公开(公告)号：US08513315B2

公开(公告)日：2013-08-20

申请号：US12981665

申请日：2010-12-30

申请人： Charles L. Kibby

发明人： Charles L. Kibby

IPC分类号： C07C27/00

CPC分类号： C10L1/08 ,  C10G2/334 ,  C10G2400/02 ,  C10L1/06 ,  Y02P20/582

摘要： A process of form hydrocarbons boiling to the gasoline range and reducing or eliminating net CO2 production during isosynthesis over a ZnO—Cr2O3 plus ZSM-5 catalyst by adding from about 5% to about 15% CO2 to the synthesis gas mixture prior to contact to with catalyst.

摘要翻译： 一种将烃类沸腾至汽油范围的方法，通过在接触之前向合成气混合物中加入约5％至约15％的CO 2而在ZnO-Cr 2 O 3加ZSM-5催化剂上的同质合成期间减少或消除净二氧化碳产生的过程 催化剂。

公开(公告)号：US08263523B2

公开(公告)日：2012-09-11

申请号：US12649135

申请日：2009-12-29

申请人： Charles L. Kibby ,  Alfred Haas

发明人： Charles L. Kibby ,  Alfred Haas

IPC分类号： B01J21/00

CPC分类号： B01J29/072 ,  B01J29/146 ,  B01J29/46 ,  B01J29/7615 ,  B01J29/7669 ,  B01J37/0045 ,  B01J37/32 ,  B01J2229/186 ,  C10G2/332 ,  C10G2300/705

摘要： A method for forming a cobalt-containing Fischer-Tropsch catalyst involves precipitating a cobalt oxy-hydroxycarbonate species by turbulent mixing, during which a basic solution collides with an acidic solution comprising cobalt. The method further involves depositing the cobalt oxy-hydroxycarbonate species onto an acidic support to provide a catalyst comprising cobalt and the acidic support. The acidic support comprises a zeolite, a molecular sieve, or combinations thereof.

摘要翻译： 形成含钴费 - 托催化剂的方法包括通过湍流混合沉淀钴 - 羟基碳酸酯物质，在此期间碱性溶液与包含钴的酸性溶液碰撞。 该方法还包括将羟基 - 羟基碳酸钴物质沉积到酸性载体上以提供包含钴和酸性载体的催化剂。 酸性载体包括沸石，分子筛或其组合。

公开(公告)号：US20120172459A1

公开(公告)日：2012-07-05

申请号：US13421601

申请日：2012-03-15

申请人： Charles L. Kibby ,  Minquan Cheng ,  Yun Lei ,  David Lawrence Trimm ,  William L. Schinski

发明人： Charles L. Kibby ,  Minquan Cheng ,  Yun Lei ,  David Lawrence Trimm ,  William L. Schinski

IPC分类号： C07C27/00

CPC分类号： C10G2/32 ,  C10G2300/304

摘要： A method is disclosed for converting syngas to Fischer-Tropsch (F-T) hydrocarbon products. A synthesis gas including carbon monoxide and hydrogen gas is provided to a F-T reactor. Also, acetylene is supplied to the F-T reactor. The ratio of the volume of acetylene to the volume of synthesis gas is at least 0.01. The synthesis gas and acetylene are reacted under suitable reaction conditions and in the presence of a catalyst to produce F-T hydrocarbon products. The F-T hydrocarbon products are then recovered from the reactor. The synthesis gas and acetylene may be provided in a combined feed stream or introduced separately into the reactor. The acetylene enhanced syngas conversion in a F-T reactor results in the synthesis of F-T products which have a tighter distribution of intermediate length carbon products than do F-T products synthesized according to conventional methods.

