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    SYSTEM AND METHOD FOR LARGE SCALE SYNTHESIS OF METAL CYANOMETALLATES
    3.
    发明申请
    SYSTEM AND METHOD FOR LARGE SCALE SYNTHESIS OF METAL CYANOMETALLATES 有权
    金属氰化物大规模合成的系统和方法

    公开(公告)号：US20160340200A1

    公开(公告)日：2016-11-24

    申请号：US15230395

    申请日：2016-08-06

    申请人： Sharp Laboratories of America, Inc.

    发明人： Yuhao Lu ,  Wei Pan ,  Sean Vail ,  Jong-Jan Lee

    IPC分类号： C01C3/11 ,  H01M10/054 ,  H01M4/58 ,  H01M10/0525 ,  B01J19/18 ,  B01J19/24

    CPC分类号： C01C3/11 ,  B01J19/1862 ,  B01J19/2445 ,  B01J2219/00051 ,  B01J2219/24 ,  C01C3/12 ,  C01P2006/40 ,  H01M2/162 ,  H01M2/1646 ,  H01M4/136 ,  H01M4/1397 ,  H01M4/381 ,  H01M4/387 ,  H01M4/58 ,  H01M4/5825 ,  H01M4/622 ,  H01M4/623 ,  H01M10/0525 ,  H01M10/054 ,  H01M10/0585

    摘要： A system and method are presented for the large scale synthesis of metal cyanometallates (MCMs). First and second precursor solutions are added to a main reactor, where the first precursor includes M1 metal cations. The second precursor solution includes AX′M2(CN)Z′, where M1 and M2 are from a first group of metals and A is from a second group of metals including alkali or alkaline earth metals. In response to stirring the first and second precursors, MCM particles are formed with the formula AXM1NM2M(CN)Z.d[H2O]ZEO.e[H2O]BND, in solution. In response to aging in the secondary reactor, the size of the MCM particles is increases. The aged MCM particles in solution are then transferred to a separation tank, where the aged MCM particles are filtered from the solution and collected. The solution reclaimed from the separation tank back is added back into the main reactor.

    摘要翻译： 提出了一种用于大规模合成金属氰金属（MCM）的系统和方法。 将第一和第二前体溶液加入到主反应器中，其中第一前体包括M1金属阳离子。 第二前体溶液包括AX'M2（CN）Z'，其中M1和M2来自第一组金属，A来自第二组金属，包括碱金属或碱土金属。 响应于搅拌第一和第二前体，在溶液中用式AXM1NM2M（CN）Z.d [H2O] ZEO.e [H2O] BND形成MCM颗粒。 响应于二次反应器中的老化，MCM颗粒的尺寸增加。 然后将溶液中的老化MCM颗粒转移到分离槽中，其中将老化的MCM颗粒从溶液中过滤并收集。 从分离罐回收的溶液回到主反应器中。

    Anode for Sodium-ion and Potassium-ion Batteries
    4.
    发明申请
    Anode for Sodium-ion and Potassium-ion Batteries 有权
    钠离子和钾离子电池阳极

    公开(公告)号：US20160028086A1

    公开(公告)日：2016-01-28

    申请号：US14656808

    申请日：2015-03-13

    申请人： Sharp Laboratories of America, Inc.

    发明人： Sean Vail ,  Yuhao Lu ,  Long Wang ,  Motoaki Nishijima ,  Jong-Jan Lee

    IPC分类号： H01M4/583 ,  H01M10/054 ,  H01M4/62 ,  H01M4/58 ,  H01M4/04 ,  H01M4/1393

    CPC分类号： H01M10/054 ,  C01C3/11 ,  H01M4/0404 ,  H01M4/0471 ,  H01M4/131 ,  H01M4/133 ,  H01M4/1391 ,  H01M4/1393 ,  H01M4/364 ,  H01M4/366 ,  H01M4/38 ,  H01M4/483 ,  H01M4/58 ,  H01M4/587 ,  H01M4/622 ,  H01M4/625 ,  H01M2004/021

    摘要： A first method for fabricating an anode for use in sodium-ion and potassium-ion batteries includes mixing a conductive carbon material having a low surface area, a hard carbon material, and a binder material. A carbon-composite material is thus formed and coated on a conductive substrate. A second method for fabricating an anode for use in sodium-ion and potassium-ion batteries mixes a metal-containing material, a hard carbon material, and binder material. A carbon-composite material is thus formed and coated on a conductive substrate. A third method for fabricating an anode for use in sodium-ion and potassium-ion batteries provides a hard carbon material having a pyrolyzed polymer coating that is mixed with a binder material to form a carbon-composite material, which is coated on a conductive substrate. Descriptions of the anodes and batteries formed by the above-described methods are also provided.

