) wherein the groups RI-RIV, the same or different, are aliphatic groups containing from 1 to 7 carbon atoms, b) an amine having formula (II) R1R2R3N (II) wherein R1 is a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, and R2 and R3, the same or different, are selected from H and a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, said alkyl being equal to or different from R1, a, b, c, d are the number of moles of the elements X, Y, Z, O, respectively, p is the weight percentage of C with respect to the total weight of the precursor having formula (A), a, b, c, d are higher than 0 a/b is higher than or equal to 0.3 and lower than or equal to 2, (a+b)/c is higher than or equal to 0.3 and lower than or equal to 10, preferably varying from 0.8 to 10 d=(2a+6b+Hc)/2 wherein H=4 when Z=Si H=3 when Z=Al and p is higher than or equal to 0 and lower than or equal to 40%. Said catalysts can be used as hydrotreating catalysts.

公开(公告)号：US20150361790A1

公开(公告)日：2015-12-17

申请号：US14761168

申请日：2014-01-14

申请人： ENI S.P.A.

发明人： Paolo FERRARA ,  Axel TUROLLA ,  Massimo ZAMPATO

IPC分类号： E21B49/00 ,  G01V1/48 ,  E21B47/06 ,  E21B10/42 ,  E21B47/022

CPC分类号： E21B49/006 ,  E21B10/00 ,  E21B10/42 ,  E21B47/02208 ,  E21B47/06 ,  G01V1/48 ,  H04R17/00

摘要： A method for revealing anomalous discontinuity interfaces in pore pressures in non-drilled geological formations and an implementing system. The method includes generating, by an electroacoustic transducer, first pressure sound waves and receiving a reflected signal of such first pressure sound waves generated by at least one discontinuity interface due to passage from first to second different geological formations situated successively along an emission direction of the electroacoustic transducer; calculating speed of the first pressure sound waves generated and distance between the electroacoustic transducer and the at least one discontinuity interface; generating, by the electroacoustic transducer, second pressure sound waves and revealing the electrical impedance induced at terminals of the electroacoustic transducer; estimating, based on the electrical impedance revealed, plural parameters characteristic of the first and second geological formation; estimating pressure of the second geological formation based on the sound speed and distance calculated and the plural characteristic parameters estimated.

摘要翻译： 揭示非钻孔地质构造孔隙压力异常不连续界面的方法和实施体系。 该方法包括通过电声换能器产生第一压力声波并且接收由至少一个不连续界面产生的这样的第一压力声波的反射信号，这是由于从第一到第二不同的地质构造物沿着沿着发射方向 电声换能器; 计算产生的第一压力声波的速度和电声换能器与至少一个不连续接口之间的距离; 通过电声换能器产生第二压力声波并且显示在电声换能器的端子处感应的电阻抗; 基于所显示的电阻抗，估计第一和第二地质构造的特征的多个参数; 基于计算的声速和距离估计第二地质构造的压力和估计的多个特征参数。