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公开(公告)号：US5124236A
公开(公告)日：1992-06-23
申请号：US215707
申请日：1988-07-06
CPC分类号： G03F7/031 , G03F7/002 , G03F7/027 , G03F7/029 , Y10S430/115 , Y10S430/121 , Y10S430/122
摘要： A photopolymerizable composition is disclosed, which comprises a photopolymerizable compound and a photopolymerization initiator comprising a cationic dye, an organic boron compound and a compound having an --SH group in the molecule thereof, and which can be used for making printing plates, as resist materials for making printed circuit boards, as color proof materials, etc.The photopolymerizable composition can be applied for an image-forming process utilizing microcapsules, which comprises the steps of encapsulating the photopolymerizable composition with a color image-forming material in the core of microcapsules, coating the microcapsules on a support to form a photosensitive sheet, imagewise exposing the photosensitive sheet, superposing the photosensitive sheet on an image-receiving sheet, pressing the whole surface of the assembly to rupture the microcapsules at the unexposed portions, and transferring the color image-forming material into the image-receiving sheet.The color image obtained by using the photopolymerizable composition exhibits high sensitivity.
摘要翻译： 公开了一种可光聚合组合物，其包含光聚合化合物和包含阳离子染料，有机硼化合物和其分子中具有-SH基团的化合物的光聚合引发剂，并且其可用于制备印刷版，作为抗蚀剂材料 用于制造印刷电路板，作为耐色材料等。可光聚合组合物可以应用于利用微胶囊的成像方法，其包括将可光聚合组合物与彩色图像形成材料包封在微胶囊芯中的步骤， 将微胶囊涂布在支撑体上以形成感光片，成像曝光感光片，将感光片重叠在图像接收片上，按压组件的整个表面以在未曝光部分破裂微胶囊，并转印彩色图像 形成材料进入图像接收片材。 通过使用可光聚合组合物获得的彩色图像显示出高灵敏度。
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公开(公告)号：US5055373A
公开(公告)日：1991-10-08
申请号：US414342
申请日：1989-09-29
申请人： Keiso Saeki , Fumiaki Shinozaki , Toshiaki Endo
发明人： Keiso Saeki , Fumiaki Shinozaki , Toshiaki Endo
CPC分类号： G03C1/002 , G03F7/002 , Y10S430/114 , Y10S430/117 , Y10T428/2984 , Y10T428/2985
摘要： A multicolor recording material is disclosed, which comprises a support having provided thereon a coating layer comprising two or more kinds of microcapsules each containing at least a leuco dye capable of being colored by oxidation and a photo oxidizing agent outside said microcapsules, and a reducing agent as necessary components, with two or more leuco dyes capable of forming different colors from each other being retained in different kinds of said microcapusles respectively composed of walls of high polymers having different glass transition points.
摘要翻译： 公开了一种多色记录材料，其包括其上设置有包含两种或更多种微胶囊的涂层的载体，每个微胶囊至少包含能够通过氧化着色的无色染料和在所述微胶囊外部的光氧化剂，还原剂 作为必要组分，具有能够形成彼此不同颜色的两种或更多种无色染料保留在分别由具有不同玻璃化转变点的高聚合物壁组成的不同种类的所述微型碳氢化合物中。
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43.发明授权
公开(公告)号：US4987050A
公开(公告)日：1991-01-22
申请号：US446362
申请日：1989-12-05
申请人： Fumiaki Shinozaki , Shunzo Yagami
发明人： Fumiaki Shinozaki , Shunzo Yagami
IPC分类号： G03F3/10
CPC分类号： G03F3/107
摘要： A light-sensitive transfer material is disclosed, comprising a substantially transparent support having provided on one side thereof, in order from the support, a stripping layer, and a lamination of a colorant layer containing a dye or a pigment and a photoresist layer or a photoresist layer containing a dye or a pigment, and having provided on the other side thereof a physical development nuclei-containing layer adapted for diffusion transfer processing using a silver halide emulsion.An image-forming process is also disclosed, comprising the steps of:(a) developing the superposed physical development nuclei-containing layer of the light-sensitive transfer material described above and an imagewise exposed silver halide emulsion layer of a diffusion transfer process silver halide light-sensitive material, to thereby form a silver image;(b) uniformly exposing the superposed materials from the silver image side thereof, to thereby expose the photoresist layer in conformance with the silver image;(c) developing the exposed photoresist layer to form a colorant image on the support; and(d) transferring the colorant image to an image-receiving sheet.
