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    Conversion system for converting oxygenates to hydrocarbons
    51.
    发明授权
    Conversion system for converting oxygenates to hydrocarbons 失效
    将含氧化合物转化为碳氢化合物的转化系统

    公开(公告)号：US4985203A

    公开(公告)日：1991-01-15

    申请号：US11666

    申请日：1987-02-05

    申请人： Samuel A. Tabak

    发明人： Samuel A. Tabak

    IPC分类号： C07C1/20 ,  C07C9/16

    CPC分类号： C07C9/16 ,  C07C1/20 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2529/70 ,  Y02P30/42

    摘要： Aliphatic oxygenates are converted to high octane gasoline by an integrated reactor system wherein three reaction zones are utilized. In a first reaction zone the oxygenates are directly converted to gasoline and an isobutane by-product. In a second reaction zone oxygenates are dehydrated to an intermediate product comprising C.sub.3 -C.sub.4 olefins, which are then further reacted with the isobutane by-product in a third reaction zone to yield a gasoline alkylate. Ethylene-containing vapors may be separated from the second reaction zone and recycled to the first reaction zone for further processing.

    摘要翻译： 脂肪族含氧化合物通过其中使用三个反应区的一体化反应器系统转化成高辛烷值汽油。 在第一反应区中，含氧化合物直接转化为汽油和异丁烷副产物。 在第二反应区中，将含氧化合物脱水至包含C 3 -C 4烯烃的中间产物，然后在第三反应区中与异丁烷副产物反应，得到烷基化汽油。 含乙烯的蒸气可以与第二反应区分离，并循环到第一反应区进行进一步处理。

    Multistage catalytic reactor system for production of heavy hydrocarbons
    53.
    发明授权
    Multistage catalytic reactor system for production of heavy hydrocarbons 失效
    用于生产重质烃的多级催化反应器系统

    公开(公告)号：US4919896A

    公开(公告)日：1990-04-24

    申请号：US260348

    申请日：1988-10-20

    申请人： Mohsen N. Harandi ,  Hartley Owen ,  Samuel A. Tabak

    发明人： Mohsen N. Harandi ,  Hartley Owen ,  Samuel A. Tabak

    IPC分类号： C07C2/00 ,  C07C2/12 ,  C10G50/00 ,  C10L1/06

    CPC分类号： C10G50/00 ,  C07C2/00 ,  C07C2/12 ,  C10L1/06 ,  C07C2529/40 ,  C10G2300/1092 ,  C10G2400/04

    摘要： A multi-stage catalytic olefin upgrading reactor system for converting lower olefinic feedstock to heavier liquid hydrocarbon product. The novel apparatus includes a fluid bed continuous primary stage reaction zone with shape selective medium pore zeolite oligomerization catalyst particles to convert at least a portion of the lower olefinic components to intermediate olefinic hydrocarbons containing olefinic and aromatic components; means are provided for cooling primary stage reaction effluent to condense at least a portion of the intermediate hydrocarbons, feeding a second olefinic stream to a serially arranged multi-reactor secondary stage for upgrading lower olefins, quenching partially upgraded secondary stage olefins with primary stage liquid, and further contacting the quenched mixture including aromatics from the primary stage with oligomerization catalyst in a high pressure fixed bed secondary stage distillate mode catalytic reactor at elevated temperature and high pressure to provide a heavier hydrocarbon effluent stream comprising distillate hydrocarbons.

    摘要翻译： 用于将较低级烯烃原料转化为较重液体烃产品的多级催化烯烃改质反应器系统。 该新型装置包括具有形状选择性中孔沸石低聚催化剂颗粒的流化床连续初级反应区，以将至少一部分低级烯烃组分转化为含有烯属和芳族组分的中间体烯烃; 提供了用于冷却初级阶段反应流出物以冷凝至少一部分中间烃的装置，将第二烯烃流进料到串联排列的多级反应器第二级以升级低级烯烃，用初级阶段液体骤冷部分升级的二级烯烃， 并且在高温和高压下将包含初级阶段的淬灭的混合物与低聚催化剂在高压固定床二级馏分模式催化反应器中进一步接触，以提供包含馏出物烃的较重烃流出物流。

