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41.发明授权Modified, fine-particle, water-insoluble aziridine polymer and use therefore for removing heavy metals from aqueous solution 失效改性，细颗粒，水不溶性的氮丙啶聚合物及其用于从水溶液中除去重金属的用途
公开(公告)号：US6063286A
公开(公告)日：2000-05-16
申请号：US147170
申请日：1998-10-22
Applicant: Ulrich Steuerle , Wolfgang Reuther , Hubert Meixner , Michael Ehle , Thomas Greindl , Rainer Betz
Inventor： Ulrich Steuerle , Wolfgang Reuther , Hubert Meixner , Michael Ehle , Thomas Greindl , Rainer Betz
CPC classification number: C08G73/0213 , B01J20/267 , C02F1/56 , C08G73/022 , Y10S210/912
Abstract: Process for preparing fine-particle, water-insoluble polymers of aziridines by polymerizing aziridines, preferably ethylenimine, in the presence of crosslinkers which contain at least two functional groups, and in at least one ether, and also modified, water-insoluble polymers of aziridines which can be obtained by reacting fine-particle, water-insoluble, crosslinked polymers of aziridines, in aqueous medium, with carbon disulfide or formaldehyde and a nucleophilic agent from the group consisting of alkali metal cyanides, primary amines, secondary amines, alkali metal sulfites and alkali metal phosphites, and use of the modified and non-modified fine-particle, water-insoluble polymers for immobilizing active compounds, as absorbents for aldehydes, ketones and acids, and also for removing heavy metal ions from wastewaters.
Abstract translation: PCT No.PCT / EP97 / 02062 Sec。 371日期：1998年10月22日 102（e）日期1998年10月22日PCT 1997年4月23日PCT公布。 WO97 / 40088 PCT公开 日期1997年10月30日通过在含有至少两个官能团的交联剂和至少一种醚以及改性的水的存在下聚合氮丙啶，优选乙烯亚胺来制备氮丙啶的微粒，水不溶性聚合物的方法 不溶性的氮丙啶聚合物，其可以通过将水性介质中的微粒，水不溶性，交联的丙烯腈交联聚合物与二硫化碳或甲醛反应而获得，并且亲核试剂由碱金属氰化物，伯胺，仲 胺，碱金属亚硫酸盐和碱金属亚磷酸盐，以及用于固定活性化合物的改性和未改性的微粒，水不溶性聚合物作为醛，酮和酸的吸收剂，以及用于从废水中除去重金属离子 。
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42.发明授权Method of making a composition for separating and concentrating certain ions from mixed ion solutions 失效制备用于从混合离子溶液中分离和浓缩某些离子的组合物的方法
公开(公告)号：US5980987A
公开(公告)日：1999-11-09
申请号：US745026
申请日：1996-11-07
Applicant: Bryon J. Tarbet , Ronald L. Bruening , Anthony J. Di Leo , Philip M. Goddard , Louis M. Scarmoutzos
Inventor： Bryon J. Tarbet , Ronald L. Bruening , Anthony J. Di Leo , Philip M. Goddard , Louis M. Scarmoutzos
IPC: B01D61/00 , B01D67/00 , B01D69/02 , B01D71/82 , B01J20/32 , B01J39/04 , B01J39/18 , B01J45/00 , C02F1/42 , C08J5/22 , G21F9/04 , B05D5/00 , B01D29/00
CPC classification number: B01D67/0093 , B01J20/24 , B01J20/261 , B01J20/262 , B01J20/264 , B01J20/267 , B01J20/28033 , B01J20/28078 , B01J20/28097 , B01J20/321 , B01J20/3212 , B01J20/3217 , B01J20/3219 , B01J20/3251 , B01J20/3282 , B01J45/00 , G21F9/04 , B01D2323/30 , B01J2220/4825 , Y10T428/3154 , Y10T428/31544 , Y10T428/31739 , Y10T428/31913 , Y10T428/31935 , Y10T428/31938 , Y10T428/31971
Abstract: A method for removing, separating, and concentrating certain selected ions from a source solution that may contain larger concentrations of other ions comprises bringing the source solution in contact with a composition comprising an ion-binding ligand covalently bonded to a membrane having hydrophilic surface properties. The ligand portion of the composition has affinity for and forms a complex with the selected ions, thereby removing them from the source solution. The selected ions are then removed from the composition through contact with a much smaller volume of a receiving solution in which the selected ions are either soluble or which has greater affinity for the selected ions than does the ligand portion of the composition, thereby quantitatively stripping the complexed ions from the ligand and recovering them in concentrated form in the receiving solution. The concentrated ions thus removed may be further separated and recovered by known methods. The process is useful in the removal of selected ions, including noble metals and other transition metals from a variety of source solutions such as are encountered in semiconductor, nuclear waste cleanup, metals refining, environmental cleanup, providing ultra high purity fluids, electric power, and other industrial enterprises. The invention is also drawn to the ligand-membrane compositions.
