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91 条记录 (耗时 0.034 秒)

    Blends of modified radial polymers and engineering thermoplastic polymers
    51.
    发明授权
    Blends of modified radial polymers and engineering thermoplastic polymers 失效
    改性径向聚合物和工程热塑性聚合物的共混物

    公开(公告)号：US5218044A

    公开(公告)日：1993-06-08

    申请号：US505373

    申请日：1990-04-06

    申请人： Richard Gelles ,  Carl L. Willis ,  John E. Gorman ,  Andres M. Arismendi, Jr.

    发明人： Richard Gelles ,  Carl L. Willis ,  John E. Gorman ,  Andres M. Arismendi, Jr.

    IPC分类号： C08L53/00 ,  C08L67/02 ,  C08L71/12 ,  C08L77/00

    CPC分类号： C08L53/005 ,  C08L67/02 ,  C08L71/123 ,  C08L77/00

    摘要： A super-tough polymeric composition comprising an engineering thermoplastic and a modified radial polymer. The engineering thermoplastic is selected from the group consisting of polyamides, thermoplastic polyesters, polyphenylene ether resins, polyarylene sulfide resins, polysulfone and the like. The modified radial polymer is modified by grafting a compound containing a carboxylic acid or carboxylic acid derivative group. The modified, radial polymer has from about 3 to about 50 arms, as determined using light scattering techniques and the arms will be olefin polymers. The polymer compositions will yield shaped articles which fail ductilely when tested using ASTM procedure D-256 at room temperature and some at -20.degree. F.

    摘要翻译： 包含工程热塑性塑料和改性径向聚合物的超韧性聚合物组合物。 工程热塑性塑料选自聚酰胺，热塑性聚酯，聚苯醚树脂，聚芳硫醚树脂，聚砜等。 通过接枝含有羧酸或羧酸衍生物基团的化合物改性改性的径向聚合物。 修饰的径向聚合物具有约3至约50个臂，如使用光散射技术测定的，臂将为烯烃聚合物。 聚合物组合物将产生成形制品，当在室温下使用ASTM程序D-256进行测试并且在-20°F下测试时，会使其延性失效。

    Functionalized polymers and process for modifying unsaturated polymers
    53.
    发明授权
    Functionalized polymers and process for modifying unsaturated polymers 失效
    官能化聚合物和改性不饱和聚合物的方法

    公开(公告)号：US4970265A

    公开(公告)日：1990-11-13

    申请号：US329059

    申请日：1989-03-27

    申请人： Carl L. Willis

    发明人： Carl L. Willis

    IPC分类号： C08F8/00 ,  C08F8/04

    CPC分类号： C08F8/00 ,  C08F8/04

    摘要： Unsaturated hydrocarbon polymers are hydrogenated in the presence of a catalyst obtained by combining a Group VIII-A metal alkoxide or carboxylate and an alkyl or hydride of a metal selected from Groups I-A, II-A and III-B and then functionalized by contacting the hydrogenated polymer with a functionalizing agent before the hydrogenation catalyst is quenched or otherwise deactivated. The hydrogenation is, generally, accomplished at relatively mild conditions to avoid degradation of the polymer and, in the case of unsaturated copolymers comprising aromatic unsaturation, to avoid any significant hydrogenation of the aromatic unsaturation. Generally, the hydrogen partial pressure employed will be below about 1000 psig and the hydrogenation temperature will be below about 125.degree. C. The hydrogenated polymer may be functionalized by reaction with functionalizing agent select from the group carbon dioxide, ethylene oxide, aldehydes, ketones, carboxylic acid salts and esters, halides, epoxides, sulfur, boron alkoxides, isocyanates, various silicon compounds and the like. Carbon dioxide is a particularly preferred functionalizing agent since the thus functionalized polymer is useful as a modifier in sheet and bulk molding compositions and readily responds to the presence of thickening agents.