    摘要翻译： 用于制造用于钠离子和钾离子电池的阳极的第一种方法包括混合具有低表面积的导电碳材料，硬质碳材料和粘合剂材料。 由此形成碳复合材料并将其涂覆在导电基板上。 用于制造用于钠离子和钾离子电池的阳极的第二种方法将含金属的材料，硬质碳材料和粘合剂材料混合。 由此形成碳复合材料并将其涂覆在导电基板上。 用于制造用于钠离子和钾离子电池的阳极的第三种方法提供了具有热解聚合物涂层的硬碳材料，其与粘合剂材料混合以形成碳复合材料，其涂覆在导电基材上 。 还提供了通过上述方法形成的阳极和电池的描述。

    Prussian Blue Analogue Electrodes without Zeolitic Water Content
    5.
    发明申请
    Prussian Blue Analogue Electrodes without Zeolitic Water Content 有权
    普鲁士蓝色模拟电极，无沸石含水量

    公开(公告)号：US20150357630A1

    公开(公告)日：2015-12-10

    申请号：US14830838

    申请日：2015-08-20

    申请人： Sharp Laboratories of America, Inc.

    发明人： Yuhao Lu ,  Jie Song ,  Jong-Jan Lee

    IPC分类号： H01M4/136 ,  H01M4/38 ,  H01M4/46 ,  H01M4/134 ,  H01M4/58 ,  C01B21/082 ,  H01M4/42

    CPC分类号： H01M4/136 ,  C01C3/11 ,  C01C3/12 ,  H01M4/58 ,  Y02E60/122

    摘要： A battery is provided with a hexacyanometallate cathode. The battery cathode is made from hexacyanometallate particles overlying a current collector. The hexacyanometallate particles have the chemical formula AXM1MM2N(CN)Z.d[H2O]ZEO.e[H2O]BND. where A is a metal from Groups 1A, 2A, or 3A of the Periodic Table, where M1 and M2 are each a metal with 2+ or 3+ valance positions, where “ZEO” and “BND” indicate zeolitic and bound water, respectively, where d is 0, and e is greater than 0 and less than 8. The anode material may primarily be a material such as hard carbon, soft carbon, oxides, sulfides, nitrides, silicon, metals, or combinations thereof. The electrolyte is non-aqueous. A method is also provided for fabricating hexacyanometallate with no zeolitic water content in response to dehydration annealing at a temperature of greater than 120 degrees C. and less than 200 degrees C.

    摘要翻译： 电池具有六金属金属阴极。 电池阴极由覆盖集电器的六氰基金属盐颗粒制成。 六氰基金属盐颗粒具有化学式AXM1MM2N（CN）Z.d [H2O] ZEO.e [H2O] BND。 其中A是元素周期表1A，2A或3A族的金属，其中M1和M2各自是具有2+或3+价位的金属，其中“ZEO”和“BND”分别表示沸石和结合水 ，其中d为0，e大于0且小于8.阳极材料可主要为诸如硬碳，软碳，氧化物，硫化物，氮化物，硅，金属或其组合的材料。 电解质是非水的。 还提供了一种方法，用于在大于120℃和小于200℃的温度下响应于脱水退火而制备无沸石含水量的六氰基金属盐酸盐

    Hard Carbon Composite for Alkali Metal-Ion Batteries
    6.
    发明申请
    Hard Carbon Composite for Alkali Metal-Ion Batteries 有权
    碱性金属离子电池的硬碳复合材料

    公开(公告)号：US20150270547A1

    公开(公告)日：2015-09-24

    申请号：US14731667

    申请日：2015-06-05

    申请人： Oregon State University ,  Sharp Laboratories of America, Inc.

