公开(公告)号：US20110021722A1

公开(公告)日：2011-01-27

申请号：US12894905

申请日：2010-09-30

申请人： Hideyuki Takai ,  Hiroyuki Hirakawa

发明人： Hideyuki Takai ,  Hiroyuki Hirakawa

IPC分类号： C08L63/00

CPC分类号： C08L67/02 ,  B33Y70/00 ,  C08G59/24 ,  C08G59/4215 ,  C08K5/0025 ,  C08K5/09 ,  C08L63/00 ,  C08L69/00 ,  H01L23/293 ,  H01L31/0203 ,  H01L2924/0002 ,  C08L2666/18 ,  C08L2666/22 ,  H01L2924/00

摘要： A liquid thermosetting epoxy resin composition contains a base resin in combination with a curing agent and a curing accelerator or with a curing catalyst. The base resin includes a cycloaliphatic epoxy compound having at least one alicyclic skeleton and two or more epoxy groups per molecule, and a polyol oligomer having two or more terminal hydroxyl groups. An optical semiconductor device includes an optical semiconductor element sealed by using the liquid thermosetting epoxy resin composition. The composition yields a cured resinous product which is free from curing failure, is optically homogenous, has a low elastic modulus in bending, a high bending strength, a high glass transition temperature, a high optical transparency and is useful for optical semiconductors.

摘要翻译： 液态热固性环氧树脂组合物含有与固化剂和固化促进剂或固化催化剂组合的基础树脂。 基础树脂包括每分子具有至少一个脂环骨架和两个或更多个环氧基团的脂环族环氧化合物和具有两个或更多个末端羟基的多元醇低聚物。 光学半导体器件包括通过使用液态热固性环氧树脂组合物密封的光学半导体元件。 该组合物产生无固化失效的固化树脂产品，光学上均匀，弯曲时具有低弹性模量，高弯曲强度，高玻璃化转变温度，高光学透明度，并且可用于光学半导体。

公开(公告)号：US20100249341A1

公开(公告)日：2010-09-30

申请号：US12305906

申请日：2007-06-29

申请人： Atsushi Sato ,  Hideyuki Takai ,  Hisashi Maeshima ,  Kyuhei Kitao

发明人： Atsushi Sato ,  Hideyuki Takai ,  Hisashi Maeshima ,  Kyuhei Kitao

IPC分类号： C08G59/02 ,  C07D303/04

CPC分类号： C07D303/04 ,  B33Y70/00 ,  C08G59/24 ,  C08L63/00

摘要： Disclosed is an alicyclic diepoxy compound which gives a cured article suffering from no deterioration in properties even when used in hot and humid surroundings or used under such conditions as to give a strong acid, which is highly reactive upon curing, and which gives a cured article superior typically in thermal stability. Specifically, the alicyclic diepoxy compound includes a 3,4,3′,4′-diepoxybicyclohexyl compound represented by following Formula (1): wherein R1 to R18 each represent a hydrogen atom, a halogen atom, a hydrocarbon group which may have an oxygen atom or a halogen atom, or a substituted or unsubstituted alkoxy group, in which the alicyclic diepoxy compound contains isomers of the 3,4,3′,4′-diepoxybicyclohexyl compound in a content of less than 20% based on the total of the 3,4,3′,4′-diepoxybicyclohexyl compound and the isomers thereof in terms of peak area ratio as determined by gas chromatography.

摘要翻译： 公开了一种脂环式二环氧化合物，即使在热湿环境下使用也不会劣化的固化物，或者在固化时具有高反应性的强酸的条件下使用，得到固化物 优良的热稳定性。 具体地，脂环族二环氧化合物包括由下式（1）表示的3,4,3'，4'-二环氧双环己基化合物：其中R 1至R 18各自表示氢原子，卤素原子，可具有氧的烃基 原子或卤素原子或取代或未取代的烷氧基，其中脂环式二环氧化合物含有3,4,3'，4'-二环氧基双环己基化合物的异构体，其含量小于20％ 3,4,3'，4'-二环氧双环己基化合物及其异构体，以气相色谱法测定的峰面积比。

