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    Polymer membrane, method for the production and use thereof
    1.
    发明授权
    Polymer membrane, method for the production and use thereof 失效
    聚合物膜，其生产和使用方法

    公开(公告)号：US08168105B2

    公开(公告)日：2012-05-01

    申请号：US12720026

    申请日：2010-03-09

    申请人： Oemer Uensal ,  Joachim Kiefer ,  Jochen Baurmeister ,  Jürgen Pawlik ,  Werner Kraus ,  Frauke Jordt

    发明人： Oemer Uensal ,  Joachim Kiefer ,  Jochen Baurmeister ,  Jürgen Pawlik ,  Werner Kraus ,  Frauke Jordt

    IPC分类号： B29D7/00

    CPC分类号： B01D67/0088 ,  B01D67/0095 ,  B01D71/62 ,  C08G61/12 ,  C08G73/18 ,  C08G73/22 ,  H01M8/103 ,  H01M8/1048 ,  H01M8/1088 ,  Y02P70/56

    摘要： The present invention relates to an acid-doped polymer membrane based on polyazoles. The acid-doped polymer membrane can be used in a variety of applications because of its excellent mechanical properties and is useful as polymer electrolyte membrane (PEM) in PEM fuel cells. A doped polymer membrane based on polyazoles is obtained by a process comprising the steps of: A) casting a film using a solution of polymers based on polyazoles in a polar, aprotic organic solvent; B) drying the film formed in step A) until it is self-supporting; C) treating the film obtained in step B) with a treatment liquid at a temperature in the range from room temperature to the boiling point of the treatment liquid; D) drying and/or dabbing the film treated according to step C) to remove the treatment liquid from step C); and E) doping the film treated according to step D) with a doping agent.

    摘要翻译： 本发明涉及基于聚唑的酸掺杂聚合物膜。 酸掺杂聚合物膜由于其优异的机械性能可用于各种应用，并且可用作PEM燃料电池中的聚合物电解质膜（PEM）。 通过包括以下步骤的方法获得基于多唑的掺杂聚合物膜：A）使用在极性非质子有机溶剂中基于多唑的聚合物溶液浇铸膜; B）干燥步骤A）中形成的膜，直到其自支撑; C）在处理液的室温至沸点范围内的温度下用处理液处理步骤B）中得到的膜; D）干燥和/或吸收根据步骤C）处理的膜以从步骤C）中除去处理液; 和E）用掺杂剂掺杂根据步骤D）处理的膜。

    PROTON-CONDUCTING POLYMER MEMBRANE COMPRISING POLYMERS CONTAINING PHOSPHONIC ACID GROUPS AND ITS USE IN FUEL CELLS
    7.
    发明申请
    PROTON-CONDUCTING POLYMER MEMBRANE COMPRISING POLYMERS CONTAINING PHOSPHONIC ACID GROUPS AND ITS USE IN FUEL CELLS 审中-公开
    包含含磷酸聚合物的聚合物的导电聚合物膜及其在燃料电池中的使用

    公开(公告)号：US20100227252A1

    公开(公告)日：2010-09-09

    申请号：US12783588

    申请日：2010-05-20

    申请人： Joachim Kiefer ,  Oemer Uensal ,  Gordon Calundann

    发明人： Joachim Kiefer ,  Oemer Uensal ,  Gordon Calundann

    IPC分类号： H01M8/10 ,  B05D5/12

    CPC分类号： C08J5/2268 ,  C08F230/02 ,  C08F271/02 ,  C08F275/00 ,  C08F291/00 ,  C08G61/122 ,  C08G73/08 ,  C08G73/10 ,  C08G73/18 ,  C08G73/22 ,  C08J2379/06 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/103 ,  H01M8/1041 ,  H01M8/1072 ,  Y02P70/56