摘要翻译： 公开了将合成气转化为费 - 托（F-T）烃产物的方法。 将包含一氧化碳和氢气的合成气体提供给F-T反应器。 此外，向F-T反应器供应乙炔。 乙炔体积与合成气体积之比至少为0.01。 合成气和乙炔在合适的反应条件下和催化剂存在下反应生成F-T烃产物。 然后从反应器中回收F-T烃产物。 合成气和乙炔可以以组合的进料流提供或分开引入反应器。 在F-T反应器中乙炔增强的合成气转化导致F-T产物的合成，其具有与根据常规方法合成的F-T产物相比中等长度碳产物分布更严格的F-T产物。

公开(公告)号：US07943673B2

公开(公告)日：2011-05-17

申请号：US12316209

申请日：2008-12-10

申请人： Charles L. Kibby ,  Allen W. Burton, Jr. ,  Alfred Haas ,  Simon Holz

发明人： Charles L. Kibby ,  Allen W. Burton, Jr. ,  Alfred Haas ,  Simon Holz

IPC分类号： C07C27/00

CPC分类号： B01J35/0006 ,  B01J23/26 ,  B01J29/87 ,  B01J35/1019 ,  B01J37/031 ,  B01J37/18 ,  C01B39/082 ,  C10G2/33 ,  C10G2/334 ,  C10L1/06

摘要： A process is described for converting synthesis gas containing carbon monoxide and hydrogen to hydrocarbons via methanol as an intermediate, by contacting the synthesis gas with a catalyst system containing a mixture of gallium silicate zeolite catalyst and a methanol catalyst. The process results in reduced amounts of undesirable low carbon number hydrocarbons, e.g., C4 and lower, undesirable high carbon number hydrocarbons, e.g., C10 and higher, and aromatic hydrocarbons. The process provides higher yields of useful, high octane hydrocarbons boiling in the gasoline range.

摘要翻译： 描述了通过使合成气与含有硅酸镓沸石催化剂和甲醇催化剂的混合物的催化剂体系接触来将含有一氧化碳和氢的合成气转化为甲醇作为中间体的方法。 该方法导致不期望的低碳数烃的量减少，例如C4和更低的不期望的高碳数烃，例如C10和更高级的芳族烃。 该方法提供了在汽油范围内沸腾的有用的高辛烷值的较高产率。

公开(公告)号：US20100168258A1

公开(公告)日：2010-07-01

申请号：US12649135

申请日：2009-12-29

申请人： Charles L. Kibby ,  Alfred Haas

发明人： Charles L. Kibby ,  Alfred Haas

IPC分类号： B01J29/072 ,  C07C27/00

CPC分类号： B01J29/072 ,  B01J29/146 ,  B01J29/46 ,  B01J29/7615 ,  B01J29/7669 ,  B01J37/0045 ,  B01J37/32 ,  B01J2229/186 ,  C10G2/332 ,  C10G2300/705

摘要： A method for forming a cobalt-containing Fischer-Tropsch catalyst involves precipitating a cobalt oxy-hydroxycarbonate species by turbulent mixing, during which a basic solution collides with an acidic solution comprising cobalt. The method further involves depositing the cobalt oxy-hydroxycarbonate species onto an acidic support to provide a catalyst comprising cobalt and the acidic support. The acidic support comprises a zeolite, a molecular sieve, or combinations thereof.

摘要翻译： 形成含钴费 - 托催化剂的方法包括通过湍流混合沉淀钴 - 羟基碳酸酯物质，在此期间碱性溶液与包含钴的酸性溶液碰撞。 该方法还包括将羟基 - 羟基碳酸钴物质沉积到酸性载体上以提供包含钴和酸性载体的催化剂。 酸性载体包括沸石，分子筛或其组合。

