公开(公告)号：US20060094917A1

公开(公告)日：2006-05-04

申请号：US11236477

申请日：2005-09-27

Applicant: Paolo Palmas ,  Daniel Myers ,  Richard Johnson

Inventor： Paolo Palmas ,  Daniel Myers ,  Richard Johnson

IPC: C07C1/00

CPC classification number: B01J38/12 ,  B01J8/0055 ,  B01J8/1818 ,  B01J8/24 ,  B01J8/26 ,  B01J29/85 ,  B01J29/90 ,  B01J2208/00292 ,  B01J2219/00006 ,  C07C1/20 ,  Y02P20/584 ,  Y02P30/42 ,  C07C11/02

Abstract: The present invention comprises a process and apparatus for producing olefins from oxygenates in a reactor. This process comprises these oxygenates with a catalyst to produce a gaseous mixture comprising light olefins and by-products, sending the mixture to a single stage cyclone within said reactor to separate said catalyst from said gaseous mixture and then sending said the to a second stage cyclone. The second stage cyclone is located outside of said reactor and it functions to remove the catalyst from the mixture. Then the catalyst can be returned to the reactor after having been treated in a regeneration zone to remove carbonaceous deposits from the catalyst.

Abstract translation: 本发明包括在反应器中由含氧化合物生产烯烃的方法和装置。 该方法包括这些含氧化物与催化剂以产生包含轻质烯烃和副产物的气体混合物，将混合物送入所述反应器内的单级旋风分离器，以将所述催化剂与所述气体混合物分离，然后将所述催化剂送至第二级旋风分离器 。 第二级旋风分离器位于所述反应器的外部，其功能是从混合物中除去催化剂。 然后可以在再生区中处理催化剂之后将催化剂返回到反应器中以从催化剂除去含碳沉积物。

公开(公告)号：US06967005B2

公开(公告)日：2005-11-22

申请号：US09958622

申请日：2001-02-06

Applicant: Donald L. Wietzke ,  Mikhail Maryamchik ,  Michael L. Silvey ,  Michael J. Szmania

Inventor： Donald L. Wietzke ,  Mikhail Maryamchik ,  Michael L. Silvey ,  Michael J. Szmania

IPC: B01D53/86 ,  B01J8/00 ,  B01J8/38 ,  F23J15/00 ,  B01D53/34 ,  B01D53/50 ,  B01D53/56

CPC classification number: F23J15/006 ,  B01D53/8631 ,  B01J8/005 ,  B01J8/0055 ,  B01J8/388 ,  B01J2208/00292 ,  B01J2208/0053 ,  B01J2219/00006 ,  F23C2206/10 ,  F23J2217/101 ,  F23J2217/102 ,  F23J2217/20 ,  F23J2217/40 ,  F23J2219/10 ,  F23J2219/60

Abstract: A CFB reactor or combustor having a selective catalytic reduction (SCR) system (150) employed downstream of the CFB reactor or combustor furnace (10) together with a dry scrubber system (220) to achieve enhanced NOx reduction.

Abstract translation: 在CFB反应器或燃烧器炉（10）的下游与干式洗涤器系统（220）一起使用具有选择性催化还原（SCR）系统（150）的CFB反应器或燃烧器，以实现增强的NO x 减少。

公开(公告)号：US06919064B2

公开(公告)日：2005-07-19

申请号：US09996142

申请日：2001-11-28

Applicant: Daniel E. Resasco ,  Boonyarach Kitiyanan ,  Walter E. Alvarez ,  Leandro Balzano

Inventor： Daniel E. Resasco ,  Boonyarach Kitiyanan ,  Walter E. Alvarez ,  Leandro Balzano

IPC: B01J8/00 ,  B01J8/38 ,  B01J38/12 ,  B01J38/60 ,  B01J38/64 ,  C01B31/02 ,  D01F9/127 ,  D01F9/12

CPC classification number: B82Y30/00 ,  B01J8/0055 ,  B01J8/388 ,  B01J38/12 ,  B01J38/60 ,  B01J38/64 ,  B01J2208/00292 ,  B82Y15/00 ,  B82Y40/00 ,  C01B32/162 ,  C01B2202/02 ,  D01F9/127 ,  D01F9/1271 ,  D01F9/1272 ,  D01F9/1278 ,  Y02P20/584 ,  Y10S977/843

