公开(公告)号：US20130310528A1

公开(公告)日：2013-11-21

申请号：US13875737

申请日：2013-05-02

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Donna J. Crowther ,  Patrick Brant ,  Carlos U. DeGracia ,  Jacqueline A. Lovell

IPC: C08F4/76

CPC classification number: C08F4/65912 ,  B01J31/12 ,  B01J31/14 ,  B01J31/2295 ,  B01J2531/48 ,  B01J2531/49 ,  C08F4/16 ,  C08F4/65908 ,  C08F4/6592 ,  C08F4/76 ,  C08F110/06 ,  C08F210/06 ,  Y10S526/943 ,  C08F210/16 ,  C08F2500/03 ,  C08F10/06 ,  C08F4/65927

Abstract: This invention relates to a homogenous process for making a vinyl terminated propylene polymer, wherein the process comprises: contacting, propylene, under polymerization conditions, with a catalyst system comprising an activator and at least one metallocene compound, where the metallocene compound is represented by the formula: where: M is hafnium or zirconium; each X is, independently, selected from the group consisting of hydrocarbyl radicals having from 1 to 20 carbon atoms, hydrides, amides, alkoxides, sulfides, phosphides, halides, dienes, amines, phosphines, ethers, and a combination thereof, (two X's may form a part of a fused ring or a ring system); each R1 is, independently, a C1 to C10 alkyl group; each R2 is, independently, a C1 to C10 alkyl group; each R3 is, independently, hydrogen; each R4, R5, and R6, is, independently, hydrogen or a substituted or unsubstituted hydrocarbyl group, a heteroatom or heteroatom containing group; T is a bridging group; each R7 is, independently, hydrogen, halogen, or a C1 to C20 hydrocarbyl, and two R7 can form a cyclic structure including aromatic, partially saturated, or saturated cyclic or fused ring system; and further provided that any of adjacent R4, R5, and R6 groups may form a fused ring or multicenter fused ring system where the rings may be aromatic, partially saturated or saturated.

Abstract translation: 本发明涉及制备乙烯基封端的丙烯聚合物的均匀方法，其中该方法包括：在聚合条件下使丙烯与包含活化剂和至少一种金属茂化合物的催化剂体系接触，其中茂金属化合物由 式：其中：M是铪或锆; 每个X独立地选自具有1至20个碳原子的烃基，氢化物，酰胺，醇盐，硫化物，磷化物，卤化物，二烯，胺，膦，醚及其组合（两个X的 可形成稠环或环系的一部分）; 每个R 1独立地为C 1至C 10烷基; 每个R 2独立地为C 1至C 10烷基; 每个R 3独立地是氢; 每个R 4，R 5和R 6独立地是氢或取代或未取代的烃基，含杂原子或杂原子的基团; T是一个桥接组; 每个R 7独立地是氢，卤素或C 1至C 20烃基，并且两个R 7可以形成包括芳族，部分饱和或饱和的环状或稠环体系的环状结构; 并且进一步规定相邻的R 4，R 5和R 6基团中的任何一个可以形成稠合环或多中心稠环体系，其中所述环可以是芳族的，部分饱和的或饱和的。

公开(公告)号：US20130261277A1

公开(公告)日：2013-10-03

申请号：US13901105

申请日：2013-05-23

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Peijun Jiang ,  Patrick Brant

IPC: C08F110/06 ,  C08F210/06

CPC classification number: C08F110/06 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F110/02 ,  C08F210/06 ,  C08F255/02 ,  C08F2500/03 ,  C08F2500/09 ,  C08F2500/20 ,  C08F4/65927 ,  C08F222/06

Abstract: This invention relates to a process for polymerization, comprising (i) contacting, at a temperature greater than 35° C., one or more monomers comprising ethylene and/or propylene, with a catalyst system comprising a metallocene catalyst compound and an activator, (ii) converting at least 50 mol % of the monomer to polyolefin; and (iii) obtaining a branched polyolefin having greater than 50% allyl chain ends, relative to total unsaturated chain ends. The invention also relates to the branched polyolefins and functionalized branched polyolefins.

