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    Rubber compositions comprising coupling agents for mineral-filled elastomer compositions
    46.
    发明授权
    Rubber compositions comprising coupling agents for mineral-filled elastomer compositions 有权
    包含矿物填充弹性体组合物的偶联剂的橡胶组合物

    公开(公告)号：US07902391B2

    公开(公告)日：2011-03-08

    申请号：US12384809

    申请日：2009-04-09

    申请人： Richard W. Cruse ,  Robert J. Pickwell

    发明人： Richard W. Cruse ,  Robert J. Pickwell

    IPC分类号： C07F7/18

    CPC分类号： C08K5/548 ,  C08K5/5419 ,  C08K9/06 ,  C08L21/00

    摘要： A composition of matter is disclosed that comprises at least one silane coupling agent for coupling an elastomer and a filler wherein said silane comprises at least one hydrolysable group that, upon compounding said silane with said elastomer and filler, is released to yield a compound that improves downstream processability of the compounded composition or the properties of the final rubber product or both.

    摘要翻译： 公开了一种物质组合物，其包含用于偶联弹性体和填料的至少一种硅烷偶联剂，其中所述硅烷包含至少一种可水解基团，在将所述硅烷与所述弹性体和填料混合后，其可释放以产生改进的化合物 复合组合物的下游加工性或最终橡胶制品的性能或两者兼有。

    Silane compositions, processes for their preparation and rubber compositions containing same
    47.
    发明授权
    Silane compositions, processes for their preparation and rubber compositions containing same 有权
    硅烷组合物，其制备方法和含有它们的橡胶组合物

    公开(公告)号：US07531588B2

    公开(公告)日：2009-05-12

    申请号：US10918828

    申请日：2004-08-13

    申请人： Keith J. Weller ,  Lesley Hwang ,  Richard W. Cruse ,  Leda Gonzalez ,  Robert J. Pickwell ,  Martin Hofstetter ,  Wesley E. Sloan ,  Prashant G. Joshi

    发明人： Keith J. Weller ,  Lesley Hwang ,  Richard W. Cruse ,  Leda Gonzalez ,  Robert J. Pickwell ,  Martin Hofstetter ,  Wesley E. Sloan ,  Prashant G. Joshi

    IPC分类号： C08K5/24 ,  C07F7/04

    CPC分类号： C08K5/5425 ,  C07F7/1804 ,  C08K5/5406 ,  C08L21/00

    摘要： Silane compositions of the general formula are provided herein comprising [(RO)x(R1)(3-x)—Si-Mt]q-L-[(Ra)cAr—(CR2═CR22)y]z wherein R and R1 are independently a hydrocarbon group of from 1 to about 20 carbon atoms; R2 are each independently hydrogen or a hydrocarbon group of from 1 to about 20 carbon atoms; M optionally is a divalent hydrocarbon connecting group of from 1 to about 20 carbon atoms to link the silicon atom and the L group; L is a covalently bound hydrocarbon linking group of from 1 to about 20 carbon atoms or a heteroatom linking group selected from the group consisting of —O—, —S—, —NR3— wherein R3 is hydrogen or a hydrocarbon group of from 1 to about 20 carbon atoms; Ra is an alkyl group of 1 to 12 carbon atoms; Ar is a substituted or unsubstituted aromatic group; q is an integer of 1 to 4; t and c are each independently 0 or 1; and x, y and z are each independently integers of 1 to 3, inclusive, with the proviso that t is 1 when L is a heteroatom group. Also provided are processes for preparing the silane compositions and rubber composition comprising the silane compositions.

