Pulverent binders for powder coating compositions containing oligo- and polyurethanes having (meth)acryloyl groups
    41.
    发明授权
    Pulverent binders for powder coating compositions containing oligo- and polyurethanes having (meth)acryloyl groups 失效
    含有(甲基)丙烯酰基的低聚物和聚氨酯的粉末涂料组合物的流平粘合剂

    公开(公告)号:US06555597B1

    公开(公告)日:2003-04-29

    申请号:US09639687

    申请日:2000-08-16

    IPC分类号: C08F246

    摘要: The present invention relates to pulverent binders for powder coating compositions which contain oligo- and polyurethanes having (meth)acryloyl groups, are curable by means of high energy radiation and have an organic solvent content of less than 1 wt. %. The present invention also relates to a process for preparing these binders in the absence of an organic solvent and to their use in powder coating compositions for coating wood, metal, plastic, mineral and/or preprimed substrates.

    摘要翻译: 本发明涉及用于粉末涂料组合物的浆料粘合剂,其含有具有(甲基)丙烯酰基的低聚物和聚氨酯,可通过高能量辐射固化并且有机溶剂含量小于1wt。 %。 本发明还涉及在不存在有机溶剂的情况下制备这些粘合剂的方法,以及它们在用于涂覆木材,金属,塑料,矿物和/或预制基材的粉末涂料组合物中的用途。

    Process for preparing esters of (meth) acrylic acid
    43.
    发明授权
    Process for preparing esters of (meth) acrylic acid 有权
    制备(甲基)丙烯酸酯的方法

    公开(公告)号:US6150458A

    公开(公告)日:2000-11-21

    申请号:US358303

    申请日:1999-07-21

    IPC分类号: C07C67/60 C08G63/91 C08G65/32

    CPC分类号: C07C67/60 Y10S525/921

    摘要: The present invention relates to a process for preparing (meth)acrylic acid esters by1) reacting hydroxyl group-containing polyethers, polyesters or polyester ethers with (meth)acrylic acid in the presence of an acid esterification catalyst and a solvent to form (meth)acrylic acid esters, and2) reacting the acid esterification catalyst acid and unreacted (meth)acrylic acid with a compound containing two or more epoxide groups in the presence of the solvent used in step 1).

    摘要翻译: 本发明涉及一种制备(甲基)丙烯酸酯的方法,该方法是在酸酯化催化剂和溶剂的存在下使含羟基的聚醚,聚酯或聚酯醚与(甲基)丙烯酸反应形成(甲基) )丙烯酸酯,和2)在步骤1)中使用的溶剂的存在下,使酸酯化催化剂酸和未反应的(甲基)丙烯酸与含有两个或更多个环氧基的化合物反应。

    Radiation-curing binders and a process for their preparation
    45.
    发明授权
    Radiation-curing binders and a process for their preparation 有权
    辐射固化粘合剂及其制备方法

    公开(公告)号:US08980970B2

    公开(公告)日:2015-03-17

    申请号:US11217725

    申请日:2005-09-01

    摘要: The invention relates to a process for preparing binders which contain 1) allophanate groups, 2) groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups) and 3) optionally NCO-reactive groups, by reacting at temperatures ≦130° C. A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds that contain isocyanate-reactive groups and groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups), and then C) with one or more saturated, hydroxyl-containing compounds other than B), at least one of these compounds having an OH functionality of ≧2, in the presence of D) a catalyst containing one or more zinc compounds, the reaction with compounds C) taking place at least proportionally with the formation of allophanate groups. The present invention also relates to the binders obtained by the process of the invention.

    摘要翻译: 本发明涉及一种制备粘合剂的方法,其包含1)脲基甲酸酯基团,2)与烯键式不饱和化合物反应的基团与暴露于光化辐射(辐射固化基团)和3)任选的NCO-反应性基团反应的基团, A)一种或多种含有脲二酮基团的NCO-官能化合物,B)一种或多种含有异氰酸酯反应性基团的化合物和与烯键式不饱和化合物反应而与光化辐射(辐射 - 固化基团),然后C)与除了B)之外的一种或多种饱和的含羟基化合物,在D存在下,在具有OH官能度≥2的这些化合物中的至少一种的化合物存在下,含有一种或多种锌 化合物,与化合物C)的反应至少与脲基甲酸酯基团的形成成比例地发生。 本发明还涉及通过本发明的方法获得的粘合剂。

    Blocked polyisocyanates curing free from elimination products for dualcure systems
    46.
    发明授权
    Blocked polyisocyanates curing free from elimination products for dualcure systems 有权
    封闭的多异氰酸酯固化不含双固化系统的消除产物

    公开(公告)号:US08957176B2

    公开(公告)日:2015-02-17

    申请号:US11219395

    申请日:2005-09-02

    CPC分类号: C08G18/8175 C09D175/16

    摘要: The invention provides innovative blocked polyisocyanates whose crosslinking is initiated thermally and photochemically. The polyisocyanates comprise at least one thermally reversibly blocked NCO group whose blocking agent contains at least one group which on exposure to actinic radiation reacts, with polymerization, with ethylenically unsaturated compounds. A process for preparing the polyisocyanates, and their use in binders, is also provided.

