利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

528 条记录 (耗时 0.021 秒)

    Functionalized initiators for anionic polymerization
    42.
    发明授权
    Functionalized initiators for anionic polymerization 失效
    用于阴离子聚合的官能化引发剂

    公开(公告)号：US5827929A

    公开(公告)日：1998-10-27

    申请号：US631274

    申请日：1996-04-12

    申请人： James A. Schwindeman ,  Eric J. Granger ,  John F. Engel ,  Conrad W. Kamienski

    发明人： James A. Schwindeman ,  Eric J. Granger ,  John F. Engel ,  Conrad W. Kamienski

    IPC分类号： C07F1/02 ,  C08C19/44 ,  C08F4/48 ,  C08F8/00 ,  C08F36/04 ,  C08F297/04 ,  C07C43/115

    CPC分类号： C08F36/04 ,  C07F1/02 ,  C08C19/44 ,  C08F4/48

    摘要： A process for the preparation of hydrocarbon solutions of monofunctional ether initiators of the following general structure: M--Z--O--C(R.sup.1 R.sup.2 R.sup.3) wherein M is an alkali metal; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; and R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, alkyl, substituted alkyl groups containing lower alkoxy, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkoxy, lower alkylthio, and lower dialkylamino groups, and their employment as initiators in the anionic polymerization of olefin containing monomers in an inert, hydrocarbon solvent comprising reacting an omega-protected-1-haloalkyl with lithium metal dispersion having a particle size between 10 and 300 millimicrons in size, at a temperature between 35.degree. and 130.degree. C. in an alkane solvent containing 5 to 10 carbon atoms.

    摘要翻译： 一种制备以下一般结构的单官能醚引发剂的烃溶液的方法：M-Z-O-C（R 1 R 2 R 3）其中M为碱金属; Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; 并且R 1，R 2和R 3独立地选自氢，烷基，含有低级烷氧基，低级烷硫基和低级二烷基氨基的取代烷基，含有低级烷氧基，低级烷硫基和低级二烷基氨基的芳基或取代芳基， 作为在惰性烃溶剂中含烯烃单体的阴离子聚合中的引发剂，包括使ω-保护的1-卤代烷基与尺寸为10-300毫微米的锂金属分散体在35℃和130℃之间的温度下反应 在含有5至10个碳原子的烷烃溶剂中。

    Functionalized chain extended initiators for anionic polymerization
    44.
    发明授权
    Functionalized chain extended initiators for anionic polymerization 失效
    用于阴离子聚合的官能化扩链引发剂

    公开(公告)号：US5708092A

    公开(公告)日：1998-01-13

    申请号：US631524

    申请日：1996-04-12

    申请人： James A. Schwindeman ,  Conrad W. Kamienski ,  Robert C. Morrison

    发明人： James A. Schwindeman ,  Conrad W. Kamienski ,  Robert C. Morrison

    IPC分类号： C08C19/44 ,  C08F4/08 ,  C08F4/46 ,  C08F4/48 ,  C08F12/04 ,  C08F12/06 ,  C08F36/04 ,  C08F279/02 ,  C07F1/02

    CPC分类号： C08F279/02 ,  C08C19/44 ,  C08F12/04 ,  C08F12/06 ,  C08F36/04 ,  C08F4/46

    摘要： A process for the preparation of hydrocarbon solutions of monofunctional ether initiators of the following general structure: M--Q.sub.n --Z--OA(R.sup.1 R.sup.2 R.sup.3) wherein M is defined as an alkali metal, selected from the group consisting of lithium, sodium and potassium, Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons and alkenylsubstituted aromatic hydrocarbons; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; A is an element selected from carbon and silicon; R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and n is an integer from 1 to 5, monofunctional ethers produced by the process, use of the initiators in a polymerization process and polymers produced by the polymerization process.