    摘要翻译： 本文提供的硅烷组合物包括<？in-line-formula description =“In-line Formulas”end =“lead”？> [（RO）x（R1）（3-x）-Si-Mt] qL- [（Ra）cAr-（CR2-CR22）y] z <βin-line-formula description =“In-line Formulas”end =“tail”？>其中R和R 1独立地为1 至约20个碳原子; R 2各自独立地为氢或1〜约20个碳原子的烃基; M任选是1至约20个碳原子的连接硅原子和L基团的二价烃连接基团; L是共价键合的1至约20个碳原子的烃连接基团或选自-O - ， - S - ， - NR 3 - 的杂原子连接基团，其中R 3是氢或1〜 约20个碳原子; Ra是1〜12个碳原子的烷基; Ar是取代或未取代的芳基; q为1〜4的整数， t和c各自独立地为0或1; 并且x，y和z各自独立地为1〜3的整数，条件是当L为杂原子基团时，t为1。 还提供了制备包含硅烷组合物的硅烷组合物和橡胶组合物的方法。

    Mineral-filled elastomer compositions
    49.
    发明授权
    Mineral-filled elastomer compositions 有权
    矿物填充弹性体组合物

    公开(公告)号：US06635700B2

    公开(公告)日：2003-10-21

    申请号：US09736301

    申请日：2000-12-15

    申请人： Richard W. Cruse ,  Martin J. Hannon ,  Prashant G. Joshi ,  Frederick D. Osterholtz ,  Robert J. Pickwell

    发明人： Richard W. Cruse ,  Martin J. Hannon ,  Prashant G. Joshi ,  Frederick D. Osterholtz ,  Robert J. Pickwell

    IPC分类号： C08K55419

    CPC分类号： C08K5/548 ,  B60C1/00 ,  B60C1/0016 ,  C08K3/013 ,  C08L23/16 ,  C08L21/00

    摘要： A composition of matter is disclosed wherein the composition comprises: A) at least one latent mercaptosilane coupling agent; and B) at least one additional mercaptan. Preferably, the composition comprises: A) at least one sulfur vulcanizable rubber; B) at least one latent mercaptosilane coupling agent; C) at least one latent mercaptosilane activator; D) at least one filler; and, optionally, E) at least one additional mercaptosilane. A two pass process for preparing cured articles, such as tires and/or tire treads, which employs the composition is also disclosed.

    摘要翻译： 公开了一种物质组合物，其中所述组合物包含：A）至少一种潜在的巯基硅烷偶联剂; 优选地，组合物包含：A）至少一种硫可硫化橡胶; B）至少一种潜在的巯基硅烷偶联剂; C）至少一种潜在的巯基硅烷活化剂; D）至少一种填料; 并且任选地，E）至少一种另外的巯基硅烷。还公开了用于制备使用该组合物的固化物品例如轮胎和/或轮胎胎面的双程过程。

    Low-sulfur polysulfide silanes and process for preparation
    50.
    发明授权
    Low-sulfur polysulfide silanes and process for preparation 有权
    低硫多硫硅烷及其制备方法

    公开(公告)号：US06452034B2

    公开(公告)日：2002-09-17

    申请号：US09477394

    申请日：2000-01-04

    申请人： Richard W. Cruse

    发明人： Richard W. Cruse

    IPC分类号： C07F708

    CPC分类号： C07F7/1892 ,  C07F7/1804

    摘要： An improvement on existing methods to desulfurize oligosulfide silanes generates no added raw materials or waste streams in addition to the sodium chloride which is generated as a byproduct in the current manufacturing process for polyusulfide silanes. This is accomplished by using mercaptosilane salts as desulfurizing agents, which yield more product in addition to that already obtained from the desulfurized silane of higher sulfur rank. The process simply entails reacting an oligosulfide silane with a mercaptosilane salt to thereby obtain an oligosulfide silane whose average sulfur rank is less than the starting oligosulfide silane. Coproduct sulfide salts can be recycled back to the oligosulfide manufacturing process. The mercaptosilane salts are novel materials as well.

    摘要翻译： 除了在目前的多硫化硅硅烷的制造过程中作为副产物产生的氯化钠之外，改进现有的硫代硫硅烷脱硫方法不产生添加的原料或废物流。 这是通过使用巯基硅烷盐作为脱硫剂来实现的，除了已经从较高硫等级的脱硫硅烷获得的产物之外，还产生更多的产物。 该方法简单地使寡硫代硅烷与巯基硅烷盐反应，从而获得平均硫等级低于起始的低聚硫硅烷的低硫硅烷。 副产物硫化物盐可以循环回到寡硫化物制造过程中。 巯基硅烷盐也是新型材料。