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公开(公告)号：US09567530B2
公开(公告)日：2017-02-14
申请号：US14554209
申请日：2014-11-26
Applicant: Saudi Arabian Oil Company
Inventor： Ki-Hyouk Choi , Joo-Hyeong Lee , Abdullah T. Alabdulhadi
IPC: C10G9/40 , C10G1/00 , C10G55/04 , B01J19/24 , B01J20/20 , B01J20/28 , B01J20/30 , B01J20/32 , B01J3/00 , C10G31/08 , C10G45/26 , C10G49/18 , C10G1/06
CPC classification number: C10G9/40 , B01D2253/102 , B01D2257/7025 , B01D2259/4525 , B01J3/008 , B01J19/2415 , B01J20/20 , B01J20/28045 , B01J20/28066 , B01J20/28073 , B01J20/28076 , B01J20/3057 , B01J20/3078 , B01J20/3204 , B01J20/3214 , B01J2219/00094 , B01J2219/00105 , B01J2219/0011 , B01J2219/00135 , B01J2219/00157 , B01J2219/00159 , B01J2219/24 , C01B32/05 , C01B32/306 , C10G1/002 , C10G1/065 , C10G31/08 , C10G45/26 , C10G49/18 , C10G55/04 , C10G2300/202 , C10G2300/206 , C10G2300/708
Abstract: A process for reducing coke formation during hydrocarbon upgrading reactions using a double-wall reactor comprising the steps of feeding a heated feed water to a shell-side volume of the double-wall reactor to produce a heat transfer stream, the double-wall reactor comprising an exterior wall and an interior wall, a reaction section volume, a heating element configured to heat the heat transfer stream, wherein heat is transferred from the heat transfer stream to the reaction section volume, feeding the hot water return exiting the shell-side volume through a filter; mixing the filtered water stream with a heated hydrocarbon feedstock; feeding the mixed stream to the reaction section volume in a configuration counter-current to the heat transfer stream; reacting the reaction flow stream at a reaction temperature, wherein the heat transferred to the reaction section volume is operable to maintain the reaction temperature above the critical temperature of water.
Abstract translation: 一种使用双壁反应器在烃升级反应期间减少焦炭形成的方法，包括以下步骤：将加热的进料水进料到双壁反应器的壳侧体积以产生传热流，所述双壁反应器包含 外壁和内壁，反应部分体积，加热元件，其被配置为加热传热流，其中热量从传热流传递到反应部分体积，将离开壳侧体积的热水回流 通过过滤器; 将过滤的水流与加热的烃原料混合; 以与所述传热流逆流的构造将所述混合物流输送到所述反应部分体积; 在反应温度下使反应流动流反应，其中转移到反应段体积的热可操作以将反应温度保持在水的临界温度以上。
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42.发明授权公开(公告)号：US09492851B2
公开(公告)日：2016-11-15
申请号：US14574467
申请日：2014-12-18
Applicant: SHELL OIL COMPANY
Inventor： Joseph Broun Powell , Robert Edward Trepte , Juben Nemchand Chheda
CPC classification number: B08B3/044 , B08B3/04 , C10G1/065 , C10G3/42 , C10G3/50 , C10G3/54 , C10G3/55 , C10G3/60 , C10G2300/1014 , C10G2300/4056 , C10G2300/70 , C10G2400/02 , C10G2400/04 , C10G2400/08 , Y02P30/20
Abstract: A selective removal of metal and its anion species that are detrimental to subsequent hydrothermal hydrocatalytic conversion from the biomass feed in a continuous or semi-continuous manner prior to carrying out catalytic hydrogenation/hydrogenolysis/hydrodeoxygenation of the biomass that does not reduce the effectiveness of the hydrothermal hydrocatalytic treatment while minimizing the amount of water used in the process is provided.
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公开(公告)号：US20160326441A1
公开(公告)日：2016-11-10
申请号：US15157020
申请日：2016-05-17
Applicant: SHELL OIL COMPANY
CPC classification number: C10G1/002 , C08H8/00 , C10G1/065 , C10G3/50 , C10G2300/1014 , C10G2300/208 , C10G2300/44 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10L1/02 , C10L1/04 , C10L2200/0469 , C10L2290/544 , Y02E50/13 , Y02P30/20
Abstract: A process for liquefying a cellulosic material to produce a liquefied product from cellulosic material is provided. Products obtained from such process and use of such products to prepare biofuels is also provided.
Abstract translation: 提供了一种用于液化纤维素材料以从纤维素材料生产液化产品的方法。 还提供从这种方法获得的产品和使用这些产品来制备生物燃料。
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公开(公告)号：US20160319203A1
公开(公告)日：2016-11-03
申请号：US15206900
申请日：2016-07-11
Applicant: Virent, Inc.