公开(公告)号：US07786224B2

公开(公告)日：2010-08-31

申请号：US10883162

申请日：2004-07-01

申请人： Hideyuki Takai

发明人： Hideyuki Takai

IPC分类号： C08G59/48 ,  C08L63/00 ,  C07D301/14

CPC分类号： C07D303/22 ,  C07D303/16 ,  C08G59/226 ,  C08G59/24 ,  C08G59/38 ,  C09D163/00 ,  G03F7/038 ,  Y10T428/31511

摘要： A liquid epoxy resin composition of an epoxy resin, a curing agent, and a curing accelerator, where the epoxy resin is an alicyclic epoxy compound present in an amount from 100 to 30% by weight. The alicyclic epoxy compound is preferably produced by using a percarboxylic acid having a water content of 2% by weight. The curing agent is preferably a liquid acid anhydride.

摘要翻译： 一种环氧树脂，固化剂和固化促进剂的液体环氧树脂组合物，其中环氧树脂是以100至30重量％的量存在的脂环族环氧化合物。 脂环族环氧化合物优选通过使用水含量为2重量％的过羧酸来制备。 固化剂优选为液体酸酐。

公开(公告)号：US07781543B2

公开(公告)日：2010-08-24

申请号：US12314222

申请日：2008-12-05

申请人： Hisashi Maeshima ,  Hideyuki Takai

发明人： Hisashi Maeshima ,  Hideyuki Takai

IPC分类号： C08L63/00 ,  C08L63/04

CPC分类号： C07D303/04 ,  C07D301/14 ,  C08G59/027 ,  C08G59/24

摘要： An alicyclic diepoxy compound (A) represented by formula (I) is produced in high purity and high yield at low cost, by epoxidizing the corresponding alicyclic diolefin compound with an organic percarboxylic acid. The curable epoxy resin composition has high reactivity for various curing agents, low viscosity, and excellent workability. A cured product thereof shows useful physical properties for uses in coatings, inks, adhesives, sealants, and encapsulants, etc. It is of extremely high quality as an epoxy resin composition for the encapsulation of electronic parts. A stabilizer for an electrical insulating oil (the alicyclic diepoxy compound or an electrical insulting oil containing the compound) is low in acid value, and the stabilizer improves the properties of the insulating oil. A cured product obtained by curing a casting epoxy resin composition for electrical insulation has excellent properties such as high bending strength, high Tg, and low permittivity.

摘要翻译： 通过用有机过羧酸将相应的脂环族二烯烃化合物环氧化，以低成本制备高纯度和高收率的由式（I）表示的脂环族二环氧化合物（A）。 可固化环氧树脂组合物对各种固化剂具有高反应性，低粘度和优异的可加工性。 其固化产物显示出用于涂料，油墨，粘合剂，密封剂和密封剂等中的有用的物理性能。作为用于电子部件的封装的环氧树脂组合物具有极高的质量。 用于电绝缘油（脂环族二环氧化合物或含有该化合物的电绝缘油）的稳定剂的酸值低，稳定剂改善了绝缘油的性能。 通过固化用于电绝缘的铸塑环氧树脂组合物获得的固化产物具有优异的性能，例如高弯曲强度，高Tg和低介电常数。

公开(公告)号：US20090124776A1

公开(公告)日：2009-05-14

申请号：US11666943

申请日：2005-11-28

申请人： Hideyuki Takai

发明人： Hideyuki Takai

IPC分类号： C08F234/02 ,  C08F34/02 ,  C07C303/40

CPC分类号： C07D301/06 ,  C07D301/12 ,  C07D303/06 ,  C07D303/17 ,  C07D303/31 ,  C07D303/32 ,  C07D303/48 ,  C08F8/14 ,  C08F8/18 ,  C08F212/08 ,  C08F220/32 ,  C08F222/40

