公开(公告)号：US6083651A

公开(公告)日：2000-07-04

申请号：US160179

申请日：1998-09-25

申请人： Tohru Kobayashi ,  Yoshimasa Matsushima ,  Hiroshi Sugiyama ,  Toshimitsu Hagiwara

发明人： Tohru Kobayashi ,  Yoshimasa Matsushima ,  Hiroshi Sugiyama ,  Toshimitsu Hagiwara

IPC分类号： C07D265/38 ,  C07D279/22 ,  G03G5/06 ,  G03G5/04

CPC分类号： C07D279/22 ,  C07D265/38 ,  G03G5/0631

摘要： A phenothiazine or phenoxazine derivative represented by the following general formula (1), a charge-transporting material comprising the derivative, and an electrophotographic photoreceptor containing the charge-transporting material are disclosed. The charge-transporting material has good solubility in binder polymers, satisfactory sensitivity, and a low residual potential. ##STR1##

摘要翻译： 公开了由以下通式（1）表示的吩噻嗪或吩恶嗪衍生物，包含该衍生物的电荷输送材料和含有电荷输送材料的电子照相感光体。 电荷输送材料在粘合剂聚合物中具有良好的溶解性，令人满意的灵敏度和低残留电位。

公开(公告)号：US5981771A

公开(公告)日：1999-11-09

申请号：US100755

申请日：1998-06-22

申请人： Yoshiki Okeda ,  Yoji Hori ,  Toshimitsu Hagiwara

发明人： Yoshiki Okeda ,  Yoji Hori ,  Toshimitsu Hagiwara

IPC分类号： C07D305/12 ,  B01J31/24 ,  C07B53/00 ,  C07B61/00 ,  C07D315/00 ,  C07F15/00

CPC分类号： B01J31/2452 ,  C07D315/00 ,  C07F15/0053 ,  B01J2231/645 ,  B01J2531/0266 ,  B01J2531/821 ,  B01J31/2208 ,  B01J31/2295 ,  C07B2200/07

摘要： The present invention provides a catalyst which exhibits a high catalytic activity and allows asymmetric reaction in a high asymmetric yield to obtain a reaction product having a high optical purity. The present invention also provides a process for the preparation of an optically active 4-methyl-2-oxetanone having a high optical purity useful as starting material of polymer in a high yield in a short period in the presence of the foregoing catalyst. A novel ruthenium-iodo-optically active phosphine complex is provided, represented by the following general formula (1):Ru--I.sub.2 -(R.sup.1 -BINAP) (1)wherein R.sup.1 -BINAP represents an optically active tertiary phosphine represented by the following general formula (2): ##STR1## wherein R.sup.1 represents an aryl group which may have a substituent selected from the group consisting of a C.sub.1-4 lower alkyl group, a C.sub.1-4 lower alkoxy group, a C.sub.1-4 lower alkylamino group, and a halogen atom or a C.sub.3-8 cycloalkyl group.

摘要翻译： 本发明提供一种催化活性高的催化剂，能够以不对称产率进行不对称反应，得到光学纯度高的反应产物。 本发明还提供了在上述催化剂存在下，在短时间内以高收率制备具有高光学纯度的光学纯度高的光学活性4-甲基-2-氧杂环丁酮的方法。 提供了由以下通式（1）表示的新型钌 - 碘 - 光学活性膦配合物：Ru-I2-（R1-BINAP）（1）其中R1-BINAP表示由以下通式表示的光学活性叔膦 式（2）：其中R1表示可以具有选自C 1-4低级烷基，C 1-4低级烷氧基，C 1-4低级烷基氨基和卤素原子的取代基的芳基 或C 3-8环烷基。

公开(公告)号：US5882813A

公开(公告)日：1999-03-16

申请号：US893000

申请日：1997-07-15

申请人： Yoshimasa Matsushima ,  Tohru Kobayashi ,  Hiroshi Sugiyama ,  Yoko Takahashi ,  Toshimitsu Hagiwara