    摘要翻译: 本发明提供了创新的封端多异氰酸酯,其交联是热和光化学引发的。 多异氰酸酯包含至少一个热可逆阻挡的NCO基团,其封闭剂含有至少一个在曝光于光化辐射下与烯属不饱和化合物聚合反应的基团。 还提供了制备多异氰酸酯的方法及其在粘合剂中的用途。

    WATERBORNE POLYURETHANE ADHESIVE COMPOSITION AND METHOD FOR BONDING ARTICLES
    47.
    发明申请
    WATERBORNE POLYURETHANE ADHESIVE COMPOSITION AND METHOD FOR BONDING ARTICLES 有权
    水性聚氨酯粘合剂组合物和粘结物品的方法

    公开(公告)号:US20130273375A1

    公开(公告)日:2013-10-17

    申请号:US13989532

    申请日:2011-11-24

    IPC分类号: C09J175/00

    摘要: The present invention relates to novel waterborne adhesives which are polymerisable by UV light and are capable of being activated by heat, and which particularly display good adhesion to difficult substrates, such as ethylene vinyl acetate copolymers (EVA) with a low vinyl acetate content, or rubber. The invention further provides a novel method in which, after the application of the waterborne adhesive to an article and drying, irradiation with UV light and at the same time or thereafter activation by heat are performed. The adhesive film which is irradiated and activated in this way is then bonded to a further article. The invention also provides the use of the adhesives to make items such as shoes.

    摘要翻译: 本发明涉及可通过紫外线聚合并且能够被热活化的新型水性粘合剂,并且其特别显示出对困难的基材的良好粘合性,例如具有低乙酸乙烯酯含量的乙烯乙酸乙烯酯共聚物(EVA),或 橡胶。 本发明还提供了一种新的方法,其中在将水性粘合剂施加到制品上并干燥之后,进行紫外线照射,同时或之后进行热激活。 以这种方式照射和活化的粘合剂膜然后与另外的制品粘合。 本发明还提供了粘合剂用于制造诸如鞋的物品的用途。

    Low-viscosity allophanates containing actinically curable groups
    49.
    发明授权
    Low-viscosity allophanates containing actinically curable groups 有权
    含有光化固化基团的低粘度脲基甲酸酯

    公开(公告)号:US07960446B2

    公开(公告)日:2011-06-14

    申请号:US12072022

    申请日:2008-02-22

    摘要: A process for preparing binders containing allophanate groups which contain, at the oxygen atom of the allophanate group that is bonded via two single bonds, organic radicals with activated groups capable of participating in a polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation; the process includes reacting A) one or more compounds containing uretdione groups with B) one or more OH-functional compounds which contain groups capable of participating in a polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation, and C) optionally further NCO-reactive compounds, and D) in the presence of one or more compounds containing phenoxide groups, as catalysts. The binders can be used in preparing coatings, coating materials, coating compositions, adhesives, printing inks, casting resins, dental compounds, sizes, photoresists, stereolithography systems, resins for composite materials and sealants.

    摘要翻译: 一种制备含有脲基甲酸酯基团的粘合剂的方法,其在通过两个单键键合的脲基甲酸酯基的氧原子上含有具有活化基团的活性基团,所述活性基团在与光化辐射接触时可与烯属不饱和化合物进行聚合反应; 该方法包括使A)一种或多种含有脲二酮基团的化合物与B)一种或多种OH官能化合物,其含有能够在暴露于光化辐射下与烯键式不饱和化合物进行聚合反应的基团,和C)任选地进一步的NCO- 活性化合物和D)在一种或多种含有酚氧化物的化合物的存在下作为催化剂。 粘合剂可用于制备涂料,涂料,涂料组合物,粘合剂,印刷油墨,浇铸树脂,牙科化合物,尺寸,光致抗蚀剂,立体光刻系统,复合材料和密封剂的树脂。