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公开(公告)号：US10208259B2
公开(公告)日：2019-02-19
申请号：US15783777
申请日：2017-10-13
Applicant: UOP LLC
Inventor： Avram M. Buchbinder , Stanley J. Frey , Hayim Abrevaya , Falaah Falih
Abstract: A naphtha cracking feed stream is taken, heated and passed to a cracking reactor. Hydrogen is added to the cracking reactor to mitigate catalyst deactivation. The aliphatic compounds are selectively cracked and at least a portion of the alkyl groups on the aromatic compounds are selectively dealkylated in the presence of a cracking catalyst to produce a cracked effluent stream comprising aromatic compounds and cracked olefins.
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公开(公告)号：US20190001314A1
公开(公告)日：2019-01-03
申请号：US16128151
申请日：2018-09-11
Applicant: UOP LLC
Inventor： Avram M. Buchbinder , Hayim Abrevaya , Gavin P. Towler
Abstract: A process utilizing a micro-emulsion is described. The micro-emulsion formed by contacting an ionic liquid, a co-solvent, a hydrocarbon, an optional surfactant, and an optional catalyst promoter to form the micro-emulsion. The micro-emulsion comprises a hydrocarbon component comprising the hydrocarbon and an ionic liquid component comprising the ionic liquid. The ionic liquid comprises a halometallate anion and a cation. The co-solvent has a polarity greater than a polarity of the hydrocarbon. The ionic liquid is present in an amount of 0.05 wt % to 40 wt % of the micro-emulsion. A product mixture comprising a product is produced in a process zone containing the micro-emulsion.
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公开(公告)号：US09914679B2
公开(公告)日：2018-03-13
申请号：US14568970
申请日：2014-12-12
Applicant: UOP LLC
Inventor： Kurt Detrick , David A. Wegerer , Robert J. Schmidt , Trung Pham , Avram M. Buchbinder , Praneeth D. Edirisinghe , Susie C. Martins
CPC classification number: C07C7/12 , B01J31/0277 , B01J31/4069 , B01J38/48 , B01J2231/44 , B01J2531/002 , B01J2531/008 , C07C2/74 , C07C7/13
Abstract: One or more processes for recovering entrained ionic liquid from a hydrocarbon phase containing droplets of ionic liquid are described. The processes includes contacting the hydrocarbon phase containing the droplets of ionic liquid with a retaining material in a separation zone. The droplets of ionic liquid are retained by the retaining material. The ionic liquid may be recovered from the retaining material with a solvent or desorbent. The retaining material may be regenerated and the ionic liquid may be reactivated. The retaining material may be used in a wash vessel to retain or remove contaminant solids within the reactor or other vessels.
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公开(公告)号：US09914675B2
公开(公告)日：2018-03-13
申请号：US14675203
申请日：2015-03-31
Applicant: UOP LLC
Inventor： Avram M. Buchbinder , Douglas A. Nafis , Alakananda Bhattacharyya , Susie C. Martins
CPC classification number: C07C2/60 , C07C2527/125 , C07C2531/02 , C07C2531/22 , C10G29/205 , C10G2300/305 , C10L1/04 , C10L1/06 , C10L10/10 , C10L2270/00 , C07C9/21
Abstract: Alkylation processes are described. The processes utilize ionic liquid catalysts having a kinematic viscosity range of about 50 cSt to about 100 cSt at 25° C. Catalysts within this range produce alkylate having higher octane than catalysts outside this range, especially at higher process temperatures which are preferable from an operating cost standpoint. The alkylate can have one or more of a research octane number of at least about 93, a selectivity of C8 of at least about 65%, and a mole ratio of trimethylpentane to dimethylhexane of greater than about 7:1.
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公开(公告)号：US20180015448A1
公开(公告)日：2018-01-18
申请号：US15713017
申请日：2017-09-22
Applicant: UOP LLC
Inventor： Avram M. Buchbinder , Hayim Abrevaya , Gavin P. Towler
CPC classification number: B01J31/0288 , B01J31/0277 , B01J31/0281 , B01J31/0284 , B01J31/0289 , B01J35/0013 , C07C2/00
Abstract: A micro-emulsion and a method of making the micro-emulsion are described. The micro-emulsion composition includes more than about 50 vol % of an oil phase and polar structures. The oil phase comprises a hydrocarbon component and a co-solvent, and the polar structures comprise an ionic liquid. The ionic liquid comprises a halometallate anion and a cation which is at least slightly soluble in the hydrocarbon component or in the co-solvent. The micro-emulsion can optionally include a surfactant, and a catalyst promoter. The co-solvent has a polarity greater than the polarity of the hydrocarbon, and the co-solvent is miscible in the hydrocarbon.
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Patent Agency Ranking
公开(公告)号：US20170144141A1
公开(公告)日：2017-05-25
申请号：US15331702
申请日：2016-10-21
Applicant: UOP LLC
Inventor： David S. Lafyatis , Sean G. Mueller , Zhanping Xu , Douglas A. Nafis , Robert Mehlberg , Kurt Detrick , Avram M. Buchbinder
CPC classification number: B01J31/0282 , B01J31/0278 , B01J31/0279 , B01J31/0284 , B01J31/0288 , B01J2231/20 , B01J2231/323 , B01J2231/44 , B01J2231/52 , B01J2231/543 , C07C2/26 , C07C2/58 , C07C5/2727 , C07C6/04 , C07C2531/02 , C10G29/205 , C10G50/00 , C07C9/16
Abstract: A method of controlling a hydrocarbon conversion process is described. The method involves introducing a reactant into a reaction zone containing an ionic liquid catalyst. The reaction zone has at least two zones. The mass transfer resistance in the second zone is greater than the mass transfer resistance in the first zone.
