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    Isocyanato-acylurethanes, a process for their preparation and their use
    53.
    发明授权
    Isocyanato-acylurethanes, a process for their preparation and their use 失效
    异氰酸酯 - 氨基甲酸酯，其制备方法及其用途

    公开(公告)号：US4921996A

    公开(公告)日：1990-05-01

    申请号：US227980

    申请日：1988-08-02

    申请人： Walter Schafer ,  Hanns P. Muller ,  Tillmann Hassel

    发明人： Walter Schafer ,  Hanns P. Muller ,  Tillmann Hassel

    IPC分类号： C07C275/60 ,  C07C67/00 ,  C07C239/00 ,  C08F20/36 ,  C08G18/70 ,  C08G18/71 ,  C08G18/78

    CPC分类号： C08G18/714 ,  C08F20/36 ,  C08G18/701 ,  C08G18/7806

    摘要： The present invention relates to isocyanto-acylurethanes corresponding to Formula I ##STR1## wherein R has a valency of m+n and is a hydrocarbon group,R' is a hydrocarbon group andm and n may be identical or different, and each have a value of 1 or 2.The present invention also relates to a process for preparation of these isocyanato-acylurethanes which comprises reacting isocyanato-carboxylic acid chlorides with carbamic acid esters. Finally, the present invention is directed to the use of these isocyanato-acylurethanes as intermediate products for the production of thermally cross-linkable synthetic resins or synthetic resin precursors and also as intermediate products for the preparation of cross-linking agents for synthetic resins.

    摘要翻译： 本发明涉及对应于式I的异氰酸基 - 酰基氨基甲酸酯（I）其中R具有m + n的化合价并且是烃基，R'是烃基，m和n可以相同或不同，以及 各自具有1或2的值。本发明还涉及这些异氰酸酯基 - 氨基甲酸酯的制备方法，其包括使异氰酸根合羧酸氯化物与氨基甲酸酯反应。 最后，本发明涉及这些异氰酸酯基 - 氨基甲酸酯作为生产可热交联的合成树脂或合成树脂前体的中间产物以及用作制备用于合成树脂的交联剂的中间产品的用途。

    Ester-urethane derivatives of (meth)-acrylic acid for dental materials
    54.
    发明授权
    Ester-urethane derivatives of (meth)-acrylic acid for dental materials 失效
    用于牙科材料的（甲基）丙烯酸的酯 - 氨基甲酸酯衍生物

    公开(公告)号：US4904750A

    公开(公告)日：1990-02-27

    申请号：US287424

    申请日：1988-12-20

    申请人： Jurgen Reiners ,  Carlhans Suling ,  Walter Schafer ,  Hanns P. Muller ,  Wolfgang Podszun ,  Jens Winkel

    发明人： Jurgen Reiners ,  Carlhans Suling ,  Walter Schafer ,  Hanns P. Muller ,  Wolfgang Podszun ,  Jens Winkel

    IPC分类号： A61K6/083 ,  A61K6/09 ,  C07C271/22 ,  C08F20/34 ,  C08F220/36 ,  C08F290/00 ,  C08F299/00 ,  C08G18/67 ,  C08G18/72

    CPC分类号： A61K6/0017 ,  A61K6/09 ,  C07C271/22 ,  C08G18/672 ,  C08G18/72

    摘要： Dental fillings, coatings and teeth are formed of polymers and copolymers of a polyfunctional ester-urethane derivative of (meth)-acrylic acid of the formula ##STR1## in which A is a straight-chain or branched aliphatic radical which has 2 to 20 carbon atoms and optionally contains 1 to 3 oxygen bridges, an aromatic radical with 6 to 24 carbon atoms, an araliphatic radical with 7 to 26 carbon atoms or a cycloaliphatic radical with 6 to 26 carbon atoms,r denotes the number of chains starting from A and denotes a number from 2 to 6,R.sup.1 and R.sup.2 are identical and denote hydrogen or are different and denote hydrogen and methyl,n denotes a number from 0 to 5 independently for each chain starting from A,X stands for the group ##STR2## in which Y denotes a divalent (cyclo)aliphatic radical which has 2 to 15 carbon atoms and optionally contains ester, ether or urethane groups,Z denotes a divalent straight-chain or branched aliphatic hydrocarbon radical which has 3 to 15 carbon atoms and can optionally contain 1 to 3 oxygen bridges and can optionally be substituted by 1 to 4 additional (meth)-acrylate radicals andR.sup.3 denotes hydrogen or methyl independently for each chain starting from A.