Inventor： Ming Qiao , Elizabeth Woods , Paul Myren , Randy Cortright , Sean Connolly
CPC classification number: C10G1/065 , C07D311/72 , C07J75/00 , C08B30/00 , C08B30/12 , C08H6/00 , C08H8/00 , C10G1/06 , C10G3/00 , C10G3/45 , C10G3/47 , C10G3/49 , C10G2300/1011 , C10G2300/1014 , C10G2300/42 , C10G2300/44 , C10G2300/805 , C10G2400/22 , C10G2400/30 , C11B3/006 , C13B10/14 , C13K1/02 , C13K11/00 , C13K13/00 , C13K13/002 , D21B1/021 , Y02P30/20
Abstract: The present invention provides processes for deconstructing biomass to produce aqueous and organic products using a solvent produced in a bioreforming reaction.
Abstract translation: 本发明提供使用在生物反应形成反应中生产的溶剂来解构生物质以产生水和有机产物的方法。
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公开(公告)号：US09481833B2
公开(公告)日：2016-11-01
申请号：US13978374
申请日：2011-12-15
Applicant: Thomas Maschmeyer
Inventor： Thomas Maschmeyer
CPC classification number: C10G1/065 , C10G1/083 , C10G2300/1014 , C10G2300/1059 , C10G2300/4006 , C10G2300/4012 , C10G2300/4081 , C10G2300/802 , C10G2300/805 , C10L1/02 , Y02P30/20
Abstract: A method for biofuel production from high temperature oil-based processing of organic matter, comprising: producing a slurry from organic matter feedstock, water and oil; treating the slurry in a reactor apparatus at increased temperature and pressure; and cooling the slurry and releasing the pressure thereby providing a product comprising the biofuel.
Abstract translation: 一种从有机物的高温油基加工生产生物燃料的方法，包括：从有机物原料，水和油中制备浆料; 在升高的温度和压力下在反应器装置中处理浆料; 并冷却浆料并释放压力，从而提供包含生物燃料的产品。
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Patent Agency Ranking
46.发明授权Continuous flow, high capacity system for rapidly converting hydrocarbon containing post-consumer and post-industrial waste and renewable feedstocks into biofuel 有权连续流动，高容量的系统，用于将含有后消费者和后工业废物和可再生原料的碳氢化合物迅速转化为生物燃料公开(公告)号：US09475993B1
公开(公告)日：2016-10-25
申请号：US14205160
申请日：2014-03-11
Applicant: George Francis Cudahy
Inventor： George Francis Cudahy
CPC classification number: C10G1/008 , B01J3/02 , B01J19/004 , B01J19/20 , C10G1/02 , C10G1/06 , C10G1/10
Abstract: A continuous high capacity system for converting hydrocarbon containing post-consumer waste, post-industrial waste, renewable hydrocarbon feedstock into a biofuel, using a pug for blending less than 200 micron diameter particulate with a plasticizing agent; a sealing auger for forming an agglomerated material and sealing, a cutting device, a vacuum chamber to remove air from the cut material, an extruder forming an extrudate, a heating chamber or the heat exchanger to evolve at least one gas; a pressure sensor and temperature sensors in the heating chamber or the heat exchanger, a cooling chamber providing controlled pressure and controlled temperature cooling of the evolved gasses, wherein the cooling chamber liquefies sequentially at least 50 percent of the evolved gasses forming a liquid.
Abstract translation: 用于将含有消耗后废物，后工业废物，可再生烃原料转化为生物燃料的连续高容量系统，使用用于将小于200微米直径的颗粒与增塑剂混合的巴布; 用于形成附聚材料并密封的密封螺旋钻，切割装置，从切割材料中除去空气的真空室，形成挤出物的挤出机，加热室或热交换器以放出至少一种气体; 加热室或热交换器中的压力传感器和温度传感器，提供控制压力和放出气体的受控温度冷却的冷却室，其中冷却室顺序地液化至少50％的形成液体的放出气体。
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47.发明授权Hydrothermal hydrocatalytic treatment of biomass using water tolerant catalysts 有权使用耐水催化剂的水热催化处理生物质公开(公告)号：US09469822B2
公开(公告)日：2016-10-18
申请号：US14133704
申请日：2013-12-19
Applicant: Shell Oil Company
IPC: C07C1/00 , C10L1/18 , B01J21/04 , C10G1/06 , C10G3/00 , B01J37/20 , B01J23/882 , B01J35/10 , B01J37/02 , B01J23/86 , B01J23/88 , B01J35/00 , B01J35/02
CPC classification number: C10L1/1802 , B01J21/04 , B01J23/86 , B01J23/88 , B01J23/882 , B01J35/0046 , B01J35/026 , B01J35/1009 , B01J35/1014 , B01J35/1066 , B01J37/0201 , B01J37/20 , C10G1/065 , C10G3/46 , C10G3/48 , C10G3/50 , C10G2300/1014 , Y02E50/13 , Y02P30/20
Abstract: A method of hydrothermal hydrocatalytic treating biomass is provided. Lignocellulosic biomass solids is provided to a hydrothermal digestion unit in the presence of a digestive solvent, and a supported hydrogenolysis catalyst containing (a) sulfur, (b) Mo or W, and (c) Co, Ni or mixture thereof, incorporated into an alumina support, which support is predominantly alpha alumina; (ii) heating the lignocellulosic biomass solids and digestive solvent in the presence of hydrogen, and supported hydrogenolysis catalyst thereby forming a product solution containing plurality of oxygenated hydrocarbons, said alumina support having a specific surface area of up to about 30 m2/g and said catalyst retaining a crush strength of at least 50% after being subjected to an aqueous phase stability test compared with before the aqueous phase stability test or a crush strength of at least 0.25 kg after being subjected to an aqueous phase stability test.
