Method for making aluminosilicate ZSM-12
    1.
    发明授权
    Method for making aluminosilicate ZSM-12 有权
    铝硅酸盐ZSM-12的制备方法

    公开(公告)号:US08679451B2

    公开(公告)日:2014-03-25

    申请号:US12622680

    申请日:2009-11-20

    IPC分类号: C01B33/36 C01B39/00

    摘要: An aluminosilicate ZSM-12 may be prepared de novo in a small crystalline form from a reaction mixture containing a source of silica and a source of alumina. A small crystalline form of aluminosilicate ZSM-12 may also be prepared from a small crystalline form of borosilicate ZSM-12 by replacement of boron in the borosilicate ZSM-12 framework with aluminum. The aluminosilicate ZSM-12 is useful as an isomerization selective catalyst in processes such as isomerization dewaxing hydrocarbon feedstocks.

    摘要翻译: 铝硅酸盐ZSM-12可以从含有二氧化硅源和氧化铝源的反应混合物中以小结晶形式从头制备。 也可以通过用硼替代硼硅酸盐ZSM-12骨架中的硼,由小晶体形式的硼硅酸盐ZSM-12制备小晶体的硅酸铝ZSM-12。 铝硅酸盐ZSM-12可用作异构化选择性催化剂,例如异构化脱蜡烃原料。

    Method for making borosilicate ZSM-48 molecular sieves
    10.
    发明授权
    Method for making borosilicate ZSM-48 molecular sieves 有权
    制备硼硅酸盐ZSM-48分子筛的方法

    公开(公告)号:US08142757B2

    公开(公告)日:2012-03-27

    申请号:US12612824

    申请日:2009-11-05

    IPC分类号: C01B39/04 C01B39/46 C01B39/48

    摘要: The present invention is directed to a borosilicate ZSM-48 molecular sieve having a mole ratio of between 40 and 400 of silicon oxide to boron oxide, synthesized using novel structure directing agents. Also disclosed are processes using a borosilicate ZSM-48 as a catalyst for the selective hydroconversion of heavy normal paraffins into lighter normal paraffin products, with minimal formation of isoparaffins.

    摘要翻译: 本发明涉及使用新型结构导向剂合成的氧化硅与氧化硼的摩尔比在40和400之间的硼硅酸盐ZSM-48分子筛。 还公开了使用硼硅酸盐ZSM-48作为催化剂的重质正链烷烃选择性加氢转化为更轻的正链烷烃产物,同时形成异链烷烃的方法。