    Integrated reactor system for converting oxygenates to alkylated liquid hydrocarbons
    54.
    发明授权
    Integrated reactor system for converting oxygenates to alkylated liquid hydrocarbons 失效
    用于将含氧化合物转化为烷基化液体烃的集成反应器系统

    公开(公告)号：US4767604A

    公开(公告)日：1988-08-30

    申请号：US919151

    申请日：1986-10-15

    申请人： Hartley Owen ,  Samuel A. Tabak ,  Bernard S. Wright

    发明人： Hartley Owen ,  Samuel A. Tabak ,  Bernard S. Wright

    IPC分类号： C07C1/20

    CPC分类号： C07C1/20 ,  C07C2527/1206 ,  C07C2529/06 ,  C07C2529/40 ,  Y02P30/42

    摘要： Alkylate is produced by catalytically converting oxygenate feedstock, such as methanol, to lower olefins comprising C.sub.2 -C.sub.4 olefins. Ethene is separated by interstage sorption of C.sub.3 + components and an isoparaffin is alkylated with C.sub.3 -C.sub.4 olefins derived from sorbate. The system comprises means for fractionating an olefinic feedstream containing ethene and C.sub.3 + olefinic components by contacting the olefinic feedstream in a sorption zone with a liquid hydrocarbon sorbent to selectively sorb C.sub.3.sup.+ components; means for reacting C.sub.3.sup.+ olefins with excess isoparaffin in a catalytic alkylation reactor to produce C.sub.7 + alkylate hydrocarbons; fractionating the alkylation reactor effluent to provide a liquid hydrocarbon fraction rich in C.sub.7.sup.+ alkylate. Liquid recycle or C.sub.5.sup.+ liquid coproduced with the lower olefin may be passed to the sorption zone as lean sorbent. C.sub.7.sup.+ alkylate product and C.sub.5.sup.+ gasoline are recovered from the process.

    摘要翻译： 烷基化物通过将含氧化合物原料如甲醇催化转化成包含C 2 -C 4烯烃的低级烯烃来制备。 乙烯通过C3 +组分的级间吸附分离，异链烷烃用来自山梨酸酯的C3-C4烯烃烷基化。 该系统包括通过使吸附区中的烯烃进料流与液体烃吸附剂接触以选择性吸附C3 +组分来分馏含有乙烯和C3 +烯烃组分的烯烃进料流的装置; 在催化烷基化反应器中使C3 +烯烃与过量的异链烷烃反应以产生C7 +烷基化烃的方法; 分馏烷基化反应器流出物以提供富含C7 +烷基化物的液体烃馏分。 与低级烯烃共同生产的液体循环或C5 +液体可以作为贫吸收剂被传递到吸附区。 从该方法中回收C7 +烷基化物产物和C5 +汽油。

    Zeolite catalysis process for conversion of diene-containing olefins to aromatic hydrocarbons
    55.
    发明授权
    Zeolite catalysis process for conversion of diene-containing olefins to aromatic hydrocarbons 失效
    用于将含二烯烃烯烃转化为芳族烃的沸石催化方法

