公开(公告)号：US20120328915A1

公开(公告)日：2012-12-27

申请号：US13526133

申请日：2012-06-18

申请人： Takakazu Hirose ,  Kenichi Kawase ,  Takashi Fujinaga ,  Isao Koizumi ,  Toshio Nishi

发明人： Takakazu Hirose ,  Kenichi Kawase ,  Takashi Fujinaga ,  Isao Koizumi ,  Toshio Nishi

IPC分类号： H01M4/38 ,  H01M10/02 ,  B82Y30/00

CPC分类号： H01M4/38 ,  H01M4/131 ,  H01M4/133 ,  H01M4/134 ,  H01M4/364 ,  H01M4/366 ,  H01M4/381 ,  H01M4/382 ,  H01M4/386 ,  H01M4/387 ,  H01M4/463 ,  H01M4/48 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/54 ,  H01M4/583 ,  H01M4/587 ,  H01M4/622 ,  H01M4/623 ,  H01M4/626 ,  H01M10/0525 ,  H01M10/48 ,  H01M2004/021 ,  H01M2004/027 ,  H01M2004/028 ,  H01M2220/30 ,  Y02E60/122 ,  Y02T10/7011

摘要： A lithium-ion secondary battery includes a positive electrode, a negative electrode containing an active material, and an electrolytic solution, in which the active material includes a core portion capable of occluding and releasing lithium ions, and a covering portion arranged on at least part of a surface of the core portion, in which the covering portion contains, as constituent elements, Si, O, and at least one element M1 selected from Li, C, Mg, Al, Ca, Ti, Cr, Mn, Fe, Co, Ni, Cu, Ge, Zr, Mo, Ag, Sn, Ba, W, Ta, Na, and K, and the atomic ratio y (O/Si) of O to Si is 0.5≦y≦1.8.

摘要翻译： 锂离子二次电池包括正极，含有活性物质的负极和电解液，其中活性物质包括能够吸留和释放锂离子的核心部分，以及覆盖部分，其布置在至少部分 芯部的表面，其中覆盖部分包含Si，O和选自Li，C，Mg，Al，Ca，Ti，Cr，Mn，Fe，Co中的至少一种元素M1作为构成元素。 ，Ni，Cu，Ge，Zr，Mo，Ag，Sn，Ba，W，Ta，Na和K，O与Si的原子比y（O / Si）为0.5＆nlE; y＆nlE; 1.8。

公开(公告)号：US20120268073A1

公开(公告)日：2012-10-25

申请号：US13440588

申请日：2012-04-05

申请人： Tokuhiro Morioka ,  Hitoshi Watanabe ,  Kaoru Abe ,  Akihisa Sakamoto ,  Takakazu Hirose ,  Kenichi Kawase

发明人： Tokuhiro Morioka ,  Hitoshi Watanabe ,  Kaoru Abe ,  Akihisa Sakamoto ,  Takakazu Hirose ,  Kenichi Kawase

IPC分类号： H02J7/00 ,  B21D33/00 ,  H01M10/05 ,  H01M4/64 ,  H01M2/02

CPC分类号： H01M4/70 ,  B21D13/04 ,  B21D13/10 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/587 ,  H01M10/0587 ,  Y10T29/301

摘要： A nonaqueous electrolyte battery provided with a rolled electrode assembly, in which a positive electrode including a positive electrode active material layer disposed on a positive electrode collector formed from metal foil and a negative electrode including a negative electrode active material layer disposed on a negative electrode collector formed from metal foil are stacked with a separator therebetween and are rolled, and an electrolyte, wherein at least one of the positive electrode collector and the negative electrode collector has a compressed pattern portion which is disposed as a part of the metal foil and which has a thickness smaller than that of the other portion through compression, and the compressed pattern portion from one end parallel to the rolling direction of the metal foil to the other end opposite to the one end is not disposed continuously in the direction orthogonal to the rolling direction of the metal foil.