Abstract: A process and apparatus for catalytic production of single walled carbon nanotubes. Catalytic particles are exposed to different process conditions at successive stages wherein the catalytic particles do not come in contact with reactive (catalytic) gases until preferred process conditions have been attained, thereby controlling the quantity and form of carbon nanotubes produced. The reaction gas is preferably provided at a high space velocity to minimize CO2 build-up. The process also contemplates processes and apparatus which recycle and reuse the gases and catalytic particulate materials, thereby maximizing cost efficiency, reducing wastes, reducing the need for additional raw materials, and producing the carbon nanotubes, especially SWNTs, in greater quantities and for lower costs.

Abstract translation: 用于催化生产单壁碳纳米管的方法和装置。 催化颗粒在连续阶段暴露于不同的工艺条件，其中催化剂颗粒不与反应（催化）气体接触，直到获得优选的工艺条件，从而控制产生的碳纳米管的数量和形式。 优选以高空间速度提供反应气体以最小化CO 2 2积聚。 该方法还考虑了再循环和再利用气体和催化颗粒材料的方法和设备，从而最大限度地提高成本效率，减少废物，减少对额外原材料的需求，以及大量生产碳纳米管，特别是SWNT，并降低成本 。

公开(公告)号：US06911504B2

公开(公告)日：2005-06-28

申请号：US10257357

申请日：2001-04-12

Applicant: Vincent Reiling

Inventor： Vincent Reiling

IPC: B01J8/00 ,  B01J8/24 ,  B01J8/38 ,  C08F2/00 ,  C08F2/34 ,  C08F10/00 ,  C08F110/02

CPC classification number: B01J8/1809 ,  B01J8/0055 ,  B01J8/388 ,  B01J2208/00256 ,  B01J2208/00274 ,  B01J2208/00292 ,  B01J2208/00707 ,  C08F10/00 ,  C08F110/02 ,  Y10S526/901 ,  C08F2/34 ,  C08F2500/18 ,  C08F2500/24

Abstract: A process for the continuous gas-phase (co)polymerization of one or more olefins for which a rising stream of a gas mixture, comprising at least one olefin to be (co)polymerized, maintains polymer particles in the course of formation in the fluidized state in a polymerization reactor, the said stream entraining fine particles above the fluidized bed outside the reactor, the said fine particles being substantially separated from the gas mixture using a separator, thus dividing the said stream into (i) one or more gas streams (A) substantially devoid of solid particles which is cooled and reintroduced below and/or into the bottom part of the fluidized bed, and (ii) one or more gas streams (B) comprising at least a portion of the said particles which is introduced into or above the fluidized bed, which process is characterized in that at least one of the gas streams (B) comprising the solid particles is introduced directly into the fluidized bed by a dilute-phase transport in a simple pipe, that is to say preferably without using equipment for setting in motion.

Abstract translation: 一种或多种烯烃的连续气相（共）聚合的方法，其中包含至少一种待（共）聚合的烯烃的气体混合物的上升流在流化床的过程中保持聚合物颗粒 在聚合反应器中，所述物流夹带在反应器外部的流化床上方的细颗粒，所述细颗粒使用分离器基本上与气体混合物分离，从而将所述流分成（i）一种或多种气流 A）基本上不含在流化床的下部和/或下部冷却并重新引入的固体颗粒，和（ii）一种或多种气流（B），其包含至少部分所述颗粒，其被引入 或以上流化床，该方法的特征在于，包含固体颗粒的气流（B）中的至少一个通过简单的点的稀相输送直接引入流化床 e，也就是说，优选地不使用用于设置运动的设备。

