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    Palladium-containing catalyst
    42.
    发明授权
    Palladium-containing catalyst 失效
    含钯催化剂

    公开(公告)号：US4176085A

    公开(公告)日：1979-11-27

    申请号：US585227

    申请日：1975-06-09

    Applicant: Jin S. Yoo ,  Ronald L. Milam

    Inventor： Jin S. Yoo ,  Ronald L. Milam

    IPC: B01J31/24 ,  C07C2/04 ,  B01J31/22

    CPC classification number: B01J31/1616 ,  B01J31/122 ,  B01J31/143 ,  B01J31/2291 ,  B01J31/24 ,  C07C2/04 ,  C08F10/00 ,  C08F210/02 ,  B01J2231/12 ,  B01J2531/824 ,  C07C2521/12 ,  C07C2531/14 ,  C07C2531/22 ,  C07C2531/24

    Abstract: Solid .pi.-allyl complex catalysts comprising:(A) A palladium source;(B) A monotertiary phosphine electron donor ligand;(C) A combination of a reducing agent capable of reducing the palladium source to an oxidation state of less than 2 and a Lewis acid capable of forming a coordination bond with palladium; and(D) An acidic, solid, silica-based support material, are useful in the codimerization of a conjugated diene and a monoene. Preferably, the catalyst is activated by the additional presence of a conjugated diene. In a preferred embodiment, the solid .pi.-allyl palladium complex catalyst prepared from palladium acetylacetonate, triphenylphosphine, diethylaluminum chloride and a calcined silica-alumina support having a separate, distinct alumina phase is useful in the selective codimerization of 1,3-butadiene and ethylene to form trans-1,4-hexadiene.

    Abstract translation: 包括：（A）钯源; （B）单子膦电子供体配体; （C）能够将钯源还原成氧化态小于2的还原剂和能够与钯形成配位键的路易斯酸的组合; 和（D）酸性固体二氧化硅基载体材料可用于共轭二烯和单烯的共聚。 优选地，通过额外存在共轭二烯活化催化剂。 在优选的实施方案中，由乙酰丙酮钯，三苯基膦，二乙基氯化铝和具有单独的不同氧化铝相的煅烧二氧化硅 - 氧化铝载体制备的固体pi烯丙基钯配合物催化剂可用于1,3-丁二烯和乙烯的选择性同工化 以形成反式-1,4-己二烯。

    PROCESS FOR PREPARING AN ORGANIC ACID OR ITS DERIVATIVES USING A HOMOGENEOUS MC-TYPE CATALYST AND AN O2/CO2 MIXTURE
    45.
    发明申请
    PROCESS FOR PREPARING AN ORGANIC ACID OR ITS DERIVATIVES USING A HOMOGENEOUS MC-TYPE CATALYST AND AN O2/CO2 MIXTURE 审中-公开
    使用均质MC型催化剂和O2 / CO2混合物制备有机酸或其衍生物的方法

    公开(公告)号：US20080091043A1

    公开(公告)日：2008-04-17

    申请号：US11844685

    申请日：2007-08-24

    Applicant: Jin S. Yoo ,  Sang-Chul Lee ,  Ho Dong Kim

    Inventor： Jin S. Yoo ,  Sang-Chul Lee ,  Ho Dong Kim

    IPC: C07C69/76

    CPC classification number: C07C51/265 ,  C07C63/26 ,  C07C63/307 ,  C07C63/04 ,  C07C63/00 ,  C07C63/15

    Abstract: The present invention relates to a process for producing an organic acid or its derivatives, which comprises oxidation of a hydrocarbon substrate in the presence of a homogeneous MC-type catalyst and an oxidant. In particular, the present invention relates to a process comprising oxidation of a hydrocarbon substrate in the presence of a homogeneous MC-type catalyst selected from Co/Br, Mn/Br, Co/Mn/Br and Co/Mn/M/Br and an O2/CO2 mixed gas oxidant where the partial pressure of O2 is controlled to 30-40%, thereby improving the oxidation rate, the conversion, the selectivity and the yield even under milder conditions. Especially, the present invention remarkably reduces down to a negligible level the production of color impurities and other impurities such as 4-CBA and p-toluic acid, which had been conventionally removed by hydrogenation reduction. Further, the loss in acetic acid solvent due to combustion can also be drastically decreased using the method of the present invention.

    Abstract translation: 本发明涉及有机酸或其衍生物的制备方法，其包括在均相MC型催化剂和氧化剂存在下氧化烃底物。 特别地，本发明涉及一种包括在选自Co / Br，Mn / Br，Co / Mn / Br和Co / Mn / M / Br的均匀MC型催化剂存在下烃基底的氧化的方法，以及 将O 2分压控制在30-40％的O 2 / CO 2混合气体氧化剂，从而提高氧化速率 ，转化率，选择性和产率，甚至在较温和的条件下。 特别地，本发明显着地降低了常规通过氢化还原除去的彩色杂质和诸如4-CBA和对甲苯甲酸的其它杂质的产生的可忽略的水平。 此外，使用本发明的方法也可以大大降低由燃烧引起的乙酸溶剂的损失。

    Regeneraation of metal contaminated hydrocarbon conversion catalytsts
    46.
    发明授权
    Regeneraation of metal contaminated hydrocarbon conversion catalytsts 失效
    金属污染烃转化催化剂的再生

