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76 条记录 (耗时 0.029 秒)

    Oligomerizing alpha-olefins with a heterogeneous catalyst
    52.
    发明授权
    Oligomerizing alpha-olefins with a heterogeneous catalyst 失效
    用非均相催化剂低聚α-烯烃

    公开(公告)号：US4308414A

    公开(公告)日：1981-12-29

    申请号：US104415

    申请日：1979-12-17

    申请人： Ajay M. Madgavkar ,  Harold E. Swift

    发明人： Ajay M. Madgavkar ,  Harold E. Swift

    IPC分类号： C07C2/20 ,  C07C2/02

    CPC分类号： C07C2/20 ,  C07C2527/1213

    摘要： An alpha-olefin is oligomerized in the presence of a three-component catalyst comprising a particulate solid adsorbent having boron trifluoride and water adsorbed on the solid adsorbent. For example, 1-decene is oligomerized to a product predominating in the trimer and tetramer using silica as the solid adsorbent.

    摘要翻译： 在三组分催化剂存在下，将α-烯烃低聚，该三组分催化剂包含具有三氟化硼的颗粒固体吸附剂和吸附在固体吸附剂上的水。 例如，使用二氧化硅作为固体吸附剂，1-癸烯低聚成三聚体和四聚体中主要的产物。

    In situ combustion process for the recovery of liquid carbonaceous fuels from subterranean formations
    53.
    发明授权
    In situ combustion process for the recovery of liquid carbonaceous fuels from subterranean formations 失效
    用于从地下地层回收液态碳质燃料的原位燃烧过程

    公开(公告)号：US4273188A

    公开(公告)日：1981-06-16

    申请号：US145368

    申请日：1980-04-30

    申请人： Roger F. Vogel ,  Ajay M. Madgavkar ,  Harold E. Swift

    发明人： Roger F. Vogel ,  Ajay M. Madgavkar ,  Harold E. Swift

    IPC分类号： E21B43/243 ,  E21B43/34 ,  E21B43/24

    CPC分类号： E21B43/34 ,  E21B43/243

    摘要： An integrated in situ combustion process for recovering subterranean liquid and solid carbonaceous deposits in which the resulting flue gas of low heating value is combusted at substoichiometric conditions over two different oxidation catalysts in two combustion zones in series and is expanded in a gas turbine which drives the air compressor for injecting the combustion air into the underground carbonaceous deposit. One of the oxidation catalysts comprising platinum and at least one metal cocatalyst selected from Groups IIA and VIIB, Group VIII up through atomic No. 45, the lanthanides, chromium, zinc, silver, tin and antimony is provided to reduce the carbon monoxide in the combusted flue gas.

    摘要翻译： 用于回收地下液体和固体碳质沉积物的综合原位燃烧方法，其中所得到的低热值烟道气在亚化学计量条件下在两个不同的氧化催化剂中在两个不同的氧化催化剂中串联燃烧，并在燃气轮机中膨胀， 用于将燃烧空气注入地下含碳沉积物的空气压缩机。 包括铂和至少一种选自IIB和VIIB族金属助催化剂的氧化催化剂之一，通过45号原子的第VIII族，镧系元素，铬，锌，银，锡和锑被提供以减少 燃烧烟气。

    Hydrotreating process and catalyst
    56.
    发明授权
    Hydrotreating process and catalyst 失效
    加氢处理工艺和催化剂

    公开(公告)号：US4138326A

    公开(公告)日：1979-02-06

    申请号：US827102

    申请日：1977-08-23

    申请人： Harold E. Swift ,  Roger F. Vogel

    发明人： Harold E. Swift ,  Roger F. Vogel

    IPC分类号： B01J23/888 ,  B01J37/04 ,  C10G47/20 ,  C10G23/00 ,  B01J23/16 ,  B01J29/06 ,  C10G17/00

    CPC分类号： C10G47/20 ,  B01J23/888 ,  B01J37/04

    摘要： A catalyst comprising (1) a subgroup of a certain class of nickel and/or cobalt-substituted semicrystalline aluminosilicates which are synthetic and which are predominantly ordered in two directions (laminar clay-like materials); (2) tungsten in the form of its oxide and/or sulfide; and (3) a crystalline zeolite which has an alpha value of at least 20, which is in particulate form, and which is dispersed through the layered aluminosilicate; and processes using this catalyst.

    摘要翻译： 一种催化剂，其包括（1）合成的并且主要在两个方向上排列的某些类型的镍和/或钴取代的半结晶硅铝酸盐的亚组（层状粘土状材料）; （2）其氧化物和/或硫化物形式的钨; 和（3）α值至少为20的结晶沸石，其为颗粒形式，并通过层状铝硅酸盐分散; 并使用该催化剂进行处理。

    Process for conversion of gas oil to ethylene and needle coke
    57.
    发明授权
    Process for conversion of gas oil to ethylene and needle coke 失效
    瓦斯油转换成乙烯和针状焦的方法