    摘要翻译： 一种制备以下一般结构的单官能醚引发剂的烃溶液的方法：M-Qn-Z-OA（R1R2R3）其中M定义为碱金属，选自锂，钠和钾，Q 是通过引入选自共轭二烯烃和烯基取代的芳族烃的化合物衍生的饱和或不饱和烃基; Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; A是选自碳和硅的元素; R 1，R 2和R 3独立地选自氢，烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的取代烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的芳基或取代芳基，n是 1至5的整数，通过该方法产生的单官能醚，在聚合方法中使用引发剂和通过聚合方法制备的聚合物。

    Dichroic crystal
    45.
    发明授权
    Dichroic crystal 失效
    二向晶体

    公开(公告)号：US5656751A

    公开(公告)日：1997-08-12

    申请号：US633516

    申请日：1996-04-17

    申请人： Hiromitsu Tanaka ,  Hisato Takeuchi ,  Arimitsu Usuki ,  Kazuo Tojima ,  Atsushi Shirasawa ,  Ai Kobayashi

    发明人： Hiromitsu Tanaka ,  Hisato Takeuchi ,  Arimitsu Usuki ,  Kazuo Tojima ,  Atsushi Shirasawa ,  Ai Kobayashi

    IPC分类号： C07D487/22 ,  C07F1/02 ,  C07F1/08 ,  C09B47/04 ,  C09B67/00 ,  C09B67/50 ,  G02B1/02

    CPC分类号： C09B67/0026 ,  C09B67/0098

    摘要： Disclosed is a dichroic crystal including at least one member selected from the group consisting of phtharocyanine, a phtharocyanine derivative, phtharocyanine with a central metal introduced therein, a phtharocyanine derivative with a central metal introduced therein, and iodine. It is precipitated when the iodine is added to a solution containing the member, and it includes the iodine in a form of I.sub.3.sup.- and I.sub.5.sup.- ions. It not only has a high dichroic property but also superb heat resistance and weatherability, so that it is applicable to suspended particles display devices used in severe environments.

    摘要翻译： 公开了包含选自下组的至少一种的二色性晶体：酞菁，酞菁衍生物，引入其中的中心金属的phtharocyanine，引入了中心金属的酞菁衍生物和碘。 当将碘加入到含有该成分的溶液中时，其沉淀，并且其包括I 3 - 和I 5 - 离子形式的碘。 它不仅具有高的二色性，而且具有极好的耐热性和耐候性，因此适用于恶劣环境中使用的悬浮颗粒显示装置。

    Anionic polymerization initiators containing adducts of cyclic secondary amines and conjugated dienes, and products therefrom
    46.
    发明授权
    Anionic polymerization initiators containing adducts of cyclic secondary amines and conjugated dienes, and products therefrom 失效
    含有环状仲胺和共轭二烯的加合物的阴离子聚合引发剂及其产物

    公开(公告)号：US5610228A

    公开(公告)日：1997-03-11

    申请号：US471276

    申请日：1995-06-06

    申请人： David F. Lawson ,  Thomas A. Antkowiak ,  James E. Hall ,  Mark L. Stayer, Jr.

    发明人： David F. Lawson ,  Thomas A. Antkowiak ,  James E. Hall ,  Mark L. Stayer, Jr.

    IPC分类号： C08F4/08 ,  C07F1/02 ,  C08F4/42 ,  C08F4/46 ,  C08F4/48 ,  C08F236/04 ,  C08F236/10 ,  C08K5/01

    CPC分类号： C07F1/02

    摘要： An anionic polymerization initiator includes a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene. A method of preparing an anionic polymerization initiator includes reacting an excess of a cyclic secondary amine with a conjugated diene to form an adduct; and, reacting the adduct with an organolithium compound. A method of preparing a polymer includes forming a solution of one or more anionically polymerizable monomers in a hydrocarbon solvent; and, polymerizing the monomer with an anionic polymerization initiator comprising a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene. A functionalized polymer includes the termination product of a living polymer having the general formula AYLi, wherein A is a functional group derived from an anionic polymerization initiator; and, Y is a divalent polymer radical; wherein the anionic polymerization initiator is a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene.