    公开(公告)号：US4800185A

    公开(公告)日：1989-01-24

    申请号：US090645

    申请日：1987-08-28

    Applicant: Frank J. Elvin ,  Jan-Erik Otterstedt ,  Jin S. Yoo

    Inventor： Frank J. Elvin ,  Jan-Erik Otterstedt ,  Jin S. Yoo

    IPC: B01J29/90 ,  B01J38/48 ,  B01J38/66 ,  C10G11/05 ,  B01J29/38 ,  B01J38/64

    CPC classification number: B01J38/48 ,  B01J29/90 ,  B01J38/66 ,  C10G11/05 ,  Y10S502/516

    Abstract: A process for treating a catalyst contaminated with at least one metal which was so contaminated while promoting conversion of a substantially hydrocarbon feedstock containing the metal comprising at least one of the following: (1) contacting the catalyst component to increase the ammonium ion-containing component to increase the ammonium ion content of the catalyst; and (2) contacting the catalyst with at least one rare earth metal ion-containing component to increase the rare earth metal ion content of the catalyst. Improved hydrocarbon conversion processes are also disclosed.

    Abstract translation: 一种处理被至少一种被污染的催化剂污染的催化剂的方法，该催化剂同时促进包含以下至少一种的包含金属的基本上含烃的原料的转化：（1）使催化剂组分接触以增加含铵离子的组分 以增加催化剂的铵离子含量; 和（2）使催化剂与至少一种含稀土金属离子的组分接触以增加催化剂的稀土金属离子含量。 还公开了改进的烃转化方法。

    Catalyst for conversion of hydrocarbons
    47.
    发明授权
    Catalyst for conversion of hydrocarbons 失效
    碳氢化合物转化催化剂

    公开(公告)号：US4495304A

    公开(公告)日：1985-01-22

    申请号：US494604

    申请日：1983-05-16

    Applicant: Jin S. Yoo ,  John A. Jaecker

    Inventor： Jin S. Yoo ,  John A. Jaecker

    IPC: B01J21/00 ,  B01J23/00 ,  B01J37/04 ,  C10G11/04 ,  B01J29/06

    CPC classification number: C10G11/04 ,  B01J21/005 ,  B01J23/005 ,  B01J37/04

    Abstract: An improved process for converting hydrocarbons using a catalyst which is periodically regenerated to remove carbonaceous deposits, the catalyst being comprised of a mixture containing, as a major component, solid particles capable of promoting hydrocarbon conversion at hydrocarbon conversion conditions, and, as a minor component, discrete entities comprising at least one spinel, preferably alkaline earth metal-containing spinel; thereby reducing the amount of sulfur oxides exiting the catalyst regeneration zone.Improved hydrocarbon conversion catalysts are also disclosed.

    Abstract translation: 一种使用周期性再生以除去含碳沉积物的催化剂转化烃的改进方法，该催化剂由含有作为主要组分的能够在烃转化条件下促进烃转化的固体颗粒和作为次要组分的混合物 包括至少一种尖晶石，优选含碱土金属的尖晶石的离散实体; 从而减少离开催化剂再生区的硫氧化物的量。 还公开了改进的烃转化催化剂。

    Phosphorus passivation process
    49.
    发明授权
    Phosphorus passivation process 失效
    磷钝化工艺

    公开(公告)号：US4321128A

    公开(公告)日：1982-03-23

    申请号：US150852

    申请日：1980-05-19

    Applicant: Jin S. Yoo

    Inventor： Jin S. Yoo

    IPC: C10G11/02 ,  C10G11/18 ,  C10G47/12

    CPC classification number: C10G11/02 ,  Y10S502/521

    Abstract: A passivation process for decreasing the poisonous effects from contamination by metals, such as vanadium, iron, nickel or copper that can occur during a catalytic conversion of a hydrocarbon feedstock containing such metals is disclosed. The process employs compositions of organic or aqueous media containing one or more, at least partially soluble species of phosphorus compounds.

    Abstract translation: 公开了一种用于减少在含有这种金属的烃原料的催化转化期间可能发生的金属（例如钒，铁，镍或铜）的污染的有害影响的钝化方法。 该方法使用含有一种或多种至少部分可溶性磷化合物的有机或含水介质的组合物。

    Passivation process
    50.
    发明授权
    Passivation process 失效
    钝化过程

    公开(公告)号：US4319983A

    公开(公告)日：1982-03-16

    申请号：US150863

    申请日：1980-05-19

    Applicant: Jin S. Yoo

    Inventor： Jin S. Yoo

    IPC: B01J21/20 ,  B01J29/90 ,  C10G11/02 ,  C10G11/18 ,  C10G47/12

    CPC classification number: C10G11/02 ,  B01J21/20 ,  B01J29/90 ,  Y10S502/521

    Abstract: A passivation process for decreasing the poisonous effects from contamination by metals, such as vanadium, iron, nickel or copper that can occur during a catalytic conversion of a hydrocarbon feedstock containing such metals is disclosed. The process employs compositions of organic or aqueous media containing one or more, at least partially soluble species of silicon, alone or in combination with phosphorus and/or aluminum-containing materials or species.

    Abstract translation: 公开了一种用于减少在含有这种金属的烃原料的催化转化期间可能发生的金属（例如钒，铁，镍或铜）的污染的有害影响的钝化方法。 该方法使用含有一种或多种至少部分可溶性硅的有机或含水介质的组合物，其单独或与含磷和/或含铝材料或物质组合。

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