    发明人： Xiulei Ji ,  Wei Luo ,  Clement Bommier ,  Yuhao Lu ,  Sean Vail ,  Jong-Jan Lee

    IPC分类号： H01M4/583 ,  H01M4/04 ,  H01M4/62

    CPC分类号： H01M10/0525 ,  C01B32/192 ,  C01B32/194 ,  H01M4/133 ,  H01M4/364 ,  H01M4/587 ,  H01M4/622 ,  H01M4/625 ,  H01M10/054 ,  Y10T29/49108

    摘要： A method is provided for fabricating a graphene-doped, carbohydrate-derived hard carbon (G-HC) composite material for alkali metal-ion batteries. The method provides graphene oxide (GO) dispersed in an aqueous solution. A carbohydrate is dissolved into the aqueous solution and subsequently the water is removed to create a precipitate. In one aspect, the carbohydrate is sucrose. The precipitate is dehydrated and exposed to a thermal treatment of less than 1200 degrees C. to carbonize the carbohydrate. The result is the formation of a graphene-doped, carbohydrate-derived hard carbon (G-HC) composite. Typically, the G-HC composite is made up of graphene in the range of 0.1 and 20% by weight (wt %), and HC in the range of 80 to 99.9 wt %. The G-HC composite has a specific surface area of less than 10 square meters per gram (m2/g). A G-HC composite suitable for use in alkali metal-ion batteries electrodes is also provided.

    摘要翻译： 提供一种用于制造用于碱金属离子电池的石墨烯掺杂的碳水化合物衍生的硬碳（G-HC）复合材料的方法。 该方法提供分散在水溶液中的氧化石墨烯（GO）。 将碳水化合物溶解在水溶液中，随后除去水以产生沉淀。 一方面，碳水化合物是蔗糖。 将沉淀物脱水并暴露于低于1200摄氏度的热处理以碳化碳水化合物。 结果是形成了石墨烯掺杂的碳水化合物衍生的硬碳（G-HC）复合材料。 通常，G-HC复合材料由0.1重量％至20重量％（wt％）范围内的石墨烯和80至99.9重量％的HC组成。 G-HC复合材料的比表面积小于10平方米/克（平方米/克）。 还提供了适用于碱金属离子电池电极的G-HC复合材料。

    Transition metal hexacyanometallate-conductive polymer composite
    8.
    发明授权
    Transition metal hexacyanometallate-conductive polymer composite 有权
    过渡金属六氰基金属酸盐导电聚合物复合材料

    公开(公告)号：US09083041B2

    公开(公告)日：2015-07-14

    申请号：US14059599

    申请日：2013-10-22

    申请人： Sharp Laboratories of America, Inc.

    发明人： Sean Andrew Vail ,  Yuhao Lu ,  David Russell Evans ,  Jong-Jan Lee

    IPC分类号： H01M4/133 ,  H01M4/36 ,  H01M4/58 ,  H01M4/60 ,  H01M4/136

    CPC分类号： H01M4/364 ,  H01M4/136 ,  H01M4/137 ,  H01M4/1397 ,  H01M4/1399 ,  H01M4/366 ,  H01M4/58 ,  H01M4/60 ,  H01M4/606 ,  H01M4/608 ,  H01M4/624 ,  H01M10/0525

    摘要： A transition metal hexacyanometallate (TMHCM)-conductive polymer (CP) composite electrode is provided. The battery electrode is made up of a current collector and a transition metal hexacyanometallate-conductive polymer composite overlying the current collector. The transition metal hexacyanometallate-conductive polymer includes a AXM1YM2Z(CN)N.MH2O material, where A may be alkali metal ions, alkaline earth metal ions, ammonium ions, or combinations thereof, and M1 and M2 are transition metal ions. The transition metal hexacyanometallate-conductive polymer composite also includes a conductive polymer material. In one aspect, the conductive polymer material is polyaniline (PANI) or polypyrrole (Ppy). Also presented herein are methods for the fabrication of a TMHCM-CP composite.

    摘要翻译： 提供过渡金属六氰基金属酸盐（TMHCM） - 导电聚合物（CP）复合电极。 电池电极由集电器和覆盖集电器的过渡金属六氰基金属盐酸盐 - 导电聚合物复合体组成。 过渡金属六氰基金属盐酸盐 - 导电聚合物包括AXM1YM2Z（CN）N.MH2O材料，其中A可以是碱金属离子，碱土金属离子，铵离子或其组合，M1和M2是过渡金属离子。 过渡金属六氰基金属盐酸盐 - 导电聚合物复合材料还包括导电聚合物材料。 一方面，导电聚合物材料是聚苯胺（PANI）或聚吡咯（Ppy）。 本文还介绍了制造TMHCM-CP复合材料的方法。

    Metalloporphyrin Polymer Functionalized Substrate
    9.
    发明申请
    Metalloporphyrin Polymer Functionalized Substrate 有权
    金属卟啉聚合物官能化基材

    公开(公告)号：US20150005464A1

    公开(公告)日：2015-01-01

    申请号：US13952535

    申请日：2013-07-26

    申请人： Sharp Laboratories of America, Inc.