摘要翻译： 一种非水电解质电池，其设置有卷绕电极组件，其中包括设置在由金属箔形成的正极集电体上的正极活性物质层的正极和设置在负极集电体上的负极活性物质层的负极 由金属箔形成的层叠体，分离器之间进行卷绕，电解液，其中正极集电体和负极集电体中的至少一个具有作为金属箔的一部分配置的压缩图案部， 通过压缩的厚度小于另一部分的厚度，并且压缩图案部分从与金属箔的滚动方向平行的一端到与一端相反的另一端的压缩图案部分不沿与轧制方向正交的方向 的金属箔。

公开(公告)号：US20120164533A1

公开(公告)日：2012-06-28

申请号：US13326013

申请日：2011-12-14

申请人： Masaharu Senoue ,  Kenichi Kawase ,  Takakazu Hirose ,  Masayuki Ihara

发明人： Masaharu Senoue ,  Kenichi Kawase ,  Takakazu Hirose ,  Masayuki Ihara

IPC分类号： H01M4/52 ,  H01M4/38 ,  H01M4/50 ,  H01M4/54 ,  H01M4/48

CPC分类号： H01M4/525 ,  H01M4/485 ,  H01M4/505 ,  Y02E60/122

摘要： A lithium ion secondary battery including a positive electrode; a negative electrode; and an electrolytic solution, wherein the positive electrode includes a first lithium composite oxide and a second lithium composite oxide expressed by following formula (1) as a positive electrode active material, and wherein the second lithium composite oxide has a charge capacity greater than the first lithium composite oxide Li1+a(NibM1cM21−b−c)1.5−0.5aO2  (1) wherein, M1 represents at least one selected from among elements of group 13 to group 15 in an extended periodic table of elements excluding boron B, or carbon C, or nitrogen N, M2 represents at least one selected from among elements of group 3 to group 12, and a, b, and c satisfy relationships of 0.95≦a≦1.05, 0

摘要翻译： 一种锂离子二次电池，包括正极; 负极; 和电解液，其中所述正极包括第一锂复合氧化物和由下式（1）表示的第二锂复合氧化物作为正极活性材料，并且其中所述第二锂复合氧化物的充电容量大于所述第一锂复合氧化物 锂复合氧化物Li1 + a（NibM1cM21-b-c）1.5-0.5a​​O2（1）其中，M1表示除了硼B以外的元素的延伸周期表中的第13〜15族的元素中的至少1种 C或氮N，M 2表示选自第3组至第12组的元素中的至少一种，a，b和c满足0.95＆nlE; a＆nlE; 1.05,0

公开(公告)号：US20100124707A1

公开(公告)日：2010-05-20

申请号：US12617306

申请日：2009-11-12

申请人： Takakazu Hirose ,  Kenichi Kawase ,  Kazunori Noguchi ,  Takayuki Fujii

发明人： Takakazu Hirose ,  Kenichi Kawase ,  Kazunori Noguchi ,  Takayuki Fujii

IPC分类号： H01M6/16 ,  H01M6/04 ,  H01M4/02

CPC分类号： H01M4/364 ,  H01M4/134 ,  H01M4/1395 ,  H01M4/38 ,  H01M4/386 ,  H01M4/483 ,  H01M4/525 ,  H01M10/0525 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2300/0025

摘要： A secondary battery capable of obtaining superior cycle characteristics and superior swollenness characteristics is provided. The secondary battery includes a cathode and an anode capable of inserting and extracting an electrode reactant; and an electrolyte containing a solvent and an electrolyte salt. The anode has an anode active material layer on an anode current collector. The anode active material layer contains a plurality of crystalline anode active material particles having silicon (Si) as an element. The plurality of anode active material particles contain a spherical particle and a nonspherical particle.