    公开(公告)号：US4751339A

    公开(公告)日：1988-06-14

    申请号：US6089

    申请日：1987-01-23

    申请人： James H. Beech, Jr. ,  Samuel A. Tabak

    发明人： James H. Beech, Jr. ,  Samuel A. Tabak

    IPC分类号： C07C2/00 ,  C07C15/00 ,  C10G29/00

    CPC分类号： C07C15/00 ,  C07C2/00 ,  C07C2529/40 ,  Y02P20/584

    摘要： A technique for continuous conversion of diene-containing aliphatic hydrocarbon feedstock to heavier hydrocarbon products wherein the feedstock is contacted at elevated temperature under endothermic high severity reaction conditions with a fluidized bed of acidic zeolite fine catalyst particles, comprising methods and means for:maintaining the fluidized catalyst bed in a vertical reactor having a turbulent reaction zone by passing vapor upwardly through the reaction zone at a velocity greater than dense bed transition velocity to a turbulent regime and less than transport velocity for the average catalyst particle;feeding a continuous stream of feedstock into the reaction zone, said feedstream comprising sufficient C.sub.3.sup.+ alkanes to require net endothermic reaction conditions;withdrawing a portion of coked catalyst from the reaction zone, oxidatively regenerating the withdrawn catalyst, heating the catalyst substantially above process temperature in the fluidized bed reactor, and returning hot regenerated catalyst to the reaction zone at a rate to control catalyst activity and reaction temperature under conditions of reaction severity to effect feedstock conversion to an aromatics-rich hydrocarbon effluent stream; andseparating an aromatics-rich product from the fluidized bed effluent stream.Aromatics yield is increased by recovering a recycle stream comprising C.sub.5.sup.+ aliphatic hydrocarbons from the fluidized bed effluent stream for further conversion in the fluidized bed to increase aromatics product yield.

    摘要翻译： 一种用于将含二烯烃的脂族烃原料连续转化为较重烃产物的技术，其中原料在吸热高度苛刻度的反应条件下在升高的温度下与酸性沸石细催化剂颗粒的流化床接触，包括以下步骤： 催化剂床在具有湍流反应区的立式反应器中，通过使蒸气向上通过反应区，速度大于致密床转变速度至湍流状态且小于平均催化剂颗粒的输送速度; 将连续的原料流送入反应区，所述进料流包含足够的C3 +烷烃以需要净吸热反应条件; 将一部分焦化催化剂从反应区中取出，氧化再生催化剂，在流化床反应器中将催化剂加热至高于工艺温度，并将热再生催化剂返回到反应区，以控制催化剂活性和反应温度 使原料转化成富含芳烃的烃流出物流的反应条件; 以及从流化床流出物流中分离富含芳烃的产物。 通过从流化床流出物流中回收包含C5 +脂族烃的再循环料流以在流化床中进一步转化以提高芳族化合物产物产率来提高芳族化合物产率。

    Olefin upgrading system for extracted feed
    58.
    发明授权
    Olefin upgrading system for extracted feed 失效
    提取饲料的烯烃升级系统

    公开(公告)号：US4626415A

    公开(公告)日：1986-12-02

    申请号：US716317

    申请日：1985-03-27

    申请人： Samuel A. Tabak

    发明人： Samuel A. Tabak

    IPC分类号： C07C1/04 ,  C07C2/12 ,  C07C11/02 ,  B01J8/04 ,  C07C2/02

    CPC分类号： C07C2/12 ,  C07C1/0485 ,  C07C11/02 ,  C07C2529/40

    摘要： Apparatus is disclosed for oligomerizing olefinic Fischer-Tropsch liquids to produce heavier hydrocarbons by converting olefinic feedstock containing oxygenated hydrocarbons over an acidic zeolite catalyst. The improvement comprises an extraction unit for removing oxygenates from the feedstock; means for converting the extracted feedstock in a primary stage distillate mode catalytic reactor system under low severity conditions at high pressure and moderate pressure; means for recovering the oxygenates and light hydrocarbons from the primary stage and a secondary stage reactor system for conversion of oxygenates under high severity conditions at substantially higher temperature than the primary stage, thereby converting oxygenates and light hydrocarbons to heavier hydrocarbons.

    摘要翻译： 公开了通过在酸性沸石催化剂上转化含有氧化烃的烯烃原料来使烯属费 - 托液体低聚以产生较重烃的装置。 改进包括用于从原料中除去含氧化合物的提取单元; 用于在低压和中等压力的低苛刻度条件下将提取的原料转化为初级馏分模式催化反应器系统的装置; 用于从初级阶段回收含氧化合物和轻质烃的装置和用于在高苛刻度条件下以比初级阶段高得多的温度转化含氧化合物的二级反应器系统，从而将含氧化合物和轻质烃转化成较重的烃。