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47.发明授权公开(公告)号：US09566578B2
公开(公告)日：2017-02-14
申请号：US14567844
申请日：2014-12-11
Applicant: UOP LLC
Inventor： Michael Brendel , Avram M. Buchbinder , Paul Olson , Susie C. Martins , Kaitlin M. DeSalvo , Douglas A. Nafis
CPC classification number: B01J31/4069 , B01J31/0298 , B01J38/68 , B01J2231/44 , B01J2531/002 , B01J2531/008 , C07F9/025 , C07F9/5407 , Y02P20/584
Abstract: A method for regenerating deactivated acidic ionic liquid is described. The method involves reducing a level of free hydrochloric acid in the deactivated acidic ionic liquid in a removal zone using at least one of heat, a stripping fluid, reduced pressure, and liquid-liquid extraction to form a deactivated acidic ionic liquid having a reduced level of free hydrochloric acid; and regenerating the deactivated acidic ionic liquid having the reduced level of free hydrochloric acid.
Abstract translation: 描述了一种用于再生失活的酸性离子液体的方法。 该方法包括使用热，汽提液，减压和液 - 液萃取中的至少一种来降低去除区中失活的酸性离子液体中的游离盐酸水平，以形成具有降低水平的失活酸性离子液体 的游离盐酸; 并再生具有降低的游离盐酸水平的失活的酸性离子液体。
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48.发明申请公开(公告)号：US20160168058A1
公开(公告)日：2016-06-16
申请号：US14568970
申请日：2014-12-12
Applicant: UOP LLC
Inventor： Kurt Detrick , David A. Wegerer , Robert J. Schmidt , Trung Pham , Avram M. Buchbinder , Praneeth D. Edirisinghe , Susie C. Martins
CPC classification number: C07C7/12 , B01J31/0277 , B01J31/4069 , B01J38/48 , B01J2231/44 , B01J2531/002 , B01J2531/008 , C07C2/74 , C07C7/13
Abstract: One or more processes for recovering entrained ionic liquid from a hydrocarbon phase containing droplets of ionic liquid are described. The processes includes contacting the hydrocarbon phase containing the droplets of ionic liquid with a retaining material in a separation zone. The droplets of ionic liquid are retained by the retaining material. The ionic liquid may be recovered from the retaining material with a solvent or desorbent. The retaining material may be regenerated and the ionic liquid may be reactivated. The retaining material may be used in a wash vessel to retain or remove contaminant solids within the reactor or other vessels.
Abstract translation: 描述了一种或多种用于从含有离子液体的液滴的烃相中回收夹带的离子液体的方法。 这些方法包括将含有离子液体的液滴的烃相与保留材料接触在分离区中。 离子液体的液滴被保持材料保留。 离子液体可以用溶剂或解吸剂从保持材料中回收。 可以再生保留材料，并且可以重新激活离子液体。 保持材料可用于洗涤容器中以保持或去除反应器或其它容器内的污染物固体。
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公开(公告)号：US20160168055A1
公开(公告)日：2016-06-16
申请号：US14567877
申请日：2014-12-11
Applicant: UOP LLC
Inventor： Avram M. Buchbinder , Kurt Detrick , Trung Pham
CPC classification number: C07C7/005 , B01D3/143 , B01D17/0208 , C07C7/04 , C10G29/205 , C10G31/00 , C07C9/10
Abstract: Methods of recovering droplets of ionic liquid catalyst from a process stream are described. The volume fraction of ionic liquid in the hydrocarbon is increased to cause the ionic liquid droplets to coalesce. One method incorporates various combinations of gravity separation zone(s) and fractionation zones. Another method involves using a combination of a flash vessel and a fractionation zone, as well as an optional gravity separation zone.
Abstract translation: 描述了从工艺流中回收离子液体催化剂的液滴的方法。 烃中离子液体的体积分数增加，导致离子液滴聚结。 一种方法包括重力分离区和分馏区的各种组合。 另一种方法包括使用闪蒸容器和分馏区的组合以及可选的重力分离区。
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公开(公告)号：US08884056B2
公开(公告)日：2014-11-11
申请号：US13715571
申请日：2012-12-14
Applicant: UOP LLC
Inventor： Avram M. Buchbinder , Alakananda Bhattacharyya , Joel T. Walenga
IPC: C07C51/487
CPC classification number: C07C51/367 , C07C51/16 , Y02P20/542 , C07C65/03 , C07C63/26
Abstract: A method of decreasing an amount of an aromatic aldehyde in a product is described. The method includes reacting the aromatic aldehyde in the presence of a reaction medium comprising a nucleophilic solvent, or an ionic liquid and a carboxylic acid, the reaction taking place in the absence of a hydrogenating agent and an oxidizing agent, to form aromatic carboxylic acid, an aromatic alcohol, or both.
Abstract translation: 描述了减少产物中芳族醛的量的方法。 该方法包括在包含亲核溶剂或离子液体和羧酸的反应介质的存在下使芳醛反应，该反应发生在不存在氢化剂和氧化剂的情况下，形成芳族羧酸， 芳香醇，或两者。
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