    摘要翻译： 牙科填充物，涂料和牙齿由式（IMA）（I）的（甲基）丙烯酸的多官能酯 - 氨基甲酸酯衍生物的聚合物和共聚物形成，其中A是直链或支链脂族基团，其具有2 至20个碳原子，并且任选地含有1至3个氧桥，具有6至24个碳原子的芳族基团，具有7至26个碳原子的芳脂族基团或具有6至26个碳原子的脂环族基团，r表示链起始数 从A表示2至6的数，R1和R2相同并且表示氢或不同，表示氢和甲基，n表示从A开始独立地为0至5的数，X表示< IMAGE>其中Y表示具有2至15个碳原子并且任选地含有酯，醚或氨基甲酸酯基团的二价（环）脂族基团，Z表示具有3至15个碳原子的二价直链或支链脂族烃基， ca n任选地含有1至3个氧桥，并且可以任选地被1至4个另外的（甲基）丙烯酸酯基团取代，并且对于从A开始的每个链，R 3表示氢或甲基。

    Isocyanurate group-containing polyisocyanates
    55.
    发明授权
    Isocyanurate group-containing polyisocyanates 失效
    含异氰脲酸酯基的多异氰酸酯

    公开(公告)号：US4851531A

    公开(公告)日：1989-07-25

    申请号：US74380

    申请日：1987-07-16

    申请人： Reinhard Halpaap ,  Gerhard Klein ,  Roland Richter ,  Hanns P. Muller ,  Josef Pedain ,  Hans-Joachim Kreuder

    发明人： Reinhard Halpaap ,  Gerhard Klein ,  Roland Richter ,  Hanns P. Muller ,  Josef Pedain ,  Hans-Joachim Kreuder

    IPC分类号： C08G18/00 ,  C07D251/34 ,  C08G18/02 ,  C08G18/79 ,  C09D5/46 ,  C09D175/00 ,  C09D175/12

    CPC分类号： C08G18/792 ,  C07D251/34 ,  C08G2150/20

    摘要： The present invention is directed to isocyanato isocyanurates prepared from diisocyanates which contain a sterically unhindered isocyanate group bound to a primary aliphatic carbon atom and a sterically hindered isocyanate group which is bound to a tertiary carbon atom forming part of a cycloaliphatic ring system, said diisocyanate having an NCO content of about 20 to 50% by weight. The present invention is further directed to a process for preparing these isocyanato isocyanurates by catalytic trimerization and the use of the isocyanato isocyanurates in a process for the production of polyisocyanate polyaddition products, preferably two-component polyurethane stoving lacquers.

    摘要翻译： 本发明涉及由二异氰酸酯制备的异氰酸根合异氰脲酸酯，该二异氰酸酯包含与主要脂族碳原子结合的空间上不受阻碍的异氰酸酯基团和与形成脂环族环系的一部分的叔碳原子结合的空间位阻异氰酸酯基团，所述二异氰酸酯具有 约20至50重量％的NCO含量。 本发明还涉及一种通过催化三聚制备这些异氰酸酯异氰脲酸酯的方法，以及在制备多异氰酸酯加聚产物的方法中使用异氰酸酯基异氰脲酸酯的方法，优选为双组分聚氨酯烘烤漆。

    Alkoxylated aminopolyethers, a process for their preparation
    57.
    发明授权
    Alkoxylated aminopolyethers, a process for their preparation 失效
    烷氧基化氨基聚醚，其制备方法

    公开(公告)号：US4739094A

    公开(公告)日：1988-04-19

    申请号：US807388

    申请日：1985-12-10

    申请人： Jan Mazanek ,  Hanns P. Muller ,  Roland Nast ,  Wolfgang Oberkirch ,  Franz-Moritz Richter ,  Walter Schafer

    发明人： Jan Mazanek ,  Hanns P. Muller ,  Roland Nast ,  Wolfgang Oberkirch ,  Franz-Moritz Richter ,  Walter Schafer

    IPC分类号： F23K1/02 ,  C08G65/26 ,  C08G65/32 ,  C10L1/32

    CPC分类号： C10L1/326 ,  C08G65/2624

    摘要： New alkoxylated aminopolyethers of the formula ##STR1## in which Q denotes a polyalkylene oxide radical which has a valency corresponding to n, which has a structure derived from an aminopolyether by removal of the terminal amino groups and which has an average molecular weight of 82 to 30,000,A.sub.1 and A.sub.2 denote identical or different mono- or polyalkylene oxide radicals of the type (RO).sub.y,whereineach radical R represents an alkylene radical with 2 to 40 C atoms andy represents an integer from 1 to 200,B.sub.1 and B.sub.2 denote identical or different mono- or polyalkylene oxide radicals of the type (R'O).sub.z,whereinat least 50% of the R' radicals represent a --CH.sub.2 --CH.sub.2 -- group,the other R' radicals which may be present each represent an alkylene radical with 3 to 40 C atoms andz represents an integer from 1 to 300,Z denotes hydrogen, ##STR2## wherein M.sup..sym. represents one equivalent of a metal ion or represents NH.sub.4.sup..sym. andn denotes an integer from 1 to 30,a process for their preparation and coal/water slurries containing them.

