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    Prussian blue analogue electrodes without zeolitic water content
    47.
    发明授权
    Prussian blue analogue electrodes without zeolitic water content 有权
    普鲁士蓝色模拟电极，无沸石含水量

    公开(公告)号：US09478798B2

    公开(公告)日：2016-10-25

    申请号：US14830838

    申请日：2015-08-20

    申请人： Sharp Laboratories of America, Inc.

    发明人： Yuhao Lu ,  Jie Song ,  Jong-Jan Lee

    IPC分类号： H01M4/00 ,  H01M4/136 ,  H01M4/58 ,  C01C3/11

    CPC分类号： H01M4/136 ,  C01C3/11 ,  C01C3/12 ,  H01M4/58 ,  Y02E60/122

    摘要： A battery is provided with a hexacyanometallate cathode. The battery cathode is made from hexacyanometallate particles overlying a current collector. The hexacyanometallate particles have the chemical formula AXM1MM2N(CN)Z.d[H2O]ZEO.e[H2O]BND, where A is a metal from Groups 1A, 2A, or 3A of the Periodic Table, where M1 and M2 are each a metal with 2+ or 3+ valance positions, where “ZEO” and “BND” indicate zeolitic and bound water, respectively, where d is 0, and e is greater than 0 and less than 8. The anode material may primarily be a material such as hard carbon, soft carbon, oxides, sulfides, nitrides, silicon, metals, or combinations thereof. The electrolyte is non-aqueous. A method is also provided for fabricating hexacyanometallate with no zeolitic water content in response to dehydration annealing at a temperature of greater than 120 degrees C. and less than 200 degrees C.

    摘要翻译： 电池具有六金属金属阴极。 电池阴极由覆盖集电器的六氰基金属盐颗粒制成。 六氰基金属盐颗粒具有化学式AXM1MM2N（CN）Zd [H2O] ZEO.e [H2O] BND，其中A是元素周期表第1A，2A或3A族的金属，其中M1和M2各自为金属， 2+或3+价位，其中“ZEO”和“BND”分别表示沸石和结合水，其中d为0，e大于0且小于8.阳极材料可主要为诸如 硬碳，软碳，氧化物，硫化物，氮化物，硅，金属或其组合。 电解质是非水的。 还提供了一种方法，用于在大于120℃和小于200℃的温度下响应于脱水退火而制备无沸石含水量的六氰基金属盐酸盐

    Transition Metal Hexacyanoferrate Battery with Carbonaceous Anode
    48.
    发明申请
    Transition Metal Hexacyanoferrate Battery with Carbonaceous Anode 有权
    碳酸阳极过渡金属六氰基铁酸盐电池

    公开(公告)号：US20160285098A1

    公开(公告)日：2016-09-29

    申请号：US15173866

    申请日：2016-06-06

    申请人： Sharp Laboratories of America, Inc.

    发明人： Yuhao Lu ,  Hidayat Kisdarjono ,  Jong-Jan Lee ,  David Evans

    IPC分类号： H01M4/58 ,  H01M4/62 ,  H01M10/054 ,  H01M10/0568

    CPC分类号： H01M4/5825 ,  H01M4/136 ,  H01M4/58 ,  H01M4/625 ,  H01M10/054 ,  H01M10/0568 ,  H01M10/446 ,  H01M2004/028 ,  H02J7/0063 ,  H02J7/0068 ,  Y02E60/122

    摘要： A transition metal hexacyanoferrate (TMH) cathode battery is provided. The battery has a AxMn[Fe(CN)6]y.zH2O cathode, where the A cations are either alkali or alkaline-earth cations, such as sodium or potassium, where x is in the range of 1 to 2, where y is in the range of 0.5 to 1, and where z is in the range of 0 to 3.5. The AxMn[Fe(CN)6]y.zH2O has a rhombohedral crystal structure with Mn2+/3+ and Fe2+/3+ having the same reduction/oxidation potential. The battery also has an electrolyte, and anode made of an A metal, an A composite, or a material that can host A atoms. The battery has a single plateau charging curve, where a single plateau charging curve is defined as a constant charging voltage slope between 15% and 85% battery charge capacity. Fabrication methods are also provided.

    摘要翻译： 提供了一种过渡金属六氰基铁酸盐（TMH）阴极电池。 电池具有AxMn [Fe（CN）6] y.zH 2 O阴极，其中A阳离子是碱金属或碱土金属阳离子，如钠或钾，其中x在1至2的范围内，其中y是 在0.5至1的范围内，其中z在0至3.5的范围内。 AxMn [Fe（CN）6] y.zH2O具有具有相同还原/氧化电位的Mn2 + / 3 +和Fe2 + / 3 +的菱方晶体结构。 电池还具有电解质和由A金属，A复合材料或能够承载A原子的材料制成的阳极。 电池具有单个平台充电曲线，其中单个平台充电曲线被定义为电池充电容量的15％至85％之间的恒定充电电压斜率。 还提供制造方法。