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41.发明授权Catalytic oligomerization process using synthetic mesoporous crystalline material 失效使用合成介孔结晶材料的催化低聚方法
公开(公告)号：US5134243A
公开(公告)日：1992-07-28
申请号：US718893
申请日：1991-06-21
申请人： Nazeer A. Bhore , Quang N. Le , Grant H. Yokomizo
发明人： Nazeer A. Bhore , Quang N. Le , Grant H. Yokomizo
IPC分类号： C07C2/12
CPC分类号： B01J29/041 , C07C2/12 , C07C2529/70
摘要： A process for upgrading olefins employing new synthetic catalyst of ultra-large pore crystalline material. The new crystalline material exhibits unusually large sorption capacity demonstrated by its benzene adsorption capacity of greater than about 15 grams benzene/100 grams at 50 torr and 25.degree. C., a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 Angstrom Units and a hexagonal arrangement of uniformly sized pores with a maximum perpendicular cross section of at least about 13 Angstrom units.A new process is provided for catalytic oligomerization of olefin feedstock which comprises contacting the feedstock under catalytic conversion conditions with acid metallosilicate solid catalyst having the structure of MCM-41 with hexagonal honeycomb lattice structure consisting essentially of uniform pores in the range of about 20 to 100 Angstroms. The oligomerization reaction is very selective, especially when conducted at temperature of about 40.degree. to 250.degree. C. Low severity reaction permits excellent conversion of lower olefins at pressure of about 100-13,000 pKa range and moderate space velocity.
摘要翻译： 一种使用超大孔结晶材料的新型合成催化剂改质烯烃的方法。 新的结晶材料表现出非常大的吸附能力，其吸附能力在50托和25℃时苯吸附能力大于约15克苯/ 100克，可以用大于约100的d100值进行指数的六方电子衍射图 18埃单位和具有至少约13埃单位的最大垂直截面的均匀尺寸孔的六边形排列。 提供了用于烯烃原料的催化低聚的新方法，其包括在催化转化条件下使原料与具有MCM-41结构的酸性金属硅酸盐固体催化剂接触，其具有基本上由约20至100范围内的均匀孔组成的六方蜂窝晶格结构 埃 低聚反应是非常有选择性的，特别是在约40℃至250℃的温度下进行。低强度反应允许在约100-13000pKa范围和适度的空间速度的压力下对低级烯烃进行极好的转化。
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公开(公告)号：US5118894A
公开(公告)日：1992-06-02
申请号：US732265
申请日：1991-07-18
申请人： Quang N. Le
发明人： Quang N. Le
CPC分类号： C07C2/66 , B01J29/04 , B01J35/002 , B01J35/1019 , B01J35/1023 , B01J35/1028 , B01J35/1057 , B01J35/1061 , C07C2529/70
摘要： Ethylbenzene is produced by the alkylation of benzene with ethylene in the presence of an alkylation catalyst which comprises an inorganic, non-layered, porous, crystalline phase aluminosilicate material whcih exhibits a benzene adsorption capacity of greater than about 15 grams benzene per 100 grams at 50 torr and 25.degree. C. In its preferred catalytic form, the crystalline material has a uniform, hexagonal arrangement of pores with diameters of at least about 13 .ANG. and exhibiting, after calcination, an X-ray diffraction pattern with at least one d-spacing greater than about 18 A and a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 .ANG. which corresponds to at least one peak in the X-ray diffraction pattern. The process is typically carried out at a temperatue of 200.degree. to 1000.degree. F. but the catalyst provides sufficient activity for the reaction to be carried out at temperatures below 700.degree. F. Liquid phase operation is preferred, giving a lower yield of polyethylated products. The use of the selected catalyst also results in a reduction of the xylene impurity level.