Abstract translation: 用于从可能含有较大浓度的其它离子的源溶液中去除，分离和浓缩某些选定离子的方法包括使源溶液与包含共价键合到具有亲水表面性质的膜的离子结合配体的组合物接触。 组合物的配体部分与所选择的离子具有亲和力并与选择的离子形成复合物，从而将其从源溶液中除去。 然后通过与少量体积的接收溶液（其中所选择的离子是可溶的或对组合物的配体部分具有比选择的离子更大的亲和力）与组合物的配体部分接触来从组合物中除去选定的离子，从而定量地剥离 从配体中复合离子并将其以浓缩形式在接收溶液中回收。 这样除去的浓缩离子可以通过已知的方法进一步分离和回收。 该方法可用于从各种源解决方案中去除选定的离子，包括贵金属和其他过渡金属，例如半导体遇到的核废料清理，金属精炼，环境清洁，提供超高纯度流体，电力， 等工业企业。 本发明还涉及配体 - 膜组合物。
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公开(公告)号：US5945079A
公开(公告)日：1999-08-31
申请号：US994129
申请日：1997-12-19
Applicant: Joseph Timothy Mullhaupt , Neil Andrew Stephenson , Paula Chinn Stephenson
CPC classification number: B01J45/00 , B01D53/02 , B01D53/46 , B01J20/3204 , B01J20/3265 , B01J20/3289 , B01D2257/104
Abstract: The invention comprises a process for air separation using oxygen-selective sorbents with enhanced selectivity, loading capacities and oxygen uptake rates have a transition element complex in solid form supported on a high surface substrate. The transition element complex is substantially uniformly spaced, and includes a transition element ion accessible to an oxygen-containing gas stream during use in the separation of oxygen from an oxygen-containing gas mixture such as air.
Abstract translation: 本发明包括使用具有增强的选择性，负载能力和吸氧速率的氧选择性吸附剂进行空气分离的方法，其具有支撑在高表面基底上的固体形式的过渡元素络合物。 过渡元素络合物基本均匀地间隔开，并且包括在用于从含氧气体混合物如空气分离氧的过程中，含氧气体流可接近的过渡元素离子。
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公开(公告)号：US5908557A
公开(公告)日：1999-06-01
申请号：US854834
申请日：1997-05-12
Applicant: Paul K. Smith , Eugene P. Bergemann
Inventor： Paul K. Smith , Eugene P. Bergemann
CPC classification number: B01J41/043 , B01J45/00 , C02F1/285 , C02F1/56 , C02F1/766 , C02F2101/103 , Y10S210/911
Abstract: A process for the separation of pentavalent arsenic from an aqueous solution using an N-alkyl pyridinium-containing adsorption medium is disclosed. An oxidizing medium and process for the oxidation of trivalent arsenic to pentavalent arsenic with removal of the pentavalent arsenic so formed is also disclosed.