摘要翻译： 公开了一种感光转印材料，其包括基本上透明的支撑体，其一侧上设置有从载体，剥离层以及含有染料或颜料和光致抗蚀剂层或着色剂层的着色剂层的叠层 含有染料或颜料的光致抗蚀剂层，并且在其另一侧上提供适于使用卤化银乳剂进行扩散转移处理的物理显影含核层。 还公开了一种图像形成方法，包括以下步骤：（a）显影上述感光转印材料的重叠物理显影含核层和扩散转移法卤化银的成像曝光卤化银乳剂层 感光材料，从而形成银色图像; （b）将叠加的材料从其银图像侧均匀地曝光，从而使光致抗蚀剂层与银图像一致; （c）显影所述曝光的光致抗蚀剂层以在所述载体上形成着色剂图像; 和（d）将着色剂图像转印到图像接收片材上。
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公开(公告)号：US4962009A
公开(公告)日：1990-10-09
申请号：US257580
申请日：1988-10-14
申请人： Shintaro Washizu , Jun Yamaguchi , Fumiaki Shinozaki , Akihiro Shimomura , Toshimasa Usami , Toshiaki Endo , Keiso Saeki
发明人： Shintaro Washizu , Jun Yamaguchi , Fumiaki Shinozaki , Akihiro Shimomura , Toshimasa Usami , Toshiaki Endo , Keiso Saeki
摘要： An image-forming material comprising: (a) microcapsules, in which at least one leuco dye capable of developing a color by oxidation and at least one photooxidizing agent (preferably a combination of a lophine dimer and an organic halogeno-compound) are enclosed together, and (b) at least one reducing agent not enclosed in the microcapsules (preferably present in the form of an emulsified dispersion), thereby achieving image formation in a completely dried condition, and ensuring excellent freshness keeping property, image reproducibility and fixability.
摘要翻译： 一种图像形成材料，包括：（a）微胶囊，其中至少一种能够通过氧化形成颜色的至少一种无色染料和至少一种光氧化剂（优选的是二氢卟吩和有机卤代化合物的组合）被封闭在一起 ，和（b）未包封在微胶囊中的至少一种还原剂（优选以乳化分散体的形式存在），从而在完全干燥的条件下实现图像形成，并且确保优异的保鲜性，图像再现性和定影性。
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45.发明授权Image-recording method comprising heating a light-sensitive material containing microcapsule 失效图像记录方法，包括加热含有微胶囊的感光材料
公开(公告)号：US4912011A
公开(公告)日：1990-03-27
申请号：US201334
申请日：1988-05-31
CPC分类号： G03F7/002 , G03C1/498 , G03F7/0285
摘要： A light-sensitive material and an image recording method using the same are disclosed. The material comprises a support having provided thereon a light sensitive layer containing at least a light-sensitive silver halide, a reducing agent, a polymerizable compound, and a color image forming substance, wherein at least the polymerizable compound and the color image forming substance are encapsulated in the same microcapsules. The material exhibits high sensitivity and excellent stability with time.
摘要翻译： 公开了一种感光材料和使用其的图像记录方法。 该材料包括其上设置有至少含有感光卤化银，还原剂，可聚合化合物和彩色图像形成物质的光敏层的载体，其中至少可聚合化合物和彩色图像形成物质为 封装在相同的微胶囊中。 该材料具有高灵敏度和优异的时间稳定性。
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公开(公告)号：US4877712A
公开(公告)日：1989-10-31
申请号：US199822
申请日：1988-05-27
申请人： Tomizo Namiki , Kazuo Suzuki , Fumiaki Shinozaki
发明人： Tomizo Namiki , Kazuo Suzuki , Fumiaki Shinozaki
CPC分类号： B44C1/1712 , G03F3/10
摘要： An image-forming process comprising the steps of:(A) transferring an image layer, formed on a transferable light-sensitive material, onto an image-receiving sheet, and(B) transferring the image layer onto a permanent support, wherein the image-receiving sheet comprises a support having formed thereon an image-receiving layer composed of a composition containing an organic high molecular material as the main component, wherein an adhesive power P.sub.1 between the support of the image-receiving sheet and the image-receiving layer and an adhesive power P.sub.2 between the image-receiving layer and the image layer are higher than an adhesive power P.sub.3 between the image layer and the support of the transferable light-sensitive material, and also an adhesive power P.sub.4 between the permanent support and the image layer and adhesive power P.sub.1 are higher than adhesive power P.sub.2, and wherein the image layer is transferred onto the permanent support via the image-receiving sheet without transferring the image-receiving layer onto the permanent support.