摘要翻译： 在烷基化催化剂存在下，通过苯与乙烯的烷基化生产乙苯，该烷基化催化剂包含无机，非分层，多孔的结晶相铝硅酸盐材料，其在50℃下表现出大于约15克苯/ 100克的苯吸附能力 托和25℃。在其优选的催化形式中，结晶材料具有均匀的六边形排列的孔，其直径至少约为13，并且在煅烧之后表现出具有至少一个d间距的X射线衍射图 大于约18的六边形电子衍射图案和可以对应于X射线衍射图中的至少一个峰值的d100值大于约18的折射率的六角形电子衍射图案。 该方法通常在200至1000°F的温度下进行，但催化剂提供足够的活性以使反应在低于700°F的温度下进行。优选液相操作，从而降低聚乙烯化产物的产率 。 使用所选择的催化剂也导致二甲苯杂质水平的降低。
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公开(公告)号：US5100534A
公开(公告)日：1992-03-31
申请号：US609553
申请日：1990-11-06
申请人： Quang N. Le , Paul H. Schipper , Hartley Owen
发明人： Quang N. Le , Paul H. Schipper , Hartley Owen
摘要： An improved process for upgrading paraffinic naphtha to high octane fuel by contacting a naphtha feedstock, such as virgin naphtha feedstock stream containing predominantly C.sub.7 -C.sub.12 alkanes and naphthenes, with solid medium pore acid zeolite cracking catalyst under low pressure selective cracking conditions effective to produce at least 10 wt % selectivity C.sub.4 -C.sub.5 isoalkene. Cracking effluent is separated to obtain a light olefinic fraction rich in C.sub.4 -C.sub.5 isoalkene and a C.sub.6 + liquid fraction of enhanced octane value containing less than 50 wt % aromatic hydrocarbons. In a multistage operation enhanced octane products are obtained by etherifying the isoalkene fraction and by contacting the C.sub.6 + normally liquid fraction with reforming catalyst under moderate reforming conditions at elevated temperature to obtain a reformate product of enhanced octane value.
摘要翻译： 将石脑油原料（如含有主要为C 7 -C 12烷烃和环烷烃的原始石脑油原料流）与固体中孔孔酸沸石裂化催化剂接触的改进方法，该方法是在低压选择性裂解条件下有效生产 至少10重量％的选择性C4-C5异烯烃。 裂解流出物被分离以获得富含C4-C5异烯烃的轻烯烃馏分和含有小于50重量％芳烃的增强辛烷值的C6 +液体馏分。 在多级操作中，通过醚化异烯烃馏分并且在中等重整条件下在升高的温度下使C6 +正常液体馏分与重整催化剂接触获得增强的辛烷值产物，以获得增强的辛烷值的重整产物。
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公开(公告)号：US5609654A
公开(公告)日：1997-03-11
申请号：US455746
申请日：1995-05-31
申请人： Quang N. Le , Robert T. Thomson
发明人： Quang N. Le , Robert T. Thomson
CPC分类号： C07C41/06
摘要： A process for production of alkyl tertiary alkyl ethers in C.sub.4 + hydrocarbon streams rich in isoolefins, typically containing catalyst deactivating amounts of dienes and/or compounds containing heteroatoms. The process is especially advantageous in extending the cycle length for the zeolite catalyzed etherification of isoolefins in C.sub.4 + FCC gasoline by reducing catalyst aging. It has been discovered that if hydrogen is cofed with the alkanol and C.sub.4 + isoolefin rich feedstreams to an etherification reaction catalyzed by acidic zeolite wherein the zeolite has been impregnated with a noble metal the rate of catalyst aging or deactivation is substantially lowered. The process is especially effective, i.e., catalyst aging is particularly reduced, when hydrogen is cofed to an etherification reaction using acidic zeolite Beta catalyst containing palladium.
摘要翻译： 在富含异烯烃的C4 +烃流中生产烷基叔烷基醚的方法，通常含有催化剂失活量的二烯和/或含杂原子的化合物。 该方法特别有利于通过降低催化剂老化来延长C4 + FCC汽油中异烯烃沸石催化醚化的循环长度。 已经发现，如果氢气与链烷醇和C 4 +异烯烃富集的原料流共沸到由酸性沸石催化的醚化反应，其中沸石已经用贵金属浸渍，则催化剂老化或失活的速率显着降低。 当使用含钯的酸性沸石β催化剂将氢气共沸至醚化反应时，该方法特别有效，即催化剂老化特别降低。
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公开(公告)号：US5284984A
公开(公告)日：1994-02-08
申请号：US998807
申请日：1992-12-29
摘要： A method for upgrading an aromatics-containing charge composition boiling in the gasoline boiling range comprises i) contacting the charge composition with a nitrating agent under nitrating conditions to form a product comprising nitrated aromatics; ii) hydrogenating a feed containing the product of i) under conditions sufficient to substantially reduce the nitro group of the nitrated aromatics so as to form a product comprising aromatic amines, water and heavy amines; and iii) removing the water and heavy amines from the product of step ii) to provide a gasoline boiling range product of an octane rating greater than the charge composition.