公开(公告)号：US06331573B1

公开(公告)日：2001-12-18

申请号：US09515693

申请日：2000-02-29

申请人： Charles L. Kibby

发明人： Charles L. Kibby

IPC分类号： C07C2700

CPC分类号： C10G2/332 ,  Y02P30/40

摘要： An integrated process for producing liquid fuels from syngas via a two-stage Fischer-Tropsch reaction is disclosed. The first stage of the Fischer-Tropsch chemistry is performed using conditions in which chain growth probabilities are relatively low to moderate, and the product of the reaction includes a relatively high proportion of low molecular (C2-8) weight olefins and a relatively low proportion of high molecular weight (C30+) waxes. The product from the first stage is fed into the second stage where the chain growth probabilities are relatively high. The wax and other paraffins produced in the first reaction are largely inert under these conditions. The light olefins compete with heavier olefins for chain initiation, and fewer chains will be initiated at C20+. With most chains initiated at C2-8, moderate chain growth probability will produce a relatively larger fraction in the C5-12 range. In this manner, wax yield is minimized.

摘要翻译： 公开了一种通过两步费 - 托反应从合成气生产液体燃料的综合方法。 费 - 托化学的第一阶段是使用链增长概率相对低到中等的条件进行的，反应产物包括相对较高比例的低分子量（C2-8）重量烯烃和相对较低的比例 的高分子量（C30 +）蜡。 来自第一阶段的产品进入链增长概率相对较高的第二阶段。 在第一反应中产生的蜡和其它链烷烃在这些条件下很大程度上是惰性的。 轻烯烃与较重的烯烃竞争链起始，较少的链将在C20 +引发。 大多数链起始于C2-8，中等链增长概率将在C5-12范围内产生相对较大的分数。 以这种方式，蜡产率被最小化。

公开(公告)号：US4729981A

公开(公告)日：1988-03-08

申请号：US869705

申请日：1986-06-02

申请人： Thaddeus P. Kobylinski ,  Charles L. Kibby ,  Richard B. Pannell ,  Elizabeth L. Eddy

发明人： Thaddeus P. Kobylinski ,  Charles L. Kibby ,  Richard B. Pannell ,  Elizabeth L. Eddy

IPC分类号： B01J23/75 ,  B01J23/89 ,  B01J37/14 ,  B01J37/18 ,  C07C1/04 ,  B01J23/70

CPC分类号： C07C1/0445 ,  B01J23/75 ,  B01J23/894 ,  B01J37/14 ,  B01J37/18 ,  C07C2521/04 ,  C07C2523/10 ,  C07C2523/12 ,  C07C2523/46 ,  C07C2523/75

摘要： Catalyst for synthesis gas conversion in which a gas comprising carbon monoxide and hydrogen is converted to a liquid hydrocarbon is prepared by subjecting cobalt or nickel on a refractory metal oxide support to an activation procedure at a temperature of from about 100.degree. to about 450.degree. C. comprising, in sequence, (A) reduction in hydrogen, (B) oxidation in an oxygen-containing gas, and (C) reduction in hydrogen.

摘要翻译： 将含有一氧化碳和氢气的气体转化为液态烃的合成气转化催化剂是通过将钴或镍在难熔金属氧化物载体上进行活化程序制备的，该活化程序在约100至约450℃ （A）还原氢，（B）含氧气体中的氧化，和（C）氢的还原。

公开(公告)号：US4605680A

公开(公告)日：1986-08-12

申请号：US768923

申请日：1985-08-23

申请人： Harold Beuther ,  Charles L. Kibby ,  Thaddeus P. Kobylinski ,  Richard B. Pannell

发明人： Harold Beuther ,  Charles L. Kibby ,  Thaddeus P. Kobylinski ,  Richard B. Pannell

IPC分类号： B01J23/75 ,  B01J23/83 ,  C07C1/04 ,  C10G63/02

CPC分类号： C10G63/02 ,  B01J23/75 ,  B01J23/83 ,  C07C1/0445 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2523/10 ,  C07C2523/12 ,  C07C2523/40 ,  C07C2523/46 ,  C07C2523/75 ,  C07C2527/06

摘要： Synthesis gas is converted to diesel fuel and a high octane gasoline in two stages. In the first stage the synthesis gas is converted to straight chain paraffins mainly boiling in the diesel fuel boiling range utilizing a catalyst consisting essentially of cobalt, preferably promoted with a Group IIIB or IVB metal oxide, on a support of gamma-alumina, eta-alumina or mixtures thereof. A straight chain paraffin portion of the effluent in the C.sub.5 -C.sub.9 range is converted in a second stage to a highly aromatic and branched chain paraffinic gasoline using a platinum group metal catalyst.