摘要翻译： 一种图像形成方法，包括以下步骤：（A）将形成在可转印感光材料上的图像层转印到图像接收片上，（B）将图像层转印到永久性支持体上，其中图像 接收片包括其上形成有由包含有机高分子材料作为主要成分的组合物构成的图像接收层的支撑体，其中，图像接收片材的支撑体与图像接收层之间的粘合力P1和 图像接收层和图像层之间的粘合力P2高于图像层和可转印感光材料的支撑体之间的粘合力P3，以及永久性支撑体和图像层之间的粘合力P4 并且粘合力P1高于粘合力P2，并且其中图像层经由图像接收片材转印到永久性支撑件上而不转印图像 电子接收层到永久支持。
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公开(公告)号：US4766053A
公开(公告)日：1988-08-23
申请号：US830816
申请日：1986-02-19
申请人： Fumiaki Shinozaki , Tomizo Namiki , Kazuo Suzuki
发明人： Fumiaki Shinozaki , Tomizo Namiki , Kazuo Suzuki
IPC分类号： G03C1/00 , G03C5/00 , G03C11/12 , G03F3/10 , G03F7/004 , G03F7/09 , G03F7/105 , G03F7/11 , G03F7/34 , G03C1/90
摘要： A method is described for forming an image by transferring an image layer formed on a transferable light-sensitive material to an image-receiving sheet, and then further transferring the image to a permanent support, wherein the image-receiving sheet comprises a support, a first layer on the support, said first layer being made of a first organic polymeric substance, and a second layer on the first layer, said second layer being made of a second organic polymeric substance, whereinin peeling apart the image-receiving sheet from the transferable light-sensitive material,P.sub.1, P.sub.2, P.sub.3 >P.sub.4 wherein P.sub.1 is an adhesion force between the support and the first layer, P.sub.2 is an adhesion force between the first and second layers, P.sub.3 is an adhesion force between the second layer and the image layer, and P.sub.4 is an adhesion force between the transferable image layer and the support of the image, andin re-transferring the image layer to the permanent support and peeling apart the image-receiving sheet from the permanent support,P.sub.5, P.sub.1, P.sub.2 >P.sub.3, orP.sub.5, P.sub.1, P.sub.3 >P.sub.2 wherein P.sub.5 is an adhesion force between the permanent support and the transferable image layer.
摘要翻译： 描述了通过将形成在可转印的感光材料上的图像层转印到图像接收片材上，然后进一步将图像转印到永久性支持体上来形成图像的方法，其中图像接收片材包括支撑体， 所述第一层由第一有机聚合物质制成，所述第一层在所述第一层上，所述第二层由第二有机聚合物质制成，其中，将所述图像接收片从所述第一层剥离下来， 可转印感光材料P1，P2，P3> P4，其中P1是支撑体和第一层之间的粘附力，P2是第一和第二层之间的粘附力，P3是第二层和第二层之间的粘合力 图像层，P4是可转印图像层与图像支持体之间的粘合力，并且在将图像层重新转印到永久支撑件上并剥离图像接收片材f 永久支撑P5，P1，P2> P3或P5，P1，P3> P2，其中P5是永久支撑体和可转移图像层之间的粘附力。
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公开(公告)号：US4598036A
公开(公告)日：1986-07-01
申请号：US649002
申请日：1984-09-10
摘要： A print-out composition containing a leuco dye and a photooxidizing agent is described, said print-out composition containing at least one carbazomethane compound represented by formula (I) as the leuco dye ##STR1## wherein Y represents an amino group-substituted phenyl group represented by formula (Ia) ##STR2## or an indolyl group represented by formula (Ib) ##STR3## wherein X.sub.1 and X.sub.2 each represents a hydrogen atom, an unsubstituted alkyl group, or an alkyl group substituted by a halogen atom, a hydroxy group, a cyano group, or a lower alkoxy group, said alkyl group having up to 12 carbon atoms, a cycloalkyl group, a phenyl group, a benzyl group, or a phenyl or benzyl group substituted by a halogen atom, a lower alkyl group, or a lower alkoxy group, or said X.sub.1 and X.sub.2 together may form a 5-membered or 6-membered heterocyclic group together with the nitrogen atom bonded thereto; X.sub.3 represents a hydrogen atom, a halogen atom, a nitro group, a lower alkyl group, or a lower alkoxy group; R.sub.1 and Z.sub.1 each represents a hydrogen atom, an unsubstituted alkyl group or an alkyl group substituted by a halogen atom having up to 12 carbon atoms, a hydroxy group, a cyano group, or a lower alkoxy group, an alkenyl group having up to 12 carbon atoms, an acyl group having from 1 to 12 carbon atoms, a phenyl group, a benzyl group, or a phenyl or benzyl group substituted by a member selected from the group consisting of a halogen atom, a lower alkyl group, a lower alkoxy group, and a nitro group; Z.sub.2 represents a hydrogen atom, a lower alkyl group, or a phenyl group; and rings A, B, and D each may be further substituted by a cyano group, a nitro group, a halogen atom, a lower alkyl group, a lower alkoxy group, or a lower alkylcarbonyl group.