发明人： Yoshimasa Matsushima ,  Tohru Kobayashi ,  Hiroshi Sugiyama ,  Yoko Takahashi ,  Toshimitsu Hagiwara

IPC分类号： G03G5/06 ,  G03G5/047

CPC分类号： G03G5/0668 ,  G03G5/0614 ,  G03G5/0616 ,  G03G5/0666 ,  G03G5/0672

摘要： An electrophotographic photoreceptor comprising a charge transporting material containing at least one triphenylamine compound represented by general formula (1) and at least one compound selected from the group consisting of a hydrazone compound, a triphenylamine dimer compound and a distyryl compound: ##STR1## said charge transporting material being able to express high carrier mobility, being high in solubility in a binder polymer, and being able to form a homogeneous charge transporting layer.

摘要翻译： 一种电子照相感光体，包含含有至少一种由通式（1）表示的三苯胺化合物和至少一种选自腙化合物，三苯胺二聚体化合物和二苯乙烯基化合物的化合物的电荷输送材料： ）+ TR 所述电荷输送材料能够表现出高的载流子迁移率，在粘合剂聚合物中的溶解度高，并且能够形成均匀的电荷输送层。

公开(公告)号：US5716542A

公开(公告)日：1998-02-10

申请号：US637284

申请日：1996-04-24

申请人： Yukiharu Iwaya ,  Mamoru Yamada ,  Hitoshi Kondo ,  Toshimitsu Hagiwara

发明人： Yukiharu Iwaya ,  Mamoru Yamada ,  Hitoshi Kondo ,  Toshimitsu Hagiwara

IPC分类号： C07D213/30 ,  C07D237/08 ,  C07D239/26 ,  C07D241/12 ,  C09K19/02 ,  C09K19/34 ,  C07D213/24 ,  C07D239/02 ,  C09K19/30

CPC分类号： C07D213/30 ,  C07D237/08 ,  C07D239/26 ,  C07D241/12 ,  C09K19/0266 ,  C09K19/3444 ,  C09K19/3452 ,  C09K19/3455 ,  C09K19/3463

摘要： A liquid crystal compound represented by formula (I) and a liquid crystal composition containing the same. The compound exhibits an antiferroelectric liquid crystal phase and has good compatibility with known liquid crystal compounds. ##STR1## wherein R.sup.1 represents a straight-chain or branched alkyl, alkoxy, alkoxycarbonyl, alkanoyloxy or alkoxycarbonyloxy group having 4 to 16 carbon atoms; R.sup.2 represents a straight-chain alkyl group having 4 to 10 carbon atoms or a branched alkyl group containing 1 to 3 carbon atoms in its branch and 4 to 12 carbon atoms in total; X represents an oxygen or sulfur atom; rings A and B each represent an F-substituted or unsubstituted phenylene group, a cyclohexylene group or a divalent nitrogen-containing heterocyclic group, provided that either one of rings A and B is the nitrogen-containing heterocyclic group; ring C represents an F-substituted or unsubstituted phenylene group; and C* represents an asymmetric carbon atom.

摘要翻译： 由式（I）表示的液晶化合物和含有该液晶化合物的液晶组合物。 该化合物表现出反铁电液晶相，与已知的液晶化合物具有良好的相容性。 （I）其中R1表示具有4至16个碳原子的直链或支链烷基，烷氧基，烷氧基羰基，烷酰氧基或烷氧基羰氧基; R2表示碳原子数为4〜10的直链烷基或碳原子数为1〜3的支链烷基，总共为4〜12个碳原子。 X表示氧或硫原子; 环A和B各自表示F取代或未取代的亚苯基，亚环己基或二价含氮杂环基，条件是环A和B中的任一个为含氮杂环基; 环C表示F取代或未取代的亚苯基; C *表示不对称碳原子。

