摘要:
The elution of zinc from zinc-impregnated zeolite catalysts is minimized by incorporating gallium into the catalyst composition. Optionally, palladium may also be included in the composition. The catalyst composition is used to effect the conversion of propane in hydrocarbon streams to aromatic hydrocarbons.
摘要:
Isomerization of xylene in admixture with ethylbenzene by contact with a zeolite catalyst such as ZSM-5 is improved by use of a zeolite having a catalyst particle size of at least 1 micron and having incorporated thereon two metals such as platinum and magnesium.
摘要:
Cracking catalysts or catalyst supports prepared from mixtures comprising colloidal alumina, colloidal silica, a particulate weighting agent, and/or an active catalytic component possess excellent catalytic and physical properties. The catalysts in accordance with the invention also show excellent resistance to metal poisoning, and are also highly useful in non-cracking and/or hydroconversion processes.
摘要:
A cracking catalyst composition co-impregnated with a combination of a rare earth oxide and with either chromium, manganese, cobalt, nickel or platinum group metals. Such catalyst compositions, when used in fluidized catalytic cracking processes, result in significant reductions of sulfur content in the coke produced thereby, in turn significantly reducing sulfur oxide (SO.sub.x) emission in the regeneration stack gases.
摘要:
This invention relates to an energy-efficient process for dewaxing hydrocrackate and manufacturing a stabilized and dewaxed hydrocracked lubricating oil stock from hydrocarbon feedstock boiling above about 343.degree. C.
摘要:
Isomerization of xylene admixed with other alkyl aromatics of at least eight carbon atoms and with normal or slightly branched paraffins is conducted at 600.degree.-800.degree. F. with a zeolite like zeolite ZSM-5 of reduced acid activity.
摘要:
A method of preparing aromatics processing catalysts which comprises incorporating a noble metal with a member or members of a useful class of zeolites, with such incorporation occurring after zeolite crystallization, but prior to final catalyst particle formation, i.e. extrusion into particles. Said useful class of zeolites is characterized by a silica to alumina mole ratio of at least 12 and a Constraint Index in the approximate range of 1 to 12.
摘要:
A method of passivating metal contaminants on cracking catalysts which comprises contacting said catalysts with steam for limited periods of time and at moderate temperatures.
摘要:
A method is provided for obtaining crystalline dealuminized products by treating a slurry of a crystalline aluminosilicate zeolite in an aqueous solution of an ammonium or alkali metal salt which upon acidification yields an anion which complexes with aluminum by adding to said slurry a water-soluble acid having a first ionization constant greater than 10.sup.-2 at a rate such that a controlled amount of aluminum is removed from the zeolite to yield a resulting product from which at least about 10% and as much as about 85% of the initial aluminum has been removed while retaining more than 60% of the original crystallinity.
摘要:
A new synthetic porous crystalline material, designated EMM-1, is disclosed having, in its calcined form, the X-ray diffraction pattern of Table 2 above. Also disclosed are methods of making EMM-1 in the presence of HF using various organic nitrogen compounds as directing agents. Aluminum-containing EMM-1 can be produced either by inclusion of Al in the synthesis, or by incorporation of B or Ga in the synthesis, followed by post treatment with aluminum nitrate or other sources of Al. EMM-1 is useful as an acid catalyst and as an adsorbent.