    摘要翻译： 阴离子聚合引发剂包括环状仲胺与共轭二烯的加合物的碳 - 硫酸盐。 制备阴离子聚合引发剂的方法包括使过量的环状仲胺与共轭二烯反应形成加合物; 并使加合物与有机锂化合物反应。 制备聚合物的方法包括在烃溶剂中形成一种或多种阴离子聚合单体的溶液; 并且用包含环状仲胺加成物的碳 - 硫醇盐与共轭二烯的阴离子聚合引发剂聚合单体。 官能化聚合物包括具有通式AYLi的活性聚合物的终止产物，其中A是衍生自阴离子聚合引发剂的官能团; Y为二价聚合物基团; 其中所述阴离子聚合引发剂是环状仲胺与共轭二烯的加合物的碳 - 锂盐。

    Organolithium process
    47.
    发明授权
    Organolithium process 失效
    有机锂工艺

    公开(公告)号：US5523447A

    公开(公告)日：1996-06-04

    申请号：US477843

    申请日：1995-06-07

    申请人： Conrad W. Kamienski ,  James A. Schwindeman ,  B. Troy Dover ,  Robert C. Morrison

    发明人： Conrad W. Kamienski ,  James A. Schwindeman ,  B. Troy Dover ,  Robert C. Morrison

    IPC分类号： C07F1/02 ,  C07F7/08 ,  C07F1/04 ,  C07F7/18

    CPC分类号： C07F1/02

    摘要： A process for preparing easily separable solutions of organolithium compounds comprising the steps of reacting lithium metal, in the form of cast or extruded ingots or pieces cut therefrom, with an organo halide in mole ratios ranging from 3:1 to 20:1 in a solvent selected form a group of liquid hydrocarbons, alkyl ethers, and mixtures thereof under an inert atmosphere for one to ten hours with moderate stirring, cooling the resulting product, and separating the solution of the organolithium compound from the reacted lithium metal and by-product lithium chloride in the reactor.

    摘要翻译： 一种用于制备容易分离的有机锂化合物溶液的方法，包括以下步骤：将以铸造或挤出的锭或其切割的碎片形式的锂金属与摩尔比为3:1至20:1的有机卤化物在溶剂 在惰性气氛下选择形成一组液体烃，烷基醚及其混合物，在适度搅拌下搅拌1至10小时，冷却所得产物，并将有机锂化合物的溶液与反应的锂金属和副产物锂 氯化物在反应器中。

    Anionic polymerization initiators containing adducts of cyclic secondary amines and conjugated dienes, and products therefrom
    48.
    发明授权
    Anionic polymerization initiators containing adducts of cyclic secondary amines and conjugated dienes, and products therefrom 失效
    含有环状仲胺和共轭二烯的加合物的阴离子聚合引发剂及其产物

    公开(公告)号：US5502130A

    公开(公告)日：1996-03-26

    申请号：US469131

    申请日：1995-06-06

    申请人： David F. Lawson ,  Thomas A. Antkowiak ,  James E. Hall ,  Mark L. Stayer, Jr.

    发明人： David F. Lawson ,  Thomas A. Antkowiak ,  James E. Hall ,  Mark L. Stayer, Jr.

    IPC分类号： C08F4/08 ,  C07F1/02 ,  C08F4/42 ,  C08F4/46 ,  C08F4/48 ,  C08F236/04 ,  C08F236/10

    CPC分类号： C07F1/02

    摘要： An anionic polymerization initiator includes a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene. A method of preparing an anionic polymerization initiator includes reacting an excess of a cyclic secondary amine with a conjugated diene to form an adduct; and, reacting the adduct with an organolithium compound. A method of preparing a polymer includes forming a solution of one or more anionically polymerizable monomers in a hydrocarbon solvent; and, polymerizing the monomer with an anionic polymerization initiator comprising a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene. A functionalized polymer includes the termination product of a living polymer having the general formula AYLi, Wherein A is a functional group derived from an anionic polymerization initiator; and, Y is a divalent polymer radical; wherein the anionic polymerization initiator is a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene.

    摘要翻译： 阴离子聚合引发剂包括环状仲胺与共轭二烯的加合物的碳 - 硫酸盐。 制备阴离子聚合引发剂的方法包括使过量的环状仲胺与共轭二烯反应形成加合物; 并使加合物与有机锂化合物反应。 制备聚合物的方法包括在烃溶剂中形成一种或多种阴离子聚合单体的溶液; 并且用包含环状仲胺加成物的碳 - 硫醇盐与共轭二烯的阴离子聚合引发剂聚合单体。 官能化聚合物包括具有通式AYLi的活性聚合物的终止产物，其中A是衍生自阴离子聚合引发剂的官能团; Y为二价聚合物基团; 其中所述阴离子聚合引发剂是环状仲胺与共轭二烯的加合物的碳 - 锂盐。