    发明人： Sean Andrew Vail ,  David R. Evans ,  Jong-Jan Lee

    IPC分类号： C08G79/00

    CPC分类号： C08G79/00 ,  C08G73/0273 ,  C08G73/0611 ,  C08G2261/314 ,  C08G2261/91 ,  H01L51/0077 ,  Y02E10/549

    摘要： A method is provided for fabricating a metalloporphyrin polymer on a substrate. The method creates a functionalized substrate by attaching an anchor group of a linker, including a terminal alkyne group, to a substrate surface. The functionalized substrate is then exposed to metalloporphyrin monomers, where each metalloporphyrin monomer includes at least two terminal alkyne groups. A plurality of metalloporphyrin monomers (e.g., zinc porphyrin monomers) are thus linked via the metalloporphyrin monomer terminal alkyne groups, forming a metalloporphyrin polymer attached to the substrate. In one aspect, linking the plurality of metalloporphyrin monomers via the metalloporphyrin monomer terminal alkyne groups includes forming butadiyne groups between adjacent metalloporphyrins. Then, forming the metalloporphyrin polymer attached to the substrate includes attaching the metalloporphyrin polymer, via a metalloporphyrin monomer terminal alkyne group, to the terminal alkyne group of an associated linker. Alternatively stated, the metalloporphyrin polymer is attached to the substrate via a polyalkyne group.

    摘要翻译： 提供了一种在基底上制造金属卟啉聚合物的方法。 该方法通过将包含末端炔基的连接体的锚定基团连接到基底表面来产生功能化底物。 然后将官能化底物暴露于金属卟啉单体，其中每个金属卟啉单体包括至少两个末端炔基。 金属卟啉单体（例如锌卟啉单体）由此通过金属卟啉单体末端炔基连接，形成附着在基材上的金属卟啉聚合物。 一方面，通过金属卟啉单体末端炔基连接多个金属卟啉单体包括在相邻的金属卟啉之间形成泛二炔基。 然后，形成附着在基材上的金属卟啉聚合物包括通过金属卟啉单体末端炔基将金属卟啉聚合物连接到相关连接体的末端炔基上。 或者说，金属卟啉聚合物通过聚炔基连接到基底上。

    Method for the Synthesis of Metal Cyanometallates
    10.
    发明申请
    Method for the Synthesis of Metal Cyanometallates 有权
    金属金属酸盐的合成方法

    公开(公告)号：US20140264160A1

    公开(公告)日：2014-09-18

    申请号：US14289746

    申请日：2014-05-29

    申请人： Sharp Laboratories of America, Inc.

    发明人： Yuhao Lu ,  Long Wang ,  Sean Vail ,  Jong-Jan Lee

    IPC分类号： H01M4/58 ,  C01C3/12 ,  C01C3/11

    CPC分类号： H01M4/58 ,  C01C3/11 ,  C01C3/12 ,  C01P2002/50 ,  C01P2006/40

    摘要： Methods are presented for synthesizing metal cyanometallate (MCM). A first method provides a first solution of AXM2Y(CN)Z, to which a second solution including M1 is dropwise added. As a result, a precipitate is formed of ANM1PM2Q(CN)R·FH2O, where N is in the range of 1 to 4. A second method for synthesizing MCM provides a first solution of M2C(CN)B, which is dropwise added to a second solution including M1. As a result, a precipitate is formed of M1[M2S(CN)G]1/T·DH2O, where S/T is greater than or equal to 0.8. Low vacancy MCM materials are also presented.

    摘要翻译： 提出了合成金属氰金属（MCM）的方法。 第一种方法提供AXM2Y（CN）Z的第一溶液，向其中滴加包含M1的第二溶液。 结果，由ANM1PM2Q（CN）R·FH2O形成沉淀物，其中N在1〜4的范围内。合成MCM的第二种方法是提供M2C（CN）B的第一溶液，将其逐滴加入 包括M1的第二个解决方案。 结果，由M1 [M2S（CN）G] 1 / T·DH2O形成沉淀物，其中S / T大于或等于0.8。 还提出了低空缺MCM材料。