Abstract translation: 公开了一种使用N-烷基吡啶鎓吸附介质从水溶液中分离五价砷的方法。 还公开了氧化介质和三价砷氧化为五价砷的方法，同时除去如此形成的五价砷。
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公开(公告)号：US5885327A
公开(公告)日：1999-03-23
申请号：US708479
申请日：1996-09-05
Applicant: Michael J. Virnig
Inventor： Michael J. Virnig
CPC classification number: B01J45/00 , C22B11/08 , C22B3/24 , Y02P10/234
Abstract: Recovery of gold from alkaline cyanide leach solutions using ion exchange adsorbents, comprising (a) contacting the cyanide leach solution containing the gold with an extraction reagent comprised of a solid adsorbent carrying an organic base functionality of a compound having a pK.sub.a between about 9-14, such as a guanidyl functionality, to adsorb gold and eluting the adsorbed gold from the solid adsorbent with an aqueous alkaline eluant solution having a pH above about 12 and containing an alkali metal salt of an aromatic or aliphatic carboxylic acid having from about 4-14 carbon atoms, the eluant solution having incorprated therein from about 0.001 moles to about 0.2 moles per liter of an alkali metal cyanide salt. The solid adsorbent containing the aurocyanide complex may be contacted with a concentrated aqueous solution of a zinc tetracyanide salt whereby the aurocyanide complex is displaced with a zinc tetracyanide complex before treatment with the eluant solution.
Abstract translation: 使用离子交换吸附剂从碱性氰化物浸出溶液中回收金，其包括（a）使含有金的氰化物浸提溶液与由含有pKa在约9-14之间的化合物的有机碱官能团的固体吸附剂组成的萃取试剂接触 ，例如胍基官能团，用pH高于约12的含水碱性洗脱剂溶液吸附金并从固体吸附剂洗脱金，并含有约4-14的芳族或脂族羧酸的碱金属盐 碳原子，洗脱剂溶液中含有约0.001摩尔至约0.2摩尔/升的碱金属氰化物盐。 可以将含有氰化亚胺配合物的固体吸附剂与浓缩的四氰化锌盐水溶液接触，由此在用洗脱剂溶液处理之前，用四氰化锌络合物置换亚硝酰胺络合物。
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Patent Agency Ranking
公开(公告)号：USRE36118E
公开(公告)日：1999-03-02
申请号：US687632
申请日：1996-07-26
Applicant: Domenico C. Cupertino , Peter A. Tasker
Inventor： Domenico C. Cupertino , Peter A. Tasker
CPC classification number: C22B3/0067 , C22B3/0068 , C22B3/20 , Y02P10/234
Abstract: A method for the recovery of a metal from an organic complex thereof, said method comprising treating the complex with a weakly acid aqueous solution of an alkali metal or alkaline earth metal chloride having a chloride content of at least 4 molar whereby said complex is decomposed and metal ions are transferred to the aqueous solution.
Abstract translation: 一种从其有机络合物中回收金属的方法，所述方法包括用氯化物含量为至少4摩尔的碱金属或碱土金属氯化物的弱酸性水溶液处理络合物，由此所述络合物被分解， 金属离子转移到水溶液中。
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47.发明授权Derivatives of polyethers and of pentacyclic heterocycles, their polymers and their applications, particulary to the complexing of metal ions 失效聚醚和五环杂环的衍生物，它们的聚合物及其应用，特别是金属离子的络合
公开(公告)号：US5830362A
公开(公告)日：1998-11-03
申请号：US699860
申请日：1996-08-20
Applicant: Olivier Leclerc
Inventor： Olivier Leclerc
IPC: C07D333/16 , B01J45/00 , B01J47/08 , C07D207/32 , C07D207/325 , C07D207/333 , C07D333/34 , C07D333/38 , C07D498/22 , C08G61/12 , C08G65/32 , C08G65/333 , C08L71/02 , C08L79/04 , C25B3/00 , C02F1/62 , C08F116/12 , C08F126/06 , C08F128/06
CPC classification number: C07D207/325 , B01J45/00 , B01J47/08 , C08G61/123 , C08G65/33317 , C08L71/02 , C08L79/04 , Y02P20/55 , Y10S210/912
Abstract: It concerns a monomer, a polymer obtained from the monomer and a process for obtaining the said polymer. The monomer consists of a polyether containing at least 3 ether units and pyrrole or thiophene units bonded to the ends of the chains of this polyether via, for each of these heterocycic compounds, either their carbon atoms in the 3,3'-positions of their heterocycles or, as regards more particularly the pyrrole groups, via their respective nitrogen atoms, the 2- and 2'-positions of these heterocycles being, however, free of all substitutions or, at the very most, substituted by easily removable groups (protective groups, for example). Application to the purification and recovery of metal ions such as radioactive silver.