摘要翻译： 一种用于升级汽油沸程沸腾的含芳烃的电荷组分的方法包括：i）在硝化条件下使电荷组合物与硝化剂接触以形成包含硝化芳族化合物的产物; ii）在足以基本上还原硝化芳族化合物的硝基的条件下氢化含有i）产物的进料，以形成包含芳族胺，水和重胺的产物; 和iii）从步骤ii）的产物中除去水和重胺，以提供辛烷值等于大于电荷组成的汽油沸程产物。
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公开(公告)号：US5231233A
公开(公告)日：1993-07-27
申请号：US878278
申请日：1992-05-04
申请人： Quang N. Le , Grant H. Yokomizo
发明人： Quang N. Le , Grant H. Yokomizo
摘要： There is provided a process for converting light olefin to alcohol(s), ether(s) or mixtures of alcohol(s) and ether(s) which comprises contacting a feed containing at least one light olefin with water in the vapor and/or liquid phase under olefin hydration conditions in the presence of MCM-36 as olefin hydration catalyst to produce said alcohol(s) and/or ether(s).
摘要翻译： 提供了将轻烯烃转化为醇，醚或醇和醚的混合物的方法，其包括使含有至少一种轻质烯烃的进料与蒸气中的水接触和/或 在作为烯烃水合催化剂的MCM-36存在下，在烯烃水合条件下制备所述醇和/或醚。
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47.发明授权Catalysts/process to synthesize alkylated naphthalene synthetic fluids with increased alpha/beta isomers for improving product qualities 失效合成具有增加的α/β异构体的烷基化萘合成流体的催化剂/方法，以改善产品质量
公开(公告)号：US5177284A
公开(公告)日：1993-01-05
申请号：US705997
申请日：1991-05-28
申请人： Quang N. Le , Joosup Shim
发明人： Quang N. Le , Joosup Shim
CPC分类号： C07C2/66 , C07C2529/08 , C07C2529/70
摘要： This application discloses critical parameters, including process conditions and catalysts which effect the alpha:beta ratio of alkylated naphthalene isomers. The use of low alkylation temperatures and of low acidity zeolite catalysts (e.g. steamed USY and zeolite beta) lead to an increase in the alpha:beta ratio. The alkylated naphthalene fluids with higher alpha:beta ratio exhibited significantly enhanced product qualities, including thermal and oxidative stabilities.
摘要翻译： 本申请公开了影响烷基化萘异构体的α：β比的关键参数，包括工艺条件和催化剂。 使用低烷基化温度和低酸度沸石催化剂（例如蒸煮的USY和沸石β）导致α：β比例的增加。 具有较高α：β比率的烷基化萘液显示出显着提高的产品质量，包括热和氧化稳定性。
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48.发明授权Catalytic olefin upgrading process using synthetic mesoporous crystalline material 失效催化烯烃升级过程采用合成介孔结晶材料
公开(公告)号：US5134242A
公开(公告)日：1992-07-28
申请号：US718884
申请日：1991-06-21
CPC分类号： C07C7/177 , B01J29/04 , B01J35/002 , B01J35/1019 , B01J35/1023 , B01J35/1028 , B01J35/1061 , C07C11/02 , C07C2/12 , C07C4/06 , C07C2529/70 , Y02P20/52
摘要： A process for upgrading aliphatic feedstocks containing lower olefins employing new synthetic catalyst of ultra-large pore crystalline material. The new crystalline material exhibits unusually large sorption capacity demonstrated by its benzene adsorption capacity of greater than about 15 grams benzene/100 grams at 50 torr and 25.degree. C., a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 Angstrom Units and a hexagonal arrangement of uniformly sized pores with a maximum perpendicular cross section of at least about 13 Angstrom units. A new process is provied for catalytic oligomerization of lower olefin component in paraffin-containing mixed aliphatic feedstock which comprises contacting the feedstock under catalytic conversion conditions with acid metallosilicate solid catalyst having the structure of MCM-41 with hexagonal honeycomb lattice structure consisting essentially of uniform pores in the range of about 20 to 100 Angstroms. The oligomerization reaction is very selective, especially when conducted at temperature of about 40.degree. to 250.degree. C., yielding branched intermediate olefins. Low severity reaction permits execellent conversion of lower olefins at pressure of about 100-13,000 pKa range and moderate space velocity. Oligomers of propene produced over MCM-41, when reacted under cracking/disproportionation conditions yield a propylene-rich mixture which is separated as a C.sub.3 stream, and C.sub.6 + isoalkenes are recovered in good yield.