公开(公告)号：US5475517A

公开(公告)日：1995-12-12

申请号：US173484

申请日：1993-12-27

申请人： Toshimitsu Konuma ,  Takeshi Nishi ,  Akira Sugawara ,  Yoshimasa Matsushima ,  Hitoshi Kondo ,  Toshimitsu Hagiwara

发明人： Toshimitsu Konuma ,  Takeshi Nishi ,  Akira Sugawara ,  Yoshimasa Matsushima ,  Hitoshi Kondo ,  Toshimitsu Hagiwara

IPC分类号： G02F1/1337 ,  G02F1/137 ,  G02F1/141 ,  G02F1/13

CPC分类号： G02F1/1416 ,  G02F2001/133757

摘要： A ferroelectric liquid crystal device is described. The device comprises a pair of substrates, an electrode arrangement formed on the inside surface of the substrates, an orientation control surface provided on the inside surface of one of said substrates, and a blended ferroelectric liquid crystal disposed between the substrates. By suitably preparing the liquid crystal, multi-micro-domains are formed in the liquid crystal. By virtue of the multi-micro-domains, the contrast ratio and the response speed are significantly improved.

摘要翻译： 描述铁电液晶装置。 该装置包括一对基板，形成在基板的内表面上的电极装置，设置在所述基板之一的内表面上的取向控制表面和设置在基板之间的混合铁电液晶。 通过适当制备液晶，在液晶中形成多微畴。 凭借多微域，对比度和响应速度显着提高。

公开(公告)号：US5443933A

公开(公告)日：1995-08-22

申请号：US118823

申请日：1993-09-10

申请人： Kenichi Fujimori ,  Yoshitaro Nakayama ,  Takumi Shinohara ,  Atsushi Iwanami ,  Toshimitsu Hagiwara ,  Tohru Kobayashi

发明人： Kenichi Fujimori ,  Yoshitaro Nakayama ,  Takumi Shinohara ,  Atsushi Iwanami ,  Toshimitsu Hagiwara ,  Tohru Kobayashi

IPC分类号： G03G5/06 ,  G03G5/047 ,  G03G5/05

CPC分类号： G03G5/0517 ,  G03G5/047

摘要： An electrophotographic photoreceptor which is highly sensitive to light having a wavelength in the oscillatory wavelength region of semiconductor laser and responds quickly and is excellent in other electrophotographic characteristics and which consists an electroconductive support, a charge-generating layer and a charge-transfer layer, the two layers being placed on the support, and said charge-transfer layer containing a specific butadiene compound having formula (I); ##STR1## and a monophenol type antioxidant, the weight ratio of the monophenol type antioxidant/the butadiene compound ranging from 5/95 to 40/80.

摘要翻译： 对半导体激光器的振荡波长区域的波长高度敏感的电子照相感光体，快速响应并且其它电子照相特性优异，并且由导电性支持体，电荷产生层和电荷转移层组成， 两层放置在载体上，所述电荷转移层含有具有式（I）的特定丁二烯化合物; （I）和单酚型抗氧化剂，单酚型抗氧化剂/丁二烯化合物的重量比为5/95至40/80。

公开(公告)号：US06515188B2

公开(公告)日：2003-02-04

申请号：US10115096

申请日：2002-04-04

申请人： Akira Amano ,  Teruyoshi Akiyama ,  Takashi Miura ,  Toshimitsu Hagiwara

发明人： Akira Amano ,  Teruyoshi Akiyama ,  Takashi Miura ,  Toshimitsu Hagiwara

IPC分类号： C07C523

CPC分类号： C07C41/26 ,  C07B2200/07 ,  C07C41/03 ,  C07C41/42 ,  C07C67/11 ,  C07C2601/14 ,  C07C69/16 ,  C07C69/08 ,  C07C43/196