摘要： There are provided a novel compound having an 3,4-epoxytricyclo[5.2.1.02,6]decane skeleton and a polymerizable unsaturated bond, and a process for the preparation of the compound.There is also provided a copolymer including a monomeric unit (A) containing an alkali-soluble group, and a monomeric unit (B) corresponding to an epoxy-containing polymerizable unsaturated compound, or a copolymer including, in addition to the monomeric units (A) and (B), a monomeric unit (C) corresponding to an epoxy-free polymerizable unsaturated compound such as a N-substituted maleimide, in which the monomeric unit (B) occupies 40 to 90 percent by weight of total monomeric units, and 30 percent by weight or more of the monomeric unit (B) is a monomeric unit corresponding to a specific 3,4-epoxytricyclo[5.2.1.02,6]decane skeleton-containing compound. The copolymer can yield a film excellent typically in thermal stability, yield a resin composition having very high storage stability, and be easily synthetically prepared.

摘要翻译： 提供了具有3,4-环氧三环[5.2.1.02,6]癸烷骨架和可聚合不饱和键的新化合物及其制备方法。 还提供了包含含有碱溶性基团的单体单元（A）和对应于含环氧基的可聚合不饱和化合物的单体单元（B）的共聚物，或包含除单体单元（A ）和（B）中，单体单元（C）对应于不含环氧基的可聚合不饱和化合物如N-取代马来酰亚胺，其中单体单元（B）占总单体单元的40〜90重量％，以及 单体单元（B）的30重量％以上是对应于特定的3,4-环氧三环[5.2.1.02,6]癸烷骨架的化合物的单体单元。 共聚物可以产生通常在热稳定性方面优异的膜，产生具有非常高的储存稳定性的树脂组合物，并且可以容易地合成制备。

公开(公告)号：US20070179256A1

公开(公告)日：2007-08-02

申请号：US10590847

申请日：2005-03-16

申请人： Kyuhei Kitao ,  Hideyuki Takai

发明人： Kyuhei Kitao ,  Hideyuki Takai

IPC分类号： C08L63/00 ,  C08G65/00 ,  B32B27/38

CPC分类号： C07D303/04 ,  C07D303/34

摘要： The present invention provides a high-purity alicyclic epoxy compound in which an alicyclic olefin compound is epoxidized with an aliphaticpercarboxylic acid having substantially no water followed by the removal of a solvent to produce an alicyclic epoxy compound represented by the general formula (I) that is in turn subjected to purification by distillation to thereby the high-purity alicyclic epoxy compound wherein the concentration of high-molecular-weight components having an elution time shorter than that of the alicyclic epoxy compound in detection by a GPC analysis is 5.5% or less in terms of the area ratio, the concentration of impurities having a retention time shorter than that of the alicyclic epoxy compound in detection by a GC analysis is 19.5% or less in terms of the area ratio, the concentration of reactive intermediates is 4.5% or less in terms of the area ratio, and a color hue (APHA) is 60 or less; a process of efficiently producing the same by the use of a low-toxicity solvent; a curable resin composition using the same; a cured product; and applications.

摘要翻译： 本发明提供了一种高纯度脂环族环氧化合物，其中脂肪族烯烃化合物被基本上不含水的脂肪族过羧酸环氧化，然后除去溶剂，得到通式（I）表示的脂环族环氧化合物，即 然后通过蒸馏进行纯化，由此得到其中通过GPC分析检测的洗脱时间比脂环族环氧化合物的洗脱时间短的高分子量组分的浓度为5.5％以下的高纯度脂环式环氧化合物的浓度为5.5％以下 通过GC分析检测的面积比的术语，保留时间比脂环族环氧化合物的保留时间短的杂质浓度在面积比方面为19.5％以下，反应性中间体的浓度为4.5％以下 在面积比方面，色调（APHA）为60以下; 通过使用低毒溶剂有效地制备该方法的方法; 使用其的可固化树脂组合物; 固化产品; 和应用程序。