公开(公告)号：US20030199646A1

公开(公告)日：2003-10-23

申请号：US10414025

申请日：2003-04-16

Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED

Inventor： Katsutoshi Kougo

IPC: C08F002/00

CPC classification number: B01J8/382 ,  B01J8/0055 ,  B01J2208/00256 ,  B01J2208/00274 ,  B01J2208/00292 ,  B01J2219/0004 ,  C08F10/06 ,  C08F210/06 ,  C08F2/001 ,  C08F2/34 ,  C08F210/16 ,  C08F2500/12

Abstract: The object of the present invention is to provide a polyolefin polymerization method which prevents fine particles of polymer from scattering from a fluidized bed in a gas phase polymerization reactor. This object is achieved by a process for polymerization of null-olefin in multi-stage polymerization process and in at least two serially arranged polymerization reactors including a gas phase polymerization reactor, the process comprising; drawing out polyolefin particles from a polymerization reactor, and transferring the polyolefin particles into the interior of fluidized bed of a gas phase polymerization reactor of the next stage.

Abstract translation: 本发明的目的是提供一种聚烯烃聚合方法，其防止聚合物细颗粒在气相聚合反应器中从流化床散射。 该目的通过多级聚合方法中的α-烯烃聚合方法和包括气相聚合反应器在内的至少两个串联排列的聚合反应器中实现。 从聚合反应器中抽出聚烯烃颗粒，并将聚烯烃颗粒转移到下一阶段的气相聚合反应器的流化床的内部。

公开(公告)号：US5326550A

公开(公告)日：1994-07-05

申请号：US965011

申请日：1992-10-23

Applicant: Alaa-Eldin M. Adris ,  John R. Grace ,  Choon J. Lim ,  Said S. Elnashaie

Inventor： Alaa-Eldin M. Adris ,  John R. Grace ,  Choon J. Lim ,  Said S. Elnashaie

IPC: B01J8/00 ,  B01J8/18 ,  B01J19/24 ,  C01B3/44 ,  C01B3/50 ,  C01B3/26

CPC classification number: B01J8/009 ,  B01J19/2475 ,  B01J8/0055 ,  B01J8/1836 ,  C01B3/44 ,  C01B3/501 ,  B01J2208/00123 ,  B01J2208/00132 ,  B01J2208/00292 ,  B01J2208/0053 ,  B01J2208/00628 ,  C01B2203/041 ,  C01B2203/047 ,  C01B2203/0475 ,  Y02P30/30 ,  Y10S48/05

Abstract: Hydrogen gas is generated in a fluidized bed reactor by reacting gases namely steam and a hydrocarbon gas such as methane or natural gas in a fluidized bed of particulate catalytic material. The catalytic material is fluidized by injecting the mixture of the reacting gases at the bottom of the bed. Hydrogen generated within the bed is removed via a selectively permeable membrane that extends through the bed and through a freeboard area above the bed. The reaction is endothermic and therefore heat to maintain the bed at the desired temperature is added as required. Preferably a separator separates particulate catalytic material entrained in the gases in the freeboard area and delivers the particulate material separated from the gas back into the bed.

Abstract translation: 在流化床反应器中通过气体（即蒸汽和诸如甲烷或天然气的烃气体）在颗粒催化材料的流化床中产生氢气。 催化材料通过在床的底部注入反应气体的混合物而被流化。 在床内产生的氢通过选择性渗透的膜去除，其延伸穿过床并通过床上方的干舷区域。 反应是吸热的，因此根据需要加入保持床在所需温度的热量。 优选地，分离器分离夹带在干舷区域中的气体中的颗粒催化材料，并将从气体分离的颗粒材料输送回床中。

公开(公告)号：US4543399A

公开(公告)日：1985-09-24

申请号：US594962

申请日：1984-04-03

Applicant: John M. Jenkins, III ,  Russell L. Jones ,  Thomas M. Jones

Inventor： John M. Jenkins, III ,  Russell L. Jones ,  Thomas M. Jones

IPC: B01J8/18 ,  B01J8/24 ,  C08F2/34 ,  C08F10/00

CPC classification number: B01J8/1809 ,  B01J8/1836 ,  C08F10/00 ,  B01J2208/00017 ,  B01J2208/00256 ,  B01J2208/00274 ,  B01J2208/00292 ,  B01J2208/00371 ,  B01J2208/00761 ,  Y10S526/901 ,  Y10S526/903

Abstract: A process is described for increasing the space time yield of polymer production in a fluidized bed reactor employing an exothermic polymerization reaction by cooling the recycle stream to below its dew point and returning the resultant two-phase fluid stream to the reactor to maintain the fluidized bed at a desired temperature above the dew point of the recycle stream.