摘要： A method for safely and efficiently producing high purity 3-l-menthoxypropane-1,2-diol and intermediates to be used in the method. As shown in the following reaction formula, 3-l-menthoxypropane-1,2-diol represented by the chemical formula (IV) is produced by adding l-menthol to a 1,2-epoxy-3-halogenopropane represented by the general formula (I) (wherein X represents a halogen atom) in an organic solvent in the presence of a Lewis acid, thereby producing a 1-halogeno-3-l-menthoxypropan-2-ol represented by the general formula (II), allowing the first intermediate to react with an alkali metal salt of an aliphatic carboxylic acid having from 1 to 5 carbon atoms to produce a 1-acyloxy-2-substituted-3-l-menthoxypropane represented by the general formula (III) and then hydrolyzing the second intermediate.

公开(公告)号：US06323174B1

公开(公告)日：2001-11-27

申请号：US09571549

申请日：2000-05-16

申请人： Mitsuhiko Fujiwhara ,  Takenobu Nishikawa ,  Yoji Hori ,  Toshimitsu Hagiwara ,  Hisao Iwai ,  Takashi Miura

发明人： Mitsuhiko Fujiwhara ,  Takenobu Nishikawa ,  Yoji Hori ,  Toshimitsu Hagiwara ,  Hisao Iwai ,  Takashi Miura

IPC分类号： A61K746

CPC分类号： C11B9/0019 ,  C07C2/04 ,  C07C45/54 ,  C07C47/21 ,  C07C67/293 ,  C07C2531/22 ,  C11B9/0007 ,  C07C11/12 ,  C07C69/007 ,  C07C69/145 ,  C07C69/16 ,  C07C69/24

摘要： The invention provides a chain diene compound with desirable regioselectivity, in the presence of a specific ruthenium compound. This chain diene compound is a promising raw material for terpene. It has a structure represented by the general formula (I): wherein R1 represents H, a C1-C6 alkyl group which may be substituted or a C2-C6 alkenyl group which may be substituted, R2 represents a phenyl group which may have a C1-C4 alkyl group or a C1-C12 acyloxy group which may have a phenyl group or a naphthyl group, or a benzyl group or R2 is a hydroxy group which reversibly forms an aldehyde group through shifting of the position of the double bond adjacent to said hydroxy group. The chain diene compound is produced by reacting 2-substituted-1,3-butadienes with terminal olefins in the presence of a ruthenium compound in a hydrophilic solvent. Further, the above method provides an inexpensive process for preparing a mild fragrant component and a perfume composition, such as 4-methyl-5-hexen-1-al and 4-vinyl-8-methyl-7-nonenal.

摘要翻译： 在特定的钌化合物的存在下，本发明提供具有理想的区域选择性的链二烯化合物。 该链二烯化合物是萜烯的有希望的原料。 它具有由通式（I）表示的结构：其中R1表示H，可被取代的C1-C6烷基或可被取代的C2-C6烯基，R2表示可具有C1 -C4烷基或可以具有苯基或萘基的C1-C12酰氧基或苄基，或R2是通过使所述双键邻近的所述双键移位而可逆地形成醛基的羟基 羟基。 链二烯化合物通过在亲水性溶剂中在钌化合物的存在下使2-取代-1,3-丁二烯与末端烯烃反应制备。 此外，上述方法提供了用于制备温和香料组分和香料组合物的廉价方法，例如4-甲基-5-己烯-1-醇和4-乙烯基-8-甲基-7-壬烯醛。

公开(公告)号：US06239324B1

公开(公告)日：2001-05-29

申请号：US09383920

申请日：1999-08-26

申请人： Mitsuhiko Fujiwhara ,  Takenobu Nishikawa ,  Yoji Hori ,  Toshimitsu Hagiwara ,  Hisao Iwai ,  Takashi Miura

发明人： Mitsuhiko Fujiwhara ,  Takenobu Nishikawa ,  Yoji Hori ,  Toshimitsu Hagiwara ,  Hisao Iwai ,  Takashi Miura