摘要翻译： 提供能够获得优异的循环特性和优异的膨胀特性的二次电池。 二次电池包括能够插入和提取电极反应物的阴极和阳极; 以及含有溶剂和电解质盐的电解质。 阳极在阳极集电器上具有阳极活性材料层。 负极活性物质层含有多个以硅（Si）为元素的结晶负极活性物质粒子。 多个负极活性物质颗粒含有球形颗粒和非球形颗粒。

公开(公告)号：US09780368B2

公开(公告)日：2017-10-03

申请号：US13527288

申请日：2012-06-19

申请人： Takakazu Hirose ,  Kenichi Kawase ,  Toshio Nishi ,  Isao Koizumi

发明人： Takakazu Hirose ,  Kenichi Kawase ,  Toshio Nishi ,  Isao Koizumi

IPC分类号： H01M4/485 ,  H01M2/00 ,  H01M4/52 ,  H01M4/54 ,  H01M4/62 ,  H01M4/48 ,  H01M4/50 ,  H01M4/58

CPC分类号： H01M4/485 ,  H01M4/5825

摘要： A lithium-ion secondary battery includes a positive electrode, a negative electrode containing an active material, and an electrolytic solution, in which the active material contains, as constituent elements, Si, O, and at least one element M1 selected from Li, C, Mg, Al, Ca, Ti, Cr, Mn, Fe, Co, Ni, Cu, Ge, Zr, Mo, Ag, Sn, Ba, W, Ta, Na, and K, and the atomic ratio x (O/Si) of O to Si is 0.5≦x≦1.8.

公开(公告)号：US09166221B2

公开(公告)日：2015-10-20

申请号：US12974421

申请日：2010-12-21

申请人： Hiroyuki Yamaguchi ,  Hiroshi Horiuchi ,  Kenichi Kawase ,  Tadahiko Kubota ,  Hideki Nakai ,  Takakazu Hirose

发明人： Hiroyuki Yamaguchi ,  Hiroshi Horiuchi ,  Kenichi Kawase ,  Tadahiko Kubota ,  Hideki Nakai ,  Takakazu Hirose

IPC分类号： H01M4/134 ,  H01M4/13 ,  H01M4/139 ,  H01M4/36 ,  H01M4/38 ,  H01M4/485 ,  H01M10/0567 ,  H01M10/0569 ,  H01M10/058 ,  H01M4/131 ,  H01M10/052 ,  H01M4/02

CPC分类号： H01M4/366 ,  H01M4/13 ,  H01M4/131 ,  H01M4/134 ,  H01M4/139 ,  H01M4/38 ,  H01M4/386 ,  H01M4/387 ,  H01M4/483 ,  H01M4/485 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0569 ,  H01M10/058 ,  H01M10/0587 ,  H01M2004/027 ,  H01M2300/0028 ,  H01M2300/0034 ,  Y02E60/122 ,  Y02P70/54

摘要： An anode in which an anode active material layer is arranged on an anode current collector. The anode active material layer includes anode active material particles made of an anode active material including at least one of silicon and tin as an element. An oxide-containing film including an oxide of at least one kind selected from the group consisting of silicon, germanium and tin is formed in a region in contact with an electrolytic solution of the surface of each anode active material particle by a liquid-phase method such as a liquid-phase deposition method. The region in contact with the electrolytic solution of the surface of each anode active material particle is covered with the oxide-containing film, to thereby improve the chemical stability of the anode and the charge-discharge efficiency. The thickness of the oxide-containing film is preferably within a range from 0.1 nm to 500 nm both inclusive.

摘要翻译： 在阳极集电体上配置负极活性物质层的阳极。 阳极活性材料层包括由包含硅和锡中的至少一种作为元素的阳极活性材料制成的阳极活性材料颗粒。 在与阳极活性物质粒子的表面的电解液接触的区域中，通过液相法形成含有选自硅，锗，锡中的至少一种的氧化物的含氧化物膜 例如液相沉积法。 与负极活性物质粒子的表面的电解液接触的区域被含氧化物膜覆盖，从而提高阳极的化学稳定性和充放电效率。 含氧化物膜的厚度优选为0.1nm〜500nm的范围。

公开(公告)号：US09083054B2

公开(公告)日：2015-07-14

申请号：US13527284

申请日：2012-06-19

申请人： Takakazu Hirose ,  Takashi Fujinaga ,  Isao Koizumi ,  Norihiro Shimoi ,  Kenichi Kawase

发明人： Takakazu Hirose ,  Takashi Fujinaga ,  Isao Koizumi ,  Norihiro Shimoi ,  Kenichi Kawase