Abstract translation: 提供了一种水热催化处理生物质的方法。 将木质纤维素生物质固体在消化溶剂存在下提供给水热消解装置，以及负载的氢解催化剂，其包含（a）硫，（b）Mo或W，和（c）Co，Ni或其混合物， 氧化铝载体，其主要是α氧化铝; （ii）在氢气存在下加热木质纤维素生物质固体和消化溶剂，以及负载的氢解催化剂，由此形成含有多个含氧烃的产物溶液，所述氧化铝载体的比表面积高达约30m 2 / g，所述 在进行水相稳定性试验后，与水相稳定性试验相比，在进行水相稳定性试验后，在进行水相稳定性试验后，将至少50％的压碎强度保持在至少0.25kg的压碎强度。
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48.发明授权Continuous or semi-continuous biomass wash system for hydrothermal hydrocatalytic conversion 有权用于水热催化转化的连续或半连续生物质洗涤系统公开(公告)号：US09446436B2
公开(公告)日：2016-09-20
申请号：US14574426
申请日：2014-12-18
Applicant: SHELL OIL COMPANY
Inventor： Joseph Broun Powell , Robert Edward Trepte , Juben Nemchand Chheda
CPC classification number: B08B3/044 , B01D11/0242 , B01D11/0284 , B08B3/04 , C08H8/00 , C10G1/065 , C10G2300/1014 , C10G2300/205 , C10G2300/44 , Y02P30/20
Abstract: A selective removal of metal and its anion species that are detrimental to subsequent hydrothermal hydrocatalytic conversion from the biomass feed in a continuous or semi-continuous manner prior to carrying out catalytic hydrogenation/hydrogenolysis/hydrodeoxygenation of the biomass that does not reduce the effectiveness of the hydrothermal hydrocatalytic treatment while minimizing the amount of water used in the process is provided.
Abstract translation: 在进行生物质的催化氢化/氢解/加氢脱氧之前，以连续或半连续的方式选择性去除金属及其阴离子物质，对生物质进料的后续水热催化转化是不利的，其不会降低生物质的有效性 提供水热加氢处理，同时最小化该方法中使用的水量。
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公开(公告)号：US20160222298A1
公开(公告)日：2016-08-04
申请号：US15021507
申请日：2014-09-11
Applicant: Research Triangle Institute
Inventor： Matthew Von Holle , John R. CARPENTER , David c. Dayton
CPC classification number: C10B53/02 , C10B49/10 , C10B49/16 , C10B57/06 , C10C5/00 , C10G1/06 , C10G1/08 , C10L1/02 , Y02E50/13 , Y02E50/14 , Y02E50/30 , Y02E50/32 , Y02T50/678
Abstract: This invention is directed to the discovery of a reactive catalytic fast pyrolysis (RCFP) process utilizing hydrogen at low pressures.
Abstract translation: 本发明涉及在低压下利用氢的反应催化快速热解（RCFP）方法的发现。
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公开(公告)号：US09399836B2
公开(公告)日：2016-07-26
申请号：US14575112
申请日：2014-12-18
Applicant: SHELL OIL COMPANY
Inventor： Joseph Broun Powell , Juben Nemchand Chheda
CPC classification number: D21C11/0007 , C07C1/24 , C07C29/132 , C07G1/00 , C08H8/00 , C10G1/065 , C10G3/42 , C10G3/50 , C10G2300/1014 , C10G2300/202 , C10G2300/205 , C10G2300/4081 , C13K1/02 , D21C11/0028 , Y02P30/20
Abstract: A selective removal chlorine and phosphorus that are detrimental to subsequent hydrothermal hydrocatalytic conversion from the biomass feed prior to carrying out catalytic hydrogenation/hydrogenolyzis/hydrodeoxygenation of the biomass in a manner that does not reduce the effectiveness of the hydrothermal hydrocatalytic treatment while minimizing the amount of water used in the process is provided.
Abstract translation: 在生物质的催化氢化/氢解/加氢脱氧之前，不会降低水热催化剂处理的有效性，同时最小化生物质的量，从而对生物质进料的后续水热催化转化有害的选择性去除氯和磷 提供了该过程中使用的水。
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