Abstract translation: 本发明涉及一种聚合方法，其包括（i）在大于35℃的温度下使一种或多种包含乙烯和/或丙烯的单体与包含茂金属催化剂化合物和活化剂的催化剂体系接触（ ii）将至少50mol％的单体转化成聚烯烃; 和（iii）获得相对于总不饱和链末端具有大于50％烯丙基链端的支链聚烯烃。 本发明还涉及支链聚烯烃和官能化支化聚烯烃。

公开(公告)号：US20130023633A1

公开(公告)日：2013-01-24

申请号：US13628296

申请日：2012-09-27

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Matthew W. HOLTCAMP ,  Charles J. Ruff, JR. ,  Donna J. Crowther ,  John R. Hagadorn ,  Patrick Brant

IPC: C08F210/16 ,  C08F210/14 ,  C08F4/76

CPC classification number: C08F10/14 ,  C08F4/65908 ,  C08F4/65925 ,  C08F110/14 ,  C08F4/65927 ,  C08F210/14

Abstract: This invention relates to higher olefin vinyl terminated polymers having an Mn of at least 200 g/mol (measured by 1H NMR) including of one or more C4 to C40 higher olefin derived units, where the higher olefin vinyl terminated polymer comprises substantially no propylene derived units; and wherein the higher olefin polymer has at least 5% allyl chain ends and processes for the production thereof. These vinyl terminated higher olefin polymers may optionally include ethylene derived units.

Abstract translation: 本发明涉及具有至少200g / mol（通过1 H NMR测量）的Mn的高级烯烃乙烯基封端聚合物，其包含一个或多个C 4至C 40高级烯烃衍生单元，其中高级烯烃乙烯基封端聚合物基本上不含丙烯 单位; 并且其中所述较高级烯烃聚合物具有至少5％的烯丙基链末端及其生产方法。 这些乙烯基封端的较高级烯烃聚合物可以任选地包括乙烯衍生的单元。

公开(公告)号：US20190161560A1

公开(公告)日：2019-05-30

申请号：US16192493

申请日：2018-11-15

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Jian Yang ,  John R. Hagadorn ,  Gregory J. Karahalis ,  Timothy M. Boller ,  Evan J. Morris ,  Yan Jiang ,  Patrick Brant

IPC: C08F4/6592 ,  C08F4/659 ,  C08F4/649 ,  C08F210/02 ,  C08F210/14 ,  C08J5/18

Abstract: The present disclosure relates to asymmetric ansa-metallocene catalyst compounds that include at least one indenyl ligand substituted at the 3-position with a C3-C40 α-branched alkyl, such as 1-methylethyl, 1-methylpropyl, 1-methylbutyl, 1-ethylbutyl, 1,3-dimethylbutyl, 1-methyl-1-ethylbutyl, 1,1-diethylbutyl, 1-propylpentyl, and the like. Catalyst systems prepared with the catalyst compounds, polymerization methods using such catalyst systems, and polyolefins made using the polymerization methods are also described.

公开(公告)号：US20180305534A1

公开(公告)日：2018-10-25

申请号：US15774753

申请日：2016-09-16

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Jan Kalfus ,  Patrick Brant ,  Gabor Kiss ,  Abdul M. Jangda

IPC: C08L23/12

CPC classification number: C08L23/12 ,  C08L2205/025

Abstract: Provided are methods for making a polypropylene composition having a first polypropylene and second polypropylene, and compositions made therefrom. Also provided are bimodal polypropylene compositions having desirable flexural modulus and shear thinning properties.

公开(公告)号：US20170306135A1

公开(公告)日：2017-10-26

申请号：US15515045

申请日：2015-08-21

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Jan Kalfus ,  Patrick Brant ,  Peijun Jiang ,  Abdul M. Jangda

IPC: C08L23/12

CPC classification number: C08L23/12 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2207/02 ,  C08L2207/10 ,  C08L2314/02 ,  C08L23/14

Abstract: Disclosed is a method of forming a thermoplastic polyolefin composition, and the TPO itself, comprising discrete α-olefin copolymer domains within a continuous phase of polypropylene comprising combining within the range from 8 wt % to 60 wt % of the α-olefin copolymer, by weight of the thermoplastic polyolefin, and within the range from 92 wt % to 40 wt % of the polypropylene by weight of the thermoplastic polyolefin, wherein the complex viscosity of the α-olefin copolymer (CVα-olefin) and polypropylene (CVPP) satisfy the formula 0.2≦CVα-olefin/CVPP≦5 when the CVs are measured at the same frequency and temperature.

公开(公告)号：US20170253701A1

公开(公告)日：2017-09-07

申请号：US14898908

申请日：2014-06-30

Applicant: EXXONMOBIL CHEMICAL PATENTS INC.

Inventor： Andy H. Tsou ,  Donna J. Crowther ,  Man Kit Ng ,  Tabassumul Haque ,  Hong Cheng ,  Patrick Brant ,  Martin N. Webster ,  Yong Yang ,  Liehpao O. Farng ,  Rahul R. Kulkarni

IPC: C08G77/442

CPC classification number: C08G77/442 ,  C08F283/12 ,  C08F290/06 ,  C08G77/28 ,  C08G77/392 ,  C08L83/10 ,  C08L83/08 ,  C08L23/12

Abstract: Described herein is a comb-star poly(siloxane-polyolefin) comprising the reaction product of at least vinyl-terminated macromer and functional-poly(dialkylsiloxanes) comprising 2 or more functional groups, wherein the comb-star poly(siloxane-polyolefin) has the following features: a g′(vis avg) of less than 0.80; a comb number of 2 or 3 or 4 to 30 or 40 or 50 or 100 or more; and a number average molecular weight (Mn) within the range of from 25,000 g/mole to 500,000 g/mole.