IPC分类号： C07C202

CPC分类号： C11B9/0019 ,  C07C2/04 ,  C07C45/54 ,  C07C47/21 ,  C07C67/293 ,  C07C2531/22 ,  C11B9/0007 ,  C07C11/12 ,  C07C69/007 ,  C07C69/145 ,  C07C69/16 ,  C07C69/24

摘要： The invention provides a chain diene compound with desirable regioselectivity, in the presence of a specific ruthenium compound. This chain diene compound is a promising raw material for terpene. It has a structure represented by the general formula (IX): wherein R1 represents H, a C1-C6 alkyl group which may be substituted or a C2-C6 alkenyl group which may be substituted, R2 represents a phenyl group which may have a C1-C4 alkyl group or a C1-C12 acyloxy group which may have a phenyl group or a naphthyl group, or a benzyl group or R2 is a hydroxy group which reversibly forms an aldehyde group through shifting of the position of the double bond adjacent to said hydroxy group. The chain diene compound is produced by reacting 2-substituted-1,3-butadienes with terminal olefins in the presence of a ruthenium compound in a hydrophilic solvent. Further, the above method provides an inexpensive process for preparing a mild fragrant component and a perfume composition, such as 4-methyl-5-hexen-1-al and 4-vinyl-8-methyl-7-nonenal.

摘要翻译： 在特定的钌化合物的存在下，本发明提供具有理想的区域选择性的链二烯化合物。 该链二烯化合物是萜烯的有希望的原料。 其具有由通式（IX）表示的结构：其中R 1表示H，可被取代的C 1 -C 6烷基或可被取代的C 2 -C 6烯基，R 2表示可具有C 1 -C4烷基或可以具有苯基或萘基的C1-C12酰氧基或苄基，或R2是通过使所述双键邻近的所述双键的位置的移动可逆地形成醛基的羟基 羟基。 链二烯化合物通过在亲水性溶剂中在钌化合物的存在下使2-取代-1,3-丁二烯与末端烯烃反应制备。 此外，上述方法提供了用于制备温和香料组分和香料组合物的廉价方法，例如4-甲基-5-己烯-1-醇和4-乙烯基-8-甲基-7-壬烯醛。

公开(公告)号：US06228547B1

公开(公告)日：2001-05-08

申请号：US09332940

申请日：1999-06-15

申请人： Tohru Kobayashi ,  Yoshimasa Matsushima ,  Yoko Aoki ,  Mamoru Yamada ,  Hiroshi Sugiyama ,  Toshimitsu Hagiwara

发明人： Tohru Kobayashi ,  Yoshimasa Matsushima ,  Yoko Aoki ,  Mamoru Yamada ,  Hiroshi Sugiyama ,  Toshimitsu Hagiwara

IPC分类号： G03G506

CPC分类号： C07D317/66 ,  G03G5/0614 ,  G03G5/0631 ,  G03G5/0661

摘要： Disclosed are novel compounds useful in electrophotographic photoreceptors as charge-transporting materials having good miscibility with binder polymers and capable of forming a thin stable organic film having a high concentration; and an electrophotographic photoreceptor containing the same. The compounds are bis(3,4-methylenedioxyphenylamino) derivatives represented by general formula (1): wherein Ar1 and Ar2 each is an optionally substituted aryl group and Ar3 is a phenylene group or an optionally substituted biphenylene group.

摘要翻译： 公开了可用于电子照相感光体的新型化合物，作为与粘合剂聚合物具有良好混溶性且能够形成具有高浓度的薄稳定有机膜的电荷传输材料; 和含有它的电子照相感光体。 化合物是由通式（1）表示的双（3,4-亚甲二氧基苯基氨基）衍生物：其中Ar1和Ar2各自为任选取代的芳基，Ar 3是亚苯基或任选取代的亚联苯基。