    摘要： The present invention relates to a proton-conducting polymer membrane comprising polymers containing phosphonic acid groups which is obtainable by a process comprising the steps A) mixing of vinyl-containing phosphonic acid with one or more aromatic tetramino compounds with one or more aromatic carboxylic acids, esters thereof, acid halides thereof or anhydrides thereof which contain at least two acid groups per carboxylic acid monomer, and/or mixing of vinyl-containing phosphonic acid with one or more aromatic and/or heteroaromatic diamino carboxylic acids, esters thereof, acid halides thereof or anhydrides thereof, B) heating of the mixture obtainable according to step A) under inert gas at temperatures of up to 350° C. to form polyazole polymers, C) application of a layer using the mixture from step A) and/or B) to a support, D) polymerization of the vinyl-containing phosphonic acid present in the sheet-like structure obtainable according to step C).

    摘要翻译： 本发明涉及包含含有膦酸基团的聚合物的质子传导性聚合物膜，其可以通过包括以下步骤的方法获得：A）将含乙烯基的膦酸与一种或多种芳族四嗪化合物与一种或多种芳族羧酸混合， 其酯，其酰卤或其酸酐，其每个羧酸单体含有至少两个酸基，和/或含乙烯基的膦酸与一种或多种芳族和/或杂芳族二氨基羧酸，其酯，其酰卤的混合 或其酸酐，B）在惰性气体下在高达350℃的温度下加热根据步骤A）获得的混合物，以形成聚唑聚合物，C）使用来自步骤A）和/或B的混合物 ），D）根据步骤C）获得的片状结构中存在的含乙烯基膦酸的聚合。

    POLYMER MEMBRANE, METHOD FOR THE PRODUCTION AND USE THEREOF
    8.
    发明申请
    POLYMER MEMBRANE, METHOD FOR THE PRODUCTION AND USE THEREOF 审中-公开
    聚合物膜，其生产和使用方法

    公开(公告)号：US20080280182A1

    公开(公告)日：2008-11-13

    申请号：US11931734

    申请日：2007-10-31

    申请人： Oemer Uensal ,  Joachim Kiefer ,  Jochen Baurmeister ,  Jurgen Pawlik ,  Werner Kraus ,  Frauke Jordt

    发明人： Oemer Uensal ,  Joachim Kiefer ,  Jochen Baurmeister ,  Jurgen Pawlik ,  Werner Kraus ,  Frauke Jordt

    IPC分类号： H01M8/10 ,  C08G73/06

    CPC分类号： B01D67/0088 ,  B01D67/0095 ,  B01D71/62 ,  C08G61/12 ,  C08G73/18 ,  C08G73/22 ,  H01M8/103 ,  H01M8/1048 ,  H01M8/1088 ,  Y02P70/56

    摘要： The present invention relates to an acid-doped polymer membrane based on polyazoles. The acid-doped polymer membrane can be used in a variety of applications because of its excellent mechanical properties and is useful as polymer electrolyte membrane (PEM) in PEM fuel cells. A doped polymer membrane based on polyazoles is obtained by a process comprising the steps of: A) casting a film using a solution of polymers based on polyazoles in a polar, aprotic organic solvent; B) drying the film formed in step A) until it is self-supporting; C) treating the film obtained in step B) with a treatment liquid at a temperature in the range from room temperature to the boiling point of the treatment liquid; D) drying and/or dabbing the film treated according to step C) to remove the treatment liquid from step C); and E) doping the film treated according to step D) with a doping agent.

    摘要翻译： 本发明涉及基于聚唑的酸掺杂聚合物膜。 酸掺杂聚合物膜由于其优异的机械性能可用于各种应用，并且可用作PEM燃料电池中的聚合物电解质膜（PEM）。 通过包括以下步骤的方法获得基于多唑的掺杂聚合物膜：A）使用在极性非质子有机溶剂中基于聚唑的聚合物溶液浇铸膜; B）干燥步骤A）中形成的膜，直到其自支撑; C）在处理液的室温至沸点范围内的温度下用处理液处理步骤B）中获得的膜; D）干燥和/或吸收根据步骤C）处理的膜以从步骤C）中除去处理液; 和E）用掺杂剂掺杂根据步骤D）处理的膜。