Abstract translation: 描述了一种方法，用于通过将再循环流冷却至低于其露点并将所得的两相流体流返回到反应器中以使流化床中的聚合物产生的空间时间产量增加，其中使用放热聚合反应 在高于再循环流的露点的期望温度下。

公开(公告)号：US4383095A

公开(公告)日：1983-05-10

申请号：US323352

申请日：1981-11-20

Applicant: George L. Goeke ,  Burkhard E. Wagner ,  Frederick J. Karol

Inventor： George L. Goeke ,  Burkhard E. Wagner ,  Frederick J. Karol

IPC: B01J8/00 ,  B01J8/24 ,  C08F2/34 ,  C08F10/02 ,  C08F110/02

CPC classification number: B01J8/0055 ,  B01J8/0015 ,  B01J8/1872 ,  C08F10/02 ,  B01J2208/00256 ,  B01J2208/00274 ,  B01J2208/00292 ,  B01J2208/00761 ,  C08F110/02 ,  Y10S526/901

Abstract: A catalytic process for preparing ethylene polymers having a density of .gtoreq.0.95 to .ltoreq.0.97 and a melt flow ratio of about .gtoreq.22 to .ltoreq.32 in a low pressure gas phase process at a productivity of .gtoreq.50,000 pounds of polymer per pound of Ti with a catalyst formed from selected organoaluminum compounds and a precursor composition of the formulaMg.sub.m Ti.sub.1 (OR).sub.n X.sub.p [ED].sub.qwherein ED is a selected electron donor compoundm is .gtoreq.0.5 to .ltoreq.56n is 0, 1 or 2p is .gtoreq.2 to .ltoreq.116q=1.5 m+2R is a C.sub.1 to C.sub.14 aliphatic or aromatic hydrocarbon radical, or COR' wherein R' is a C.sub.1 to C.sub.14 aliphatic or aromatic hydrocarbon radical, andX is selected from the group consisting of Cl, Br, I or mixtures thereof,which catalyst is in particulate form and impregnated in a porous inert carrier material.

Abstract translation: 在低压气相方法中，在生产率> / =的情况下，制备密度为≥0.95至0.97的乙烯聚合物和熔体流动比约> / = 22至 / = 2至

公开(公告)号：US4042376A

公开(公告)日：1977-08-16

申请号：US650882

申请日：1976-01-21

Applicant: Per Harald Collin

Inventor： Per Harald Collin

IPC: B01J8/24 ,  B01J8/18 ,  B01J8/28 ,  B01J8/38 ,  C22B1/10

CPC classification number: B01J8/388 ,  B01J8/1836 ,  B01J8/28 ,  B01J2208/00292 ,  B01J2208/0053

Abstract: A method for endothermic reduction of solid materials in a circulating fluid bed comprising a vertically elongated reaction zone of intermediate and lower sections separated by a transport zone, wherein due to high gas velocity therein essentially all materials entering the transport zone are transported from the lower to the intermediate section; an apparatus for carrying out such method is also disclosed.

Abstract translation: 一种用于在循环流化床中吸热还原固体物质的方法，包括由运输区隔开的中间和下部的垂直伸长的反应区，其中基本上所有进入输送区的材料的高气体速度从较低转运到 中间部分 还公开了一种用于执行这种方法的装置。

公开(公告)号：US2856346A

公开(公告)日：1958-10-14

申请号：US36947353

申请日：1953-07-21

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： SEGURA MARNELL A

IPC: B01J8/24 ,  C10B55/08

CPC classification number: B01J8/1809 ,  B01J2208/00292 ,  B01J2208/00539 ,  B01J2208/0061 ,  C10B55/08