IPC分类号： H01M10/052 ,  H01M2/16 ,  H01M4/131 ,  H01M4/36 ,  H01M4/48 ,  H01M4/587 ,  H01M10/0587 ,  C01G45/12 ,  C01G53/00 ,  B60L3/00 ,  B60L11/18 ,  H01M2/34 ,  H01M4/04 ,  H01M4/1391 ,  H01M4/485 ,  H01M4/62 ,  H01M10/48 ,  H01M4/02

CPC分类号： H01M10/052 ,  B60L3/0046 ,  B60L3/0069 ,  B60L11/1879 ,  C01G45/1228 ,  C01G53/42 ,  C01G53/50 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2004/80 ,  C01P2006/40 ,  H01M2/1673 ,  H01M2/34 ,  H01M4/0404 ,  H01M4/0471 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/362 ,  H01M4/366 ,  H01M4/483 ,  H01M4/485 ,  H01M4/587 ,  H01M4/624 ,  H01M4/625 ,  H01M10/0587 ,  H01M10/48 ,  H01M10/486 ,  H01M2004/021 ,  H01M2220/20 ,  Y02E60/122 ,  Y02T10/7005 ,  Y02T10/7011 ,  Y02T10/705

摘要： A lithium ion secondary battery is provided with a positive electrode, a negative electrode containing an active material, and an electrolytic solution, wherein the active material includes a core portion capable of occluding and releasing lithium ions, an amorphous or low-crystalline coating portion disposed on at least a part of the surface of the core portion, and a fibrous carbon portion disposed on at least a part of the surface of the coating portion, and the coating portion contains Si and O as constituent elements, while the atomic ratio y (O/Si) of O relative to Si satisfies 0.5≦y≦1.8.

摘要翻译： 锂离子二次电池设置有正极，含有活性物质的负极和电解液，其中活性物质包括能够吸留和释放锂离子的核心部分，非晶态或低结晶性涂层部分 在芯部的表面的至少一部分上，以及设置在涂布部的表面的至少一部分上的纤维状碳部分，涂布部分含有Si和O作为构成元素，而原子比y（ O / Si）相对于Si满足0.5＆nlE; y＆nlE; 1.8。

公开(公告)号：US09048485B2

公开(公告)日：2015-06-02

申请号：US13526133

申请日：2012-06-18

申请人： Takakazu Hirose ,  Kenichi Kawase ,  Takashi Fujinaga ,  Isao Koizumi ,  Toshio Nishi

发明人： Takakazu Hirose ,  Kenichi Kawase ,  Takashi Fujinaga ,  Isao Koizumi ,  Toshio Nishi

IPC分类号： H01M4/38 ,  H01M4/48 ,  H01M4/131 ,  H01M10/0525 ,  H01M4/134 ,  H01M4/62 ,  H01M10/48

CPC分类号： H01M4/38 ,  H01M4/131 ,  H01M4/133 ,  H01M4/134 ,  H01M4/364 ,  H01M4/366 ,  H01M4/381 ,  H01M4/382 ,  H01M4/386 ,  H01M4/387 ,  H01M4/463 ,  H01M4/48 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/54 ,  H01M4/583 ,  H01M4/587 ,  H01M4/622 ,  H01M4/623 ,  H01M4/626 ,  H01M10/0525 ,  H01M10/48 ,  H01M2004/021 ,  H01M2004/027 ,  H01M2004/028 ,  H01M2220/30 ,  Y02E60/122 ,  Y02T10/7011

摘要： A lithium-ion secondary battery includes a positive electrode, a negative electrode containing an active material, and an electrolytic solution, in which the active material includes a core portion capable of occluding and releasing lithium ions, and a covering portion arranged on at least part of a surface of the core portion, in which the covering portion contains, as constituent elements, Si, O, and at least one element M1 selected from Li, C, Mg, Al, Ca, Ti, Cr, Mn, Fe, Co, Ni, Cu, Ge, Zr, Mo, Ag, Sn, Ba, W, Ta, Na, and K, and the atomic ratio y (O/Si) of O to Si is 0.5≦y≦1.8.