摘要翻译： 一种使用新型超大孔结晶材料合成催化剂升级含有低级烯烃的脂肪原料的方法。 新的结晶材料表现出非常大的吸附能力，其吸附能力在50托和25℃时苯吸附能力大于约15克苯/ 100克，可以用大于约100的d100值进行指数的六方电子衍射图 18埃单位和具有至少约13埃单位的最大垂直截面的均匀尺寸孔的六边形排列。 提出了一种新的方法，用于在含链烷烃的混合脂族原料中的低级烯烃组分的催化低聚，其包括在催化转化条件下使原料与具有基本上由均匀孔组成的六方蜂窝晶格结构的具有MCM-41结构的酸性金属硅酸盐固体催化剂 在约20至100埃的范围内。 低聚反应非常有选择性，特别是当在约40℃至250℃的温度下进行时，产生支链中间体烯烃。 低强度反应允许在约100-13000pKa范围和适度的空间速度的压力下进行低级烯烃的非常好的转化。 在裂解/歧化条件下反应时，MCM-41产生的丙烯的低聚物产生作为C3流分离的富丙烯混合物，以良好的收率回收C6 +异烯烃。
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公开(公告)号：US5100533A
公开(公告)日：1992-03-31
申请号：US607952
申请日：1990-11-01
申请人： Quang N. Le , Hartley Owen , Paul H. Schipper
发明人： Quang N. Le , Hartley Owen , Paul H. Schipper
摘要： Process and apparatus for upgrading paraffinic naphtha to high octane fuel by contacting a fresh virgin naphtha feedstock stream medium pore acid cracking catalyst comprising MCM-22 zeolite under low pressure selective cracking conditions effective to produce increased yield of total C4-C5 branched aliphatic hydrocarbhons. The preferred feedstock is straight run naptha containing C7+ alkanes, at least 15 wt % C7+ cycloaliphatic hydrocarbons and less than 20% aromatics, which can be converted with a fluidized bed catalyst in a vertical riser reactor during a short contact period.The isoalkene products of cracking are etherified to provide high octane fuel components.
摘要翻译： 通过在低压选择性裂解条件下接触包含MCM-22沸石的新鲜原始石脑油原料流介质孔隙酸裂解催化剂，有效地产生总C4-C5支链脂族烃的产率提高，将石蜡石脑油升级成高辛烷值燃料的方法和设备。 优选的原料是含有C7 +烷烃，至少15重量％的C7 +脂环族烃和少于20％的芳族化合物的直馏石脑油，其可以在短时间接触期间在垂直提升管反应器中用流化床催化剂转化。 裂化的异烯烃产物被醚化以提供高辛烷值的燃料成分。
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公开(公告)号：US4986894A
公开(公告)日：1991-01-22
申请号：US495545
申请日：1990-03-19
摘要： A process for dewaxing waxy hydrocarbon feedstocks to produce distillate fuels or lubricant stocks having improved pour point properties. The process comprises catalytic hydroisomerization of the feedstock over catalyst comprising a synthetic porous crystalline material characterized in its calcined form by an X-ray diffraction pattern including interplanar d-spacings at 12.36.+-.0.4, 11.03.+-.0.2, 8.83.+-.0.14, 6.18.+-.0.12, 6.00.+-.0.10, 4.06.+-.0.07, 3.91.+-.0.07 and 3.42.+-.0.06 Angstroms, and an Alpha Value of 10 or less.
摘要翻译： 用于脱蜡蜡质原料以生产具有改进的倾点性质的馏出燃料或润滑剂原料的方法。 该方法包括催化剂的催化加氢异构化，其包括合成多孔结晶材料，其特征在于其煅烧形式的X射线衍射图，其包括在12.36 +/- 0.4,11.03 +/- 0.2,8.83 +/-的平面d间距 0.14，6.18 +/- 0.12，6.00 +/- 0.10,4.06 +/- 0.07,3.91 +/- 0.07和3.42 +/- 0.06埃，Alpha值为10以下。
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