    公开(公告)号：US4138325A

    公开(公告)日：1979-02-06

    申请号：US863403

    申请日：1977-12-22

    申请人： Harold Beuther ,  Joel D. McKinney ,  Harold E. Swift

    发明人： Harold Beuther ,  Joel D. McKinney ,  Harold E. Swift

    IPC分类号： C10G9/00 ,  C10G51/00 ,  C10G65/16 ,  C10G69/06 ,  C10G37/06 ,  C07C3/30

    CPC分类号： C10G65/16 ,  C10G2400/20

    摘要： A process for the conversion of gas oil to a naphtha pyrolysis feedstock and needle coke comprising thermally cracking the gas oil to produce a product comprising cracked naphtha and aromatic tar oil, delay coking said aromatic tar oil to produce needle coke and coker naphtha, and hydrotreating said cracked naphtha and said coker naphtha at a temperature at least 50.degree. F. (28.degree. C.) lower than the temperature in the thermal cracking and coking zones to avoid hydrocarcking reactions and to produce a hydrogenated naphtha containing at least 10 volume percent of cycloparaffins. Said hydrogenated naphtha is thereupon passed through a pyrolysis zone without added molecular hydrogen and without a catalyst operated at a temperature between 1,300 and 2,300.degree. F. (704 and 1,260.degree. C.) and a residence between 0.05 and 2 seconds to produce a product containing ethylene. The ethylene yield can be increased by adding a sulfur compound to the hydrogenated naphtha stream flowing to the pyrolysis zone.

    摘要翻译： 一种将瓦斯油转化为石脑油热解原料和针状焦的方法，其包括热裂解瓦斯油以产生包含裂化石脑油和芳烃焦油的产物，延迟焦化所述芳烃焦油以产生针状焦炭和焦化石脑油，加氢处理 所述裂化石脑油和所述焦化石脑油在比热裂解和焦化区中的温度低至少50°F（28℃）的温度下避免氢化反应并产生含有至少10体积％的氢化石脑油 环烷烃 所述氢化石脑油随后通过热分解区而不加入分子氢，并且在温度为1300至2300°F（704和1,260℃）之间操作的催化剂和在0.05至2秒之间的惰性气体中生产含有 乙烯。 可以通过向流入热解区的氢化石脑油流中加入硫化合物来提高乙烯收率。

    Hydrocarbon synthesis using a rare earth promoted metal silicate
    58.
    发明授权
    Hydrocarbon synthesis using a rare earth promoted metal silicate 失效
    使用稀土促进金属硅酸盐的合成

    公开(公告)号：US4116995A

    公开(公告)日：1978-09-26

    申请号：US745630

    申请日：1976-11-29

    申请人： Thaddeus P. Kobylinski ,  Harold E. Swift

    发明人： Thaddeus P. Kobylinski ,  Harold E. Swift

    IPC分类号： B01J29/04 ,  C07C1/04 ,  C07C1/12 ,  C07C27/06

    CPC分类号： B01J29/049 ,  C07C1/0435 ,  C07C1/12 ,  C07C2521/16 ,  C07C2523/10 ,  C07C2523/755

    摘要： The conversion of carbon monoxide and hydrogen to produce a mixture of low molecular weight hydrocarbons which, on a methane-free basis, contain a predominance of C.sub.2 -C.sub.6 paraffins is achieved using as the catalyst a rare earth metal promoted layered complex metal silicate composition characterized as having repeating units of the structural formula[(1-x)Ni.sup.a + xRu.sup.6 ].sub.n (OH).sub.4 Si.sub.2 O.sub.5.wH.sub.2 Owhere x is a number from 0 to 1, this number expressing the atomic fraction of the metals nickel and ruthenium; a is the valence of nickel; b is the valence of ruthenium; n is a number equal in value to that defined by the ratio6/[a(1-x) + bx]and w is a number ranging from 0 to 4. A rare earth promoted nickel chrysotile is the preferred catalyst.

    Recovery of aluminum from ethylene telomer product
    60.
    发明授权
    Recovery of aluminum from ethylene telomer product 失效
    从乙烯调聚物产品回收铝

    公开(公告)号：US4022839A

    公开(公告)日：1977-05-10

    申请号：US699899

    申请日：1976-06-25

    申请人： Harold Beuther ,  William L. Kehl ,  Harold E. Swift

    发明人： Harold Beuther ,  William L. Kehl ,  Harold E. Swift

    IPC分类号： C01F7/36 ,  C07C2/88 ,  C07C7/10 ,  C07C11/02

    CPC分类号： C07C2/88 ,  C01F7/36 ,  C07C7/10 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16

    摘要： When ethylene is telomerized to produce alpha-olefins in the presence of an organo-aluminum catalyst, the aluminum catalyst is present in the normally liquid alpha-olefin product and must be removed prior to distillation of that product. This removal is accomplished in two zones. Water is added to the alpha-olefin product containing the organo-aluminum catalyst in a first zone to produce an aqueous phase containing a suspension of aluminum hydroxide and an organic phase containing the alpha-olefins. After removal of the organic phase, a sufficient amount of an aqueous solution of a polyacrylamide in anionic form is added to the aqueous phase to result in at least 90 percent of the aluminum hydroxide settling in a time period of less than ten minutes at ambient conditions.

    摘要翻译： 当乙烯在有机铝催化剂存在下调聚生成α-烯烃时，铝催化剂存在于通常液态的α-烯烃产物中，在蒸馏该产物之前必须除去。 这种删除在两个区域中完成。 在第一区域中将水加入到含有有机铝催化剂的α-烯烃产物中以产生含有氢氧化铝和含有α-烯烃的有机相的悬浮液的水相。 除去有机相后，向水相中加入足够量的阴离子型聚丙烯酰胺水溶液，使至少90％的氢氧化铝在环境条件下在少于10分钟的时间内沉降 。