Abstract translation: 它涉及单体，从单体获得的聚合物和获得所述聚合物的方法。 单体由含有至少3个醚单元的聚醚和与该聚醚的链末端键合的吡咯或噻吩单元组成，对于这些杂环化合物中的每一个，它们的3,3'位的碳原子 或者更具体地说是吡咯基团，通过它们各自的氮原子，这些杂环的2位和2位不过是全部取代，或者最多被易于除去的基团取代（保护性 组）。 应用于金属离子如放射性银的纯化和回收。
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公开(公告)号：US5804606A
公开(公告)日：1998-09-08
申请号：US844740
申请日：1997-04-21
Applicant: Joanna Surowiec , Jaques Franc , Jeannot Lucien Hawecker
Inventor： Joanna Surowiec , Jaques Franc , Jeannot Lucien Hawecker
IPC: B01J45/00 , C02F1/42 , C02F5/00 , C08F6/24 , C08F8/00 , C08F8/36 , C08F212/08 , B01J39/18 , C02F1/58 , C02F1/62
CPC classification number: B01J45/00 , C08F212/08 , C08F8/02 , C08F8/12 , C08F8/24 , C08F8/32 , C08F8/40 , C02F1/42 , C02F2101/20 , C02F5/00 , C08F2800/20 , C08F2810/20
Abstract: The present invention is concerned with improved chelating resins. More particularly, the present invention is concerned with macroporous, aminoalkylphosphonic or iminodiacetic acid chelating resins having improved stability and capacity in the removal of cations (e.g. calcium, magnesium, barium and strontium) from brines and in the removal of metals (e.g. nickel, copper and zinc) from waste streams.
Abstract translation: 本发明涉及改进的螯合树脂。 更具体地说，本发明涉及具有改进的从盐水中除去阳离子（例如钙，镁，钡和锶）以及金属去除（例如镍，铜）的稳定性和能力的大孔，氨基烷基膦酸或亚氨基二乙酸螯合树脂 和锌）。
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公开(公告)号：US5738791A
公开(公告)日：1998-04-14
申请号：US714870
申请日：1996-09-17
Applicant: Elwin Schomaker , Abele Broer van der Meer , Johannes Bos , Erik Leonard Middelhoek
Inventor： Elwin Schomaker , Abele Broer van der Meer , Johannes Bos , Erik Leonard Middelhoek
IPC: C08L71/02 , B01J45/00 , C08L101/00 , C08L101/12 , C22B3/24 , B01D11/02 , B01D11/04
CPC classification number: B01J45/00
Abstract: A method for the making and use of a porous, preferably dimensionally stable, hydrophobic polymer for the extraction of metal ions from an aqueous solution, with the polymer being in the form of a regenerative granulate or powder having an average particle diameter of from 0.1 to 10 mm and pores of from 0.1 to 50 .mu.m, which is obtained by the dissolving of a polymer, with heating, at a temperature above the upper critical demixing temperature Tc in a complexing agent containing hydrophobic liquid, followed by lowering of the temperature, resulting in a porous polymer filled with the hydrophobic liquid, and the mechanical diminution of the solidified mass is disclosed. Favorable results have been attained using polypropylene as the hydrophobic polymer, bis(2,4,4-trimethylpentyl)thio acid as the complexing agent, and with a mixture of dibenzyl toluene and/or polypropylene glycol ether being part of the hydrophobic liquid.
