Abstract:
Disclosed are detergent compositions comprising critical amounts of divalent cations and a minimum amount of a mixture of a salt of alpha-sulfonated methyl ester of a fatty acid, anionic surfactants and foam stabilizing auxiliary surfactants.
Abstract:
Disclosed are alkyl sulfoacetate compositions comprising a sulfonated ester of the formula:RO(CH.sub.2 CHR.sub.1 O).sub.n COCH.sub.2 SO.sub.3 MwhereR represents straight chain alkyl having from about 6 to 20 carbon atoms;R.sub.1 is hydrogen, methyl, or ethyl;n is 0, or an integer of from 1 to 20; andM represents a cation;the composition being substantially free from monochloroacetate salts and monochloroacetic acid. These compositions are prepared by reacting an alkyl chloroester of the formula RO(CH.sub.2 CHR.sub.1 O).sub.n COCH.sub.2 Cl where R, R.sub.1 and n are as defined above with an excess of sodium sulfite in the presence of a sulfitation catalyst at a temperature of at least about 75.degree. C. Also disclosed are oral care compositions comprising these surfactant compositions.
Abstract:
A foaming agent having improved foaming performance comprised of a mixture of alkyl sulfates and alkyl ether sulfates which have the general formula: R (CH.sub.2 CH.sub.2 O).sub.y --SO.sub.3 M (I) wherein R is a linear and/or branched hydrocarbon moiety having a maximum molecular weight of about 169, y is an integer, representing the number of moles of ethylene oxide per mole of R and, on a percent by weight distribution of the oxyethylene oligomers, the alkyl sulfate oligomer is from about 25 to 85 percent by weight of the total oligomeric distribution, and the sum of the alkyl sulfate, alkyl mono-ether sulfate, alkyl di-ether sulfate, alkyl tri-ether sulfate, alkyl tetra-ether sulfate, and alkyl penta-ether sulfate oligomers is from about 80 to 96 percent by weight of the total oligomeric distribution; M is a cation capable of producing a water-soluble surfactant; said hydrocarbon moiety being comprised of at least about 80 percent by weight of a first anionic active species, represented by R, having a molecular weight ranging from about 100 to 156, and up to about 20 percent by weight of a second anionic active species, represented by R, having a molecular weight of up to about 86, and up to about 10 percent by weight of a third anionic active species, represented by R, having a molecular weight of about 170 or greater. A method of using this foaming agent in the making of gypsum products and the resulting gypsum products is also disclosed. The foaming agent may also be used for other purposes, for instance, as a fire fighting foam.
Abstract:
Disclosed are methods and compositions for preparing rigid foams by contacting a polyisocyanate with a polyol mixture comprising(a) from about 40-95% by weight of a polyester or polyether polyol;(b) a catalytic amount of a catalyst system comprising a primary catalyst and an amino acid salt catalyst derived from sarcosine; and(c) a non-chlorofluorocarbon blowing agent.
Abstract:
The invention encompasses methods for preparing in high purity and in high yield p-phenyl sulfonic acid acyl glycolates of the formula ##STR1## where R represents branched or straight chain alkyl having 6-12 carbon atoms by treating a phenyl ester or phenyl acyl glycolate of the formula ##STR2## where R represents branched or straight chain alkyl having 6-12 carbon atoms with a sulfonating agent to form intermediate sulfonation; transmuting the intermediate sulfonation products; and quenching the transmuted intermediate sulfonation products with a quenching reagent reactive with sulfur trioxide.
Abstract:
An improved method for deresination of wood chips or pulp is provided. The method comprises contacting the chips or pulp with an ethoxylated alkyl phenol deresinating composition during processing to reduce the level of natural resins present therein. The improvement comprises substituting a sufonated fatty acid for part of the ethoxylated alkyl phenol while maintaining substantially the same level of deresination.
Abstract:
Polyol blend compositions are provided containing nonionic ethoxylate propoxylate compounds and aromatic ester polyols, especially phthalate polyester polyols, which blends are miscible with fluorocarbon blowing agents. These blends are suitable for reaction with polyfunctional organic isocyanates in the presence of polymerization catalysts to make cellular polyurethanes and polyisocyanurates.
Abstract:
A hydraulic fracturing method for recovering oil from a low-temperature subterranean oil formation is disclosed. Before, during, or after inducing hydraulic fracturing within the formation, a particulate, degradable polyester diverting agent is introduced into the formation in an amount effective to improve oil production from the formation. The diverting agent is allowed to degrade, and oil is recovered. The diverting agent has a melting point greater than the average temperature of the formation and is selected from: (i) ethylene glycol succinates; (ii) acid-terminated ethylene glycol succinates; (iii) acid-terminated polyglycolic acids; (iv) acid-terminated polylactic acids; and (v) mixtures of any of (i) through (iv) with a half acid ester.
Abstract:
Non-aqueous solder flux compositions are disclosed. In some aspects, the compositions comprise: (a) an alkylbenzene sulfonic acid or an acidic phosphate ester; and (b) an alkanolamide, an ethoxylated alkanolamide, an alkanolamine, or an ethoxylated amine. Methods of making solder flux compositions and methods of using the compositions as components of tacky solder fluxes are described. The solder flux compositions have excellent wettability, oxide removal capability, and rheological characteristics for high-speed, pick-and-place manufacturing processes and can be made from a simple combination of two components, thereby avoiding the need for solvents, polymeric thickeners, and other components of traditional tacky solder fluxes.