公开(公告)号：US09657116B2

公开(公告)日：2017-05-23

申请号：US14900989

申请日：2014-06-30

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Man Kit Ng ,  David T. Ferrughelli ,  Hong Cheng ,  Emmanuel Ulysse ,  Donna J. Crowther ,  Edward A. Lemon, Jr. ,  Patrick Brant

IPC: C08F8/46

CPC classification number: C08F8/46 ,  C08F2810/30 ,  C08F2810/40 ,  C08F110/10 ,  C08F110/06 ,  C08F210/06 ,  C08F210/08 ,  C08F210/14

Abstract: Disclosed is a method of functionalizing a vinyl terminated polyolefin, the method comprising combining a vinyl terminated polyolefin and a α,β-unsaturated carbonyl compound at a temperature of at least 150° C. and a pressure of at least 14 psi, forming a functionalized polyolefin. The functionalized polyolefin comprises a compound or mixture of compounds represented the formula: wherein each R1 is, independently, selected from hydrogen and C1 to C4 or C10 alkyls; n is an integer from 2 to 800; and each X is, independently, a functional group derived from the α,β-unsaturated carbonyl compound.

公开(公告)号：US09051404B2

公开(公告)日：2015-06-09

申请号：US14086298

申请日：2013-11-21

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Peijun Jiang ,  Patrick Brant ,  David Aaron Henning ,  David Raymond Johnsrud ,  Charles Lewis Sims

IPC: C08L23/00 ,  C08F210/06 ,  C08F10/06 ,  C08L23/14 ,  C09J123/14

CPC classification number: C08F210/06 ,  C08F10/06 ,  C08L23/142 ,  C08L2666/06 ,  C09J123/142 ,  C08F2/001 ,  C08F210/14 ,  C08F2500/17 ,  C08F2500/09 ,  C08F2500/20 ,  C08F2500/11 ,  C08F2500/21

Abstract: Disclosed herein is an in-reactor produced multi-component copolymer comprises a semi-crystalline component having a crystallinity of 20% or more, and an amorphous component having a crystallinity of 5% or less. The copolymer comprises at least 80 wt % of units derived from propylene and from about 1 to about 20 wt % of units derived from at least one C6 to C12 alpha-olefin. The copolymer has a viscosity at 190° C. of at least 530 mPa sec and a heat of fusion between about 10 and about 70 J/g. An adhesive containing the copolymer exhibits a good balance of adhesive properties and mechanical strength.

Abstract translation: 本文公开了一种反应器内生产的多组分共聚物，其包含结晶度为20％以上的半结晶成分和结晶度为5％以下的无定形成分。 共聚物包含至少80重量％的衍生自丙烯的单元和约1至约20重量％的衍生自至少一个C 6至C 12α-烯烃的单元。 共聚物在190℃下的粘度至少为530mPa·s，熔融热在约10至约70J / g之间。 含有共聚物的粘合剂显示良好的粘合性能和机械强度的平衡。

公开(公告)号：US08841397B2

公开(公告)日：2014-09-23

申请号：US13628296

申请日：2012-09-27

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Matthew W. Holtcamp ,  Charles J. Ruff ,  Donna J. Crowther ,  John R. Hagadorn ,  Patrick Brant

IPC: C08F10/14 ,  C08F210/02 ,  C08F210/08

CPC classification number: C08F10/14 ,  C08F4/65908 ,  C08F4/65925 ,  C08F110/14 ,  C08F4/65927 ,  C08F210/14

Abstract: This invention relates to higher olefin vinyl terminated polymers having an Mn of at least 200 g/mol (measured by 1H NMR) including of one or more C4 to C40 higher olefin derived units, where the higher olefin vinyl terminated polymer comprises substantially no propylene derived units; and wherein the higher olefin polymer has at least 5% allyl chain ends and processes for the production thereof. These vinyl terminated higher olefin polymers may optionally include ethylene derived units.

Abstract translation: 本发明涉及具有至少200g / mol（通过1 H NMR测量）的Mn的高级烯烃乙烯基封端聚合物，其包含一个或多个C 4至C 40高级烯烃衍生单元，其中高级烯烃乙烯基封端聚合物基本上不含丙烯 单位; 并且其中所述较高级烯烃聚合物具有至少5％的烯丙基链末端及其生产方法。 这些乙烯基封端的较高级烯烃聚合物可以任选地包括乙烯衍生的单元。