摘要:
The present invention relates to an acid-doped polymer membrane based on polyazoles. The acid-doped polymer membrane can be used in a variety of applications because of its excellent mechanical properties and is useful as polymer electrolyte membrane (PEM) in PEM fuel cells. A doped polymer membrane based on polyazoles is obtained by a process comprising the steps of: A) casting a film using a solution of polymers based on polyazoles in a polar, aprotic organic solvent; B) drying the film formed in step A) until it is self-supporting; C) treating the film obtained in step B) with a treatment liquid at a temperature in the range from room temperature to the boiling point of the treatment liquid; D) drying and/or dabbing the film treated according to step C) to remove the treatment liquid from step C); and E) doping the film treated according to step D) with a doping agent.
摘要:
The present invention relates to a polymer blend membrane comprising a bridged polymer which is produced by a selected process. The membrane of the invention displays a significantly improved fracture toughness (elongation at break/stress) combined with virtually unchanged other properties. The membranes of the invention are suitable for producing membrane-electrode units for fuel cells.
摘要:
The present invention relates to an asymmetric polymer film, in particular based on polazoles, a method for the production of the same and its use. The polyazole-based asymmetric polymer film according to the invention has a smooth and a rough side and enables, on account of its asymmetric structure, rapid and homogeneous doping with acids to form a proton-conducting membrane. The polyazole-based asymmetric polymer film according to the invention can be used in diverse ways on account of its excellent chemical, thermal and mechanical properties and is particularly suitable for the production of polymer electrolyte membranes (PEM) for so-called PEM fuel cells.
摘要:
The present invention relates to a proton-conducting polymer membrane comprising polymers comprising at least one porous carrier material and polymers comprising phosphonic acid groups, obtainable by polymerizing monomers comprising phosphonic acid groups.
摘要:
Method for producing a membrane made of bridged polymer and a fuel cell. The present invention relates to a membrane comprising a bridged polymer which is produced by a selected process. The membrane of the invention displays a significantly improved fracture toughness (elongation at break/tensile strength) with virtually unchanged swelling behavior. The membranes of the invention are suitable for producing membrane-electrode units for fuel cells.
摘要:
The present invention relates to a proton-conducting polymer electrolyte membrane based on polyvinylphosphonic acid/polyvinylsulfonic acid polymers, which owing to their excellent chemical and thermal properties, can be used for a variety of purposes and is particularly suitable as polymer electrolyte membrane (PEM) in PEM fuel cells.
摘要:
Mixtures containing vinyl-containing phosphonic acid, polymer electrolyte membranes comprising polyvinylphosphonic acid and their use in fuel cells. The present invention relates to a proton-conducting polymer membrane based on polyvinylphosphonic acid obtainable by a process comprising the steps A) Mixing a polymer with vinyl-containing phosphonic acid, B) Forming a two-dimensional structure using the mixture according to step A) on a carrier, C) Polymerisation of the vinyl-containing phosphonic acid present in the two-dimensional structure according to step B). A membrane according to the invention may on account of its outstanding chemical and thermal properties be used in a wide range of applications and is particularly suitable as a polymer-electrolyte membrane (PEM) in so-called PEM fuel cells.
摘要:
The present invention relates to a polymer blend membrane comprising a bridged polymer which is produced by a selected process. The membrane of the invention displays a significantly improved fracture toughness (elongation at break/stress) combined with virtually unchanged other properties. The membranes of the invention are suitable for producing membrane-electrode units for fuel cells.
摘要:
The present invention relates to a proton-conducting multilayer electrolyte membrane with a barrier layer, a process for producing it and a fuel cell containing such a membrane.
摘要:
The present invention relates to a proton-conducting multilayer electrolyte membrane with a barrier layer, a process for producing it and a fuel cell containing such a membrane.