Abstract translation: 一种用于制备和使用多孔的，优选尺寸稳定的疏水性聚合物用于从水溶液中萃取金属离子的方法，聚合物为再生颗粒或粉末的形式，其具有平均粒径为0.1至 10mm，孔隙为0.1〜50μm，通过在含有疏水性液体的络合剂中，在高于上限临界分层温度Tc的温度下加热溶解聚合物而获得，随后降低温度， 导致填充有疏水液体的多孔聚合物，并且公开了固化物料的机械减小。 使用聚丙烯作为疏水性聚合物，双（2,4,4-三甲基戊基）硫代酸作为络合剂，以及二烷基甲苯和/或聚丙二醇醚作为疏水液体的一部分的混合物已经获得了有利的结果。
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公开(公告)号：US5578217A
公开(公告)日：1996-11-26
申请号：US346809
申请日：1994-11-30
Applicant: Peter D. Unger , Ronald P. Rohrbach
Inventor： Peter D. Unger , Ronald P. Rohrbach
CPC classification number: B01J20/28047 , B01J20/24 , B01J20/261 , B01J20/262 , B01J20/265 , B01J20/267 , B01J20/28004 , B01J20/28045 , B01J20/28057 , B01J20/28078 , B01J20/3021 , B01J20/3092 , B01J20/3212 , B01J20/3248 , B01J20/3251 , B01J45/00 , C01G3/003 , C08J3/075 , C22B3/24 , B01J2220/4825 , B01J2220/4843 , B01J2220/58 , Y02P10/234
Abstract: A composition comprising a crosslinked, highly porous body derived from a water-soluble hydrogel polymer, said porous body being characterized in that it has an open-celled three-dimensional lattice structure, a density of less than about 1.0 g/cm.sup.3, a surface area of equal to or greater than about 300 m.sup.2 /g, a compression strength of equal to or less than about 10 percent yield at 300 psi, and an average pore diameter of less than about 500 Angstroms, wherein said hydrogel polymer is selected from the group consisting of alginates, gums, starch, dextrins, agar, gelatins, casein, collagen, polyvinyl alcohol, polyethylenimine, acrylate polymers, starch/acrylate copolymers, and mixtures and copolymers thereof; and a metal extractant.The composition may be used in removing and/or recovering metal ions from aqueous streams.A process of recovering metal ions from an aqueous metal ion solution including the steps of impregnating a metal extractant within the porous body described above, contacting the aqueous ion solution with the impregnated porous body in order to remove the metal ions therefrom, and separating the ions from the impregnated porous body.
Abstract translation: 一种组合物，其包含衍生自水溶性水凝胶聚合物的交联的高度多孔体，所述多孔体的特征在于其具有开孔三维晶格结构，密度小于约1.0g / cm 3，表面 面积等于或大于约300m 2 / g，在300psi下的压缩强度等于或小于约10％，平均孔径小于约500埃，其中所述水凝胶聚合物选自 由藻酸盐，树胶，淀粉，糊精，琼脂，明胶，酪蛋白，胶原，聚乙烯醇，聚乙烯亚胺，丙烯酸酯聚合物，淀粉/丙烯酸酯共聚物及其混合物和共聚物组成的组。 和金属萃取剂。 该组合物可用于从水流中除去和/或回收金属离子。 一种从金属离子水溶液中回收金属离子的方法，包括以下步骤：将金属萃取剂浸渍在上述多孔体内，使离子水溶液与浸渍的多孔体接触，以从其中除去金属离子，并将离子 从浸渍的多孔体。
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