Abstract:
Provided are a ceria-based composition having an undoped or metal-doped ceria and an undoped or metal-doped bismuth oxide, wherein the undoped or metal-doped bismuth oxide is present in an amount equal to or more than about 10 wt % and less than about 50 wt % based on the total weight of the ceria-based composition, and at least one selected from the ceria and the bismuth oxide is metal-doped. The ceria-based composition may ensure high sintering density even at a temperature significantly lower than the known sintering temperature of about 1400° C., i.e., for example at a temperature of about 1000° C. or lower, and increase ion conductivity as well.
Abstract:
Provided is poly(benzimidazole-co-benzoxazole) having polybenzimidazole to which benzoxazole units are introduced, as a polymer electrolyte material. The polymer electrolyte material has both high proton conductivity and excellent mechanical properties even when it is obtained by in-situ phosphoric acid doping. The polymer electrolyte material may substitute for the conventional phosphoric acid-doped polybenzimidazole in a polymer electrolyte membrane fuel cell, particularly in a high-temperature polymer electrolyte membrane fuel cell.
Abstract:
The present disclosure relates to a polybenzimidazole-based electrolyte membrane for alkaline water electrolysis, which includes a polybenzimidazole-based polymer, wherein the polybenzimidazole-based polymer is a biaxially oriented film. The polybenzimidazole-based electrolyte membrane for alkaline water electrolysis can reduce the concentration of an alkaline solution by improving the crystallinity of a polybenzimidazole-based polymer to increase the resistance against base, significantly improving the long-term stability of alkaline water electrolysis using a polybenzimidazole-based electrolyte membrane through the improved resistance against base, and by increasing the operation temperature to enhance the catalyst activity.
Abstract:
The present disclosure relates to a polyarylene ether-based polymer for an electrolyte membrane of a fuel cell, represented by the following Chemical Formula 1. When the polyarylene ether-based polymer for an electrolyte membrane of a fuel cell is applied to the manufacture of a membrane-electrode assembly through a decal process, the hot pressing temperature may be controlled to about 120° C. so as to conform to a low glass transition temperature. Therefore, it is possible to solve the problems of deterioration of an electrolyte membrane or incomplete transfer of an electrode catalyst layer, caused by the high hot pressing temperature applied in the case of the conventional hydrocarbon-based polymer material.
Abstract:
Disclosed are a catalyst electrode for a fuel cell, a method for fabricating the catalyst electrode, and a fuel cell including the catalyst electrode. The presence of an ionomer-ionomer support composite in the catalyst electrode prevents the porous structure of the catalyst electrode from collapsing due to oxidation of a carbon support to avoid an increase in resistance to gas diffusion and can stably secure proton channels. The presence of carbon materials with high conductivity is effective in preventing the electrical conductivity of the electrode from deterioration resulting from the use of a metal oxide in the ionomer-ionomer support composite and is also effective in suppressing collapse of the porous structure of the electrode to prevent an increase in resistance to gas diffusion in the electrode. Based on these effects, the fuel cell exhibits excellent performance characteristics and prevents its performance from deteriorating during continuous operation.
Abstract:
Disclosed are a metal single-atom catalyst and a method for preparing the same. The method uses a minimal amount of chemicals and is thus environmentally friendly compared to conventional chemical and/or physical methods. In addition, the method enables the preparation of a single-atom catalyst in a simple and economical manner without the need for further treatment such as acid treatment or heat treatment. Furthermore, the method is universally applicable to the preparation of single-atom catalysts irrespective of the kinds of metals and supports, unlike conventional methods that suffer from very limited choices of metal materials and supports. Therefore, the method can be widely utilized to prepare various types of metal single-atom catalysts. All metal atoms in the metal single-atom catalyst can participate in catalytic reactions. This optimal atom utilization achieves maximum reactivity per unit mass and can minimize the amount of the metal used, which is very economical.
Abstract:
A method for preparing a carbon-supported, platinum-cobalt alloy, nanoparticle catalyst includes mixing a solution containing, in combination, a platinum precursor, a transition metal precursor consisting of a transition metal that is cobalt, carbon, a stabilizer that is oleyl amine, and a reducing agent that is sodium borohydride to provide carbon-supported, platinum-cobalt alloy nanoparticles, and washing the carbon-supported, platinum-cobalt alloy, nanoparticles using ethanol and distilled water individually or in combination followed by drying at room temperature to obtain dried carbon-supported, platinum-cobalt alloy, nanoparticles; treating the dried carbon-supported, platinum-cobalt alloy, nanoparticles with an acetic acid solution having a concentration ranging from 1-16M to provide acetic acid-treated nanoparticles, and washing the acetic acid-treated nanoparticles using distilled water followed by drying at room temperature to obtain dried acetic acid-treated nanoparticles; and heat treating the dried acetic acid-treated nanoparticles at a temperature ranging from 600 to 1000° C. under a hydrogen-containing atmosphere.
Abstract:
Provided is an electrocatalyst for anion exchange membrane water electrolysis, including a carbonaceous material, and nickel electrodeposited on the carbonaceous material, wherein nickel is partially substituted with platinum and the substitution with platinum provides increased hydrogen evolution activity as compared to the same electrocatalyst before substitution with platinum. Also provided are a method for preparing the electrocatalyst and an anion exchange membrane water electrolyzer using the same. The nickel electrocatalyst coated with an ultralow loading amount of platinum for anion exchange membrane water electrolysis shows excellent hydrogen evolution activity and has a small thickness of catalyst, thereby providing high mass transfer and high catalyst availability. In addition, the electrocatalyst uses a particle-type electrode to facilitate emission of hydrogen bubbles generated during hydrogen evolution reaction and oxygen bubbles generated during oxygen evolution reaction, and requires low cost for preparation to provide high cost-efficiency.
Abstract:
Disclosed are a reversible fuel cell oxygen electrode in which IrO2 is electrodeposited and formed on a porous carbon material and platinum is applied thereon to form a porous platinum layer, a reversible fuel cell including the same, and a method for preparing the same. According to the corresponding reversible fuel cell oxygen electrode, as the loading amounts of IrO2 and platinum used in the reversible fuel cell oxygen electrode can be lowered, it is possible to exhibit excellent reversible fuel cell performances (excellent fuel cell performance and water electrolysis performance) by improving the mass transport of water and oxygen while being capable of reducing the loading amounts of IrO2 and platinum. Further, it is possible to exhibit a good activity of a catalyst when the present disclosure is applied to a reversible fuel cell oxygen electrode and to reduce corrosion of carbon.
Abstract:
The present disclosure relates to a catalyst for electrochemical ammonia synthesis and a method for producing the same. The catalyst has an ammonia synthesis activity up to several times to several tens of times of the activity of the existing single metal or metal oxide catalysts. Thus, when using the catalyst, it is possible to provide a method for electrochemical ammonia synthesis having an improved ammonia production yield and rate.