摘要翻译： 描述了含有无色染料和光氧化剂的印刷组合物，所述印刷组合物含有至少一种由式（I）表示的咔唑甲烷化合物作为无色染料（I），其中Y表示氨基 - （Ia）表示的取代苯基或由式（Ib）表示的吲哚基（Ib）其中X1和X2各自表示氢原子，未取代的烷基或烷基 被卤素原子，羟基，氰基或低级烷氧基取代，所述烷基具有至多12个碳原子，环烷基，苯基，苄基或苯基或苄基被 卤素原子，低级烷基或低级烷氧基，或者所述X1和X2一起可以与键合的氮原子一起形成5元或6元杂环基; X3表示氢原子，卤素原子，硝基，低级烷基或低级烷氧基; R1和Z1各自表示氢原子，未取代的烷基或被具有至多12个碳原子的卤素原子，羟基，氰基或低级烷氧基取代的烷基，具有至多12个 碳原子，具有1至12个碳原子的酰基，苯基，苄基或被选自以下的成员所取代的苯基或苄基：卤原子，低级烷基，低级烷氧基 组和硝基; Z2表示氢原子，低级烷基或苯基; 环A，B和D各自可以进一步被氰基，硝基，卤素原子，低级烷基，低级烷氧基或低级烷基羰基取代。
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公开(公告)号：US4584260A
公开(公告)日：1986-04-22
申请号：US741721
申请日：1985-06-06
CPC分类号： C08F2/50 , G03F7/0295 , Y10S430/12 , Y10S430/121 , Y10S430/124 , Y10S430/126
摘要： A photopolymerizable composition comprising an addition polymerizable unsaturated compound containing at least two ethylenically unsaturated double bonds in the molecule thereof and photopolymerization initiators, wherein a 4,4'-bis(dialkylamino)benzophenone represented by general formula I below, a benzophenone derivative represented by general formula II below and a compound having a group represented by general formula III below are contained as said photopolymerization initiators: ##STR1## wherein R represents an alkyl, cycloalkyl or hydroxyalkyl group having 1 to 6 carbon atoms or is combined with another R substituted on the same nitrogen atom to form tetramethylene, pentamethylene or oxybisethylene; ##STR2## wherein R.sup.1 represents a hydrogen atom ##STR3## X.sub.1 and X.sub.2 each represents an alkyl group, an alkoxy group, a carboxy group, an alkoxycarbonyl group, an aryloxycarbonyl group or a halogen atom; m and n each represents 0, 1 or 2 and when m and n each represents 2, X.sub.1 and X.sub.2 may be the same or different;--CY.sub.3 IIIwherein Y represents a halogen atom.
摘要翻译： 一种光聚合性组合物，其含有分子中含有至少两个烯键式不饱和双键的加聚性不饱和化合物和光聚合引发剂，其中，下述通式I表示的4,4'-双（二烷基氨基）二苯甲酮，一般为二苯甲酮衍生物 作为所述光聚合引发剂，含有下述式II化合物和具有下述通式III所示基团的化合物：其中R表示具有1至6个碳原子的烷基，环烷基或羟烷基，或与另一个R 相同的氮原子形成四亚甲基，五亚甲基或氧代二亚乙基; 其中R 1表示氢原子，X 1和X 2各自表示烷基，烷氧基，羧基，烷氧基羰基，芳氧基羰基或卤素原子; m和n各自表示0,1或2，并且当m和n各自表示2时，X 1和X 2可以相同或不同; -CY3 III，其中Y表示卤素原子。
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50.发明授权Photopolymerizable composition containing acylhaloacetic acid amide derivatives 失效含有酰基卤代乙酸酰胺衍生物的光聚合组合物
公开(公告)号：US4548892A
公开(公告)日：1985-10-22
申请号：US696214
申请日：1985-01-29
CPC分类号： G03F7/031 , C08F2/50 , Y10S430/12 , Y10S430/124 , Y10S430/126
摘要： A photopolymerizable composition is described, containing an addition polymerizable, unsaturated compound having two or more ethylenically unsaturated double bonds within the molecule and a photopolymerization initiator, wherein said photopolymerization initiator is an acylhaloacetic acid amide derivative represented by formula (I) ##STR1## wherein Ar represents a substituted or unsubstituted aryl group, X represents a carbonyl or sulfonyl group, Y represents a chlorine atom or a bromine atom, R represents a hydrogen atom, a chlorine atom or a bromine atom, and R.sup.a and R.sup.b each represents a hydrogen atom, a substituted or unsubstituted alkyl group, an aryl group, or an aralkyl group.
摘要翻译： 描述了含有分子内具有两个或更多个烯属不饱和双键的可加成聚合的不饱和化合物和光聚合引发剂的光聚合组合物，其中所述光聚合引发剂是由式（I）表示的酰基卤代乙酸酰胺衍生物 ）其中Ar表示取代或未取代的芳基，X表示羰基或磺酰基，Y表示氯原子或溴原子，R表示氢原子，氯原子或溴原子，Ra和Rb各自表示 氢原子，取代或未取代的烷基，芳基或芳烷基。
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