    摘要翻译： 不饱和烃聚合物在通过将VIII-A族金属醇盐或羧酸盐与选自IA，II-A和III-B族的金属的烷基或氢化物组合而获得的催化剂存在下氢化，然后通过使氢化 在氢化催化剂淬灭或以其它方式失活之前，使用官能化剂的聚合物。 通常在相对温和的条件下进行氢化以避免聚合物的降解，并且在包含芳族不饱和键的不饱和共聚物的情况下，以避免芳族不饱和度的任何明显氢化。 一般来说，所用的氢气分压将低于约1000psig，氢化温度将低于约125℃。氢化聚合物可以通过与选自二氧化碳，环氧乙烷，醛，酮， 羧酸盐和酯，卤化物，环氧化物，硫，硼醇盐，异氰酸酯，各种硅化合物等。 二氧化碳是特别优选的官能化剂，因为如此官能化的聚合物可用作片材和本体模塑组合物中的改性剂，并且容易响应增稠剂的存在。

    Butene-1/4-vinylcyclohexene copolymer
    56.
    发明授权
    Butene-1/4-vinylcyclohexene copolymer 失效
    丁烯-1 / 4-乙烯基环己烯共聚物

    公开(公告)号：US4405772A

    公开(公告)日：1983-09-20

    申请号：US391202

    申请日：1982-06-23

    申请人： Pui K. Wong ,  Carl L. Willis ,  Thomas F. Brownscombe

    发明人： Pui K. Wong ,  Carl L. Willis ,  Thomas F. Brownscombe

    IPC分类号： C08F210/08 ,  C08F236/20

    CPC分类号： C08F236/20 ,  C08F210/08

    摘要： Solid copolymers of butene-1 and 4-vinylcyclohexene prepared by copolymerizing the monomers in the presence of a titanium halide coordination catalyst have an unobvious balance of properties including a broader molecular weight distribution, shorter crystallization half-time, greater isotacticity and greater crystallinity than butene-1 homopolymers prepared with identical catalysts.

    摘要翻译： 通过在卤化钛配位催化剂存在下共聚单体制备的丁烯-1和4-乙烯基环己烯的固体共聚物具有非常显着的性能平衡，包括比丁烯更宽的分子量分布，更短的结晶半衰期，更大的全同立构规整度和更大的结晶度 -1均聚物用相同的催化剂制备。

    MODIFIED SULFONATED BLOCK COPOLYMERS AND THE PREPARATION THEREOF
    58.
    发明申请
    MODIFIED SULFONATED BLOCK COPOLYMERS AND THE PREPARATION THEREOF 有权
    改性磺化嵌段共聚物及其制备方法

    公开(公告)号：US20130015071A1

    公开(公告)日：2013-01-17

    申请号：US13181306

    申请日：2011-07-12

    申请人： Carl L. Willis

    发明人： Carl L. Willis

    IPC分类号： B01D61/46 ,  B32B5/02 ,  C08F236/10

    CPC分类号： B01D71/80 ,  B01D61/445 ,  B01D61/48 ,  B01D71/28 ,  B01D71/68 ,  C02F1/441 ,  C02F1/445 ,  C02F1/4693 ,  C02F1/4695 ,  C08F8/36 ,  H01M8/1023 ,  H01M8/103 ,  Y10T442/20 ,  Y10T442/2762 ,  C08F297/02

    摘要： Described herein are modified sulfonated block copolymers which comprise at least two polymer end blocks A and at least one polymer interior block B, wherein each A block contains essentially no sulfonic acid or sulfonate functional groups and each B block comprises sulfonation susceptible monomer units and, based on the number of the sulfonation susceptible monomer units, from about 10 to about 100 mol % of a functional group of formula (I) —SO2—NR1R2  (I) or of a salt thereof, methods of making them as well as methods of using them, e.g., as membrane materials for electrically or osmotically driven applications.

    摘要翻译： 本文描述的是改性的磺化嵌段共聚物，其包含至少两个聚合物端嵌段A和至少一个聚合物内部嵌段B，其中每个A嵌段基本上不含磺酸或磺酸盐官能团，并且每个B嵌段包含磺化敏感的单体单元和基于 对于磺化易感单体单元的数量，约10至约100摩尔％的式（I）-SO 2 -NR 1 R 2（I）的官能团或其盐，制备它们的方法以及使用方法 它们例如用作用于电驱动或渗透驱动应用的膜材料。