摘要翻译： 合成气体分两个阶段转化为柴油和高辛烷值汽油。 在第一阶段，使用主要由钴组成的催化剂，优选用IIIB或IVB族金属氧化物促进，将催化剂转化为主要以柴油燃料沸腾沸腾的直链烷烃，在γ-氧化铝， 氧化铝或其混合物。 在C5-C9范围内的流出物的直链石蜡部分在第二阶段中使用铂族金属催化剂转化成高度芳族和支链链烷烃汽油。

公开(公告)号：US08258195B2

公开(公告)日：2012-09-04

申请号：US13421601

申请日：2012-03-15

申请人： Charles L. Kibby ,  Minquan Cheng ,  Yun Lei ,  David Lawrence Trimm ,  William L. Schinski

发明人： Charles L. Kibby ,  Minquan Cheng ,  Yun Lei ,  David Lawrence Trimm ,  William L. Schinski

IPC分类号： C07C27/00

CPC分类号： C10G2/32 ,  C10G2300/304

摘要： A method is disclosed for converting syngas to Fischer-Tropsch (F-T) hydrocarbon products. A synthesis gas including carbon monoxide and hydrogen gas is provided to a F-T reactor. Also, acetylene is supplied to the F-T reactor. The ratio of the volume of acetylene to the volume of synthesis gas is at least 0.01. The synthesis gas and acetylene are reacted under suitable reaction conditions and in the presence of a catalyst to produce F-T hydrocarbon products. The F-T hydrocarbon products are then recovered from the reactor. The synthesis gas and acetylene may be provided in a combined feed stream or introduced separately into the reactor. The acetylene enhanced syngas conversion in a F-T reactor results in the synthesis of F-T products which have a tighter distribution of intermediate length carbon products than do F-T products synthesized according to conventional methods.

公开(公告)号：US20100174002A1

公开(公告)日：2010-07-08

申请号：US12649108

申请日：2009-12-29

申请人： Charles L. Kibby ,  Alfred Haas

发明人： Charles L. Kibby ,  Alfred Haas

IPC分类号： C07C27/06 ,  B01J23/83 ,  B01J21/04

CPC分类号： B01J23/75 ,  B01J23/755 ,  B01J23/78 ,  B01J23/83 ,  B01J23/864 ,  B01J23/8892 ,  B01J23/8896 ,  B01J23/8913 ,  B01J23/894 ,  B01J37/0045 ,  B01J37/0205 ,  B01J37/035 ,  B01J37/038 ,  B01J37/08 ,  B01J37/12 ,  B01J37/16 ,  B01J37/32 ,  C10G2/332 ,  C10G2300/705

摘要： A method for forming a cobalt-containing Fischer-Tropsch catalyst involves precipitating a cobalt oxy-hydroxycarbonate species by turbulent mixing, during which a basic solution collides with an acidic solution comprising cobalt. The method further involves depositing the cobalt oxy-hydroxycarbonate species onto a support material to provide a catalyst comprising cobalt and the support material. The support material comprises one or more of alumina, silica, magnesia, titania, zirconia, ceria-zirconia, and magnesium aluminate.

摘要翻译： 形成含钴费 - 托催化剂的方法包括通过湍流混合沉淀钴 - 羟基碳酸酯物质，在此期间碱性溶液与包含钴的酸性溶液碰撞。 该方法还包括将羟基 - 羟基碳酸钴物质沉积到载体材料上以提供包含钴和载体材料的催化剂。 载体材料包括氧化铝，二氧化硅，氧化镁，二氧化钛，氧化锆，二氧化铈 - 氧化锆和铝酸镁中的一种或多种。