公开(公告)号：US20060194933A1

公开(公告)日：2006-08-31

申请号：US10567253

申请日：2004-08-23

申请人： Hideyuki Takai ,  Hisashi Maeshima

发明人： Hideyuki Takai ,  Hisashi Maeshima

IPC分类号： C08L63/00 ,  B32B27/38

CPC分类号： C08G59/24

摘要： A thermosetting resin composition of this invention contains 100 parts by weight of composition (E), 0.01 to 20 parts by weight of a cationic polymerization initiator (C), and, where necessary, 50 parts by weight or less of an epoxy-containing acrylic resin (D), the composition (E) contains 10 to 99 percent by weight of an ester-free alicyclic epoxy compound (A), and 90 to 1 percent by weight of an epoxy compound (B) differing from (A). A cured article thereof is excellent in heat resistance, dimensional stability, and optical transparency and can be used as a replacement for glass substrates.

摘要翻译： 本发明的热固性树脂组合物含有组合物（E）100重量份，阳离子聚合引发剂（C）0.01〜20重量份，必要时含有环氧基丙烯酸酯50重量份 树脂（D）中，组合物（E）含有10〜99重量％的无酯脂环族环氧化合物（A）和90〜1重量％的不同于（A）的环氧化合物（B）。 其固化物的耐热性，尺寸稳定性和光学透明性优异，可用作玻璃基板的替代品。

公开(公告)号：US20060009547A1

公开(公告)日：2006-01-12

申请号：US10526672

申请日：2003-09-04

申请人： Hisashi Maeshima ,  Hideyuki Takai

发明人： Hisashi Maeshima ,  Hideyuki Takai

IPC分类号： C08G59/38 ,  C08L63/00

CPC分类号： C07D303/04 ,  C07D301/14 ,  C08G59/027 ,  C08G59/24

摘要： According to the present invention (1), an alicyclic diepoxy compound represented by the following general formula (I): can be produced in high purity and high yields at low cost, by epoxidizing the corresponding alicyclic diolefin compound with an organic percarboxylic acid. As the alicyclic diepoxy compound lacks an ester group in the molecule, it will show high reactivity for a cationic catalyst. Besides, when it is used as a curable epoxy resin composition of the present invention (2), it will show an effect of lowering its curing temperature or reducing its curing time. The curable epoxy resin composition has high reactivity for various curing agents, low viscosity, and excellent workability. Moreover, the curable resin composition is also superior in that it has less effect to working surroundings, and a cured product thereof shows useful physical properties for the uses in coatings, ink, adhesives, sealants, encapsulants, and the like. Furthermore, as a resin composition of the present invention (3) shows a low coefficient of water absorption, it is of extremely high quality as an epoxy resin composition for the encapsulation of electronic parts. In addition, a stabilizer for an electrical insulating oil of the present invention (4) (i.e., the alicyclic diepoxy compound or an electrical insulating oil containing such a compound) is low in acid value, and the stabilizer improves the properties of the insulating oil. In addition, a cured product obtained by curing a casting epoxy resin composition for electrical insulation of the present invention (5) has excellent properties such as high bending strength, high Tg, and low permittivity.

摘要翻译： 根据本发明（1），通过用有机过羧酸将相应的脂环族二烯烃化合物环氧化，可以低成本地以高纯度和高产率制备由以下通式（I）表示的脂环族二环氧化合物。 由于脂环族二环氧化合物在分子中缺少酯基，因此阳离子催化剂的反应性将会很高。 此外，当用作本发明（2）的可固化环氧树脂组合物时，将显示降低其固化温度或降低其固化时间的效果。 可固化环氧树脂组合物对各种固化剂具有高反应性，低粘度和优异的可加工性。 此外，可固化树脂组合物的优点在于其对周围环境的影响较小，并且其固化产物显示出用于涂料，油墨，粘合剂，密封剂，密封剂等中的有用的物理性能。 此外，作为本发明（3）的树脂组合物，由于吸水率低，所以作为电子部件的密封用的环氧树脂组合物的质量非常高。 此外，本发明的电绝缘油（4）（即脂环族二环氧化合物或含有这种化合物的电绝缘油）的稳定剂的酸值低，稳定剂改善了绝缘油的性能 。 此外，通过固化本发明（5）的电绝缘用浇注型环氧树脂组合物而得到的固化物具有优异的性能，例如高弯曲强度，高Tg，低介电常数。