摘要翻译： 锂离子二次电池包括正极，含有活性物质的负极和电解液，其中活性物质包括能够吸留和释放锂离子的核心部分，以及覆盖部分，其布置在至少部分 芯部的表面，其中覆盖部分包含Si，O和选自Li，C，Mg，Al，Ca，Ti，Cr，Mn，Fe，Co中的至少一种元素M1作为构成元素。 ，Ni，Cu，Ge，Zr，Mo，Ag，Sn，Ba，W，Ta，Na和K，O与Si的原子比y（O / Si）为0.5＆nlE; y＆nlE; 1.8。

公开(公告)号：US08932756B2

公开(公告)日：2015-01-13

申请号：US12262301

申请日：2008-10-31

申请人： Takakazu Hirose ,  Hideki Nakai ,  Kenichi Kawase ,  Hiroyuki Yamaguchi ,  Tadahiko Kubota

发明人： Takakazu Hirose ,  Hideki Nakai ,  Kenichi Kawase ,  Hiroyuki Yamaguchi ,  Tadahiko Kubota

IPC分类号： H01M4/58 ,  H01M4/62 ,  H01M4/133 ,  H01M4/134 ,  H01M4/139 ,  H01M4/36 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/0568 ,  H01M4/04 ,  H01M4/70

CPC分类号： H01M4/62 ,  H01M4/0471 ,  H01M4/133 ,  H01M4/134 ,  H01M4/139 ,  H01M4/366 ,  H01M4/38 ,  H01M4/386 ,  H01M4/387 ,  H01M4/70 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/0568 ,  H01M2004/027 ,  H01M2220/30 ,  Y02E60/122

摘要： A battery. including a cathode, an anode, and an electrolytic solution where at least one of the cathode, the anode, the separator, and/or the electrolytic solution contains at a fluorine resin and is effective to improve cycle characteristics.

摘要翻译： 一个电池 包括阴极，阳极和电解液，其中阴极，阳极，隔膜和/或电解液中的至少一个含有氟树脂，并且有效地改善循环特性。

公开(公告)号：US20100124706A1

公开(公告)日：2010-05-20

申请号：US12616633

申请日：2009-11-11

申请人： Takakazu Hirose ,  Kenichi Kawase ,  Kazunori Noguchi ,  Takayuki Fujii

发明人： Takakazu Hirose ,  Kenichi Kawase ,  Kazunori Noguchi ,  Takayuki Fujii

IPC分类号： H01M6/16 ,  H01M4/58 ,  H01M4/42 ,  H01M6/04

CPC分类号： H01M10/0525 ,  H01M4/134 ,  H01M4/58 ,  H01M10/0568 ,  H01M10/0569

摘要： A secondary battery capable of obtaining superior cycle characteristics and superior swollenness characteristics is provided. The secondary battery includes a cathode, an anode, and an electrolytic solution. The electrolytic solution is impregnated in a separator provided between the cathode and the anode. An anode active material layer contains a crystalline anode active material having silicon as an element. The anode active material layer has a coating section where the surface of an anode current collector is coated with the anode active material and a non-coating section where the surface of the anode current collector is not coated with the anode active material but is exposed. Thereby, the physical property of the anode active material is hardly deteriorated with age. Further, at the time of charge and discharge, the anode active material layer is hardly expanded and shrunk, and thus the anode current collector is hardly deformed.

摘要翻译： 提供能够获得优异的循环特性和优异的膨胀特性的二次电池。 二次电池包括阴极，阳极和电解液。 将电解液浸渍在设置在阴极和阳极之间的隔膜中。 阳极活性材料层含有具有硅作为元素的结晶阳极活性材料。 负极活性物质层具有涂覆部分，其中阳极集电体的表面涂覆有负极活性材料和非涂覆部分，其中阳极集电器的表面没有被阳极活性材料涂覆但被暴露。 由此，阳极活性物质的物性几乎不随着年龄而劣化。 此外，在充放电时，阳极活性物质层几乎不膨胀收缩，因此阳极集电体几乎不变形。