公开(公告)号：US5622799A

公开(公告)日：1997-04-22

申请号：US345702

申请日：1994-11-21

申请人： Koichi Suzuki ,  Hideyuki Takai ,  Satomi Sugiyama ,  Mitsuhiro Kunieda

发明人： Koichi Suzuki ,  Hideyuki Takai ,  Satomi Sugiyama ,  Mitsuhiro Kunieda

IPC分类号： G03G5/06 ,  G03G5/047

CPC分类号： G03G5/0683

摘要： An electrophotographic photosensitive member, a process cartridge having the electrophotographic photosensitive member and an electrophotographic apparatus are provided. The electrophotographic photosensitive member has a conductive substrate and a photosensitive layer thereon, wherein the photosensitive layer contains a disazo pigment represented by the following formula (1): ##STR1## wherein R.sub.1 to R.sub.8 are the same or different and are each a hydrogen atom, a halogen atom, an alkyl group or an alkoxy group, n is a positive integer, A.sub.1 and A.sub.2 are the same or different and are each a coupler residual group having a phenolic hydroxyl group, and at least one of A.sub.1 and A.sub.2 is a coupler residual group represented by the following formula (2): ##STR2## wherein X.sub.1 is a residual group forming a polycyclic aromatic ring or a heterocyclic ring by condensing with a benzene ring, R.sub.9 and R.sub.10 are the same or different and are each a hydrogen atom, an alkyl group, an aryl group, an aralkyl group, a heterocyclic group or a residual group forming a cyclic amino group by bonding together, and Z.sub.1 is an oxygen atom or a sulfur atom.

摘要翻译： 提供电子照相感光构件，具有电子照相感光构件的处理盒和电子照相设备。 电子照相感光构件具有导电性基材及感光层，感光层含有下述式（1）表示的双偶氮颜料：其中，R 1〜R 8相同或不同，为 氢原子，卤素原子，烷基或烷氧基，n为正整数，A1和A2相同或不同，分别为具有酚羟基的成色剂残基，A1和A2中的至少一个 （2）表示的成色剂残基：其中X1是通过与苯环缩合形成多环芳环或杂环的残基，R9和R10相同或不同 各自为氢原子，烷基，芳基，芳烷基，杂环基或通过键合而形成环状氨基的残基，Z1为氧原子或硫原子。

公开(公告)号：US5194354A

公开(公告)日：1993-03-16

申请号：US555763

申请日：1990-07-23

申请人： Hideyuki Takai ,  Kazushi Iuchi ,  Itaru Yamazaki ,  Hajime Miyazaki

发明人： Hideyuki Takai ,  Kazushi Iuchi ,  Itaru Yamazaki ,  Hajime Miyazaki

IPC分类号： C09B47/04 ,  C09B67/12 ,  C09B67/50 ,  G03G5/06

CPC分类号： C09B67/0016 ,  C09B67/0026 ,  G03G5/0696

摘要： There are disclosed low crystalline oxytitanium phthalocyanines which have characteristic strong peaks at specific angles of Bragg angle 2.theta..+-.0.2.degree.. Using the low crystalline oxytitanium phthalocyanines, it is easy to obtain oxytitanium phthalocyanines having novel crystal forms. Electrophotographic photosensitive member containing the oxytitanium phthalocyanines having novel crystal forms have a very high photosensitivity to beams of long wavelength, a ver high potential stability as well as excellent durability in repetitive use.

摘要翻译： 公开了在布拉格角2θ+/- 0.2°的特定角度下具有特征强峰的低结晶氧钛酞菁。 使用低结晶性氧钛酞菁，容易得到具有新晶体形式的氧钛酞菁。 含有具有新晶体形式的氧钛酞菁的电子照相感光构件对长波长的光束具有非常高的光敏性，高的电位稳定性以及重复使用的优异的耐久性。