    摘要翻译： 其中Q表示具有对应于n的化合价的聚亚烷基氧基的新的烷氧基化氨基聚醚，其具有通过除去末端氨基而衍生自氨基聚醚的结构，其平均分子量为82〜 30,000，A1和A2表示类型（RO）y相同或不同的单 - 或聚环氧烷基，其中每个基团R表示具有2至40个C原子的亚烷基，y表示1至200的整数，B1和B2 表示类型（R'O）z的相同或不同的单 - 或聚环氧烷基团，其中至少50％的R'基团表示-CH 2 -CH 2 - 基团，可以存在的另一个R'基团表示 具有3至40个C原子的亚烷基，z表示1至300的整数，Z表示氢，其中M（+）表示1当量的金属离子或表示NH 4（+），n表示 1〜30，其制备方法和煤/ 含水的泥浆含有它们。

    Polyisocyanate preparations and their use for the production of polyurethane plastics
    58.
    发明授权
    Polyisocyanate preparations and their use for the production of polyurethane plastics 失效
    聚异氰酸酯制剂及其用于生产聚氨酯塑料的用途

    公开(公告)号：US4719244A

    公开(公告)日：1988-01-12

    申请号：US25902

    申请日：1987-03-13

    申请人： Hanns P. Muller ,  Bernhard Jansen ,  Rudolf Hombach

    发明人： Hanns P. Muller ,  Bernhard Jansen ,  Rudolf Hombach

    IPC分类号： C08G18/10 ,  C08G18/18 ,  C09J175/04 ,  C08G18/14

    CPC分类号： C09J175/04 ,  C08G18/10 ,  C08G18/1833

    摘要： The present invention is directed to polyisocyanate compositions containing(a) at least one organic polyisocyanate and(b) at least one dissolved catalyst corresponding to the general formula ##STR1## wherein R.sup.1 and R.sup.2 may be identical or different and denote hydrogen or a methyl group, provided that R.sup.1 and R.sup.2 do not both stand for a methyl group,R.sup.3, R.sup.4 and R.sup.5 denote identical or different organic groups which are inert in isocyanate addition reactions andk, m and n represent identical or different integers with values from 1 to 5.The present invention also relates to the use of the polyisocyanate compositions as the polyisocyanate component for the production of polyisocyanate polyaddition products, especially moisture cure coating compositions or adhesives.

    摘要翻译： 本发明涉及含有（a）至少一种有机多异氰酸酯和（b）至少一种对应于通式“IMAGE”的溶解催化剂的多异氰酸酯组合物，其中R 1和R 2可以相同或不同，表示氢或甲基 条件是R1和R2不都代表甲基，R3，R4和R5表示在异氰酸酯加成反应中为惰性的相同或不同的有机基团，并且k，m和n表示相同或不同的整数，其值为1至5 本发明还涉及多异氰酸酯组合物作为多异氰酸酯组分用于生产多异氰酸酯加聚产物，特别是湿固化涂料组合物或粘合剂的用途。

    Homogeneous storage stable cyanamide solutions in polyols and a process for their production
    60.
    发明授权
    Homogeneous storage stable cyanamide solutions in polyols and a process for their production 失效
    在多元醇中均匀储存稳定的氰胺溶液及其生产工艺

    公开(公告)号：US4562289A

    公开(公告)日：1985-12-31

    申请号：US714731

    申请日：1985-03-22

    申请人： Manfred Hajek ,  Hanns P. Muller ,  Werner Rasshofer

    发明人： Manfred Hajek ,  Hanns P. Muller ,  Werner Rasshofer

    IPC分类号： C08G18/38 ,  C08G18/66 ,  C08K5/315 ,  C07C125/00

    CPC分类号： C08G18/6607 ,  C08G18/3838 ,  C08K5/315 ,  C08G2130/00

    摘要： Homogeneous storage stable solutions of cyanamide in a polyol are made by dehydrating a mixture of an aqueous cyanamide solution and at least one polyol under mild conditions. The aqueous cyanamide solution contains from 10 to 55 wt % cyanamide. The polyol may have a molecular weight of from 62 to 12,000. Polyether and/or polyester polyols having molecular weights from 400 to 12,000 are preferred. Mixtures of high and low molecular weight polyols which are not completely miscible with each other are also preferred. The dehydration is generally carried out at pressures less than 100 mbar and temperatures less than 130.degree. C. The product solution has a cyanamide content of from 0.1 to 50 wt % and a residual water content which is generally no greater than 1 wt %. These homogeneous and storage stable cyanamide in polyol solutions are particularly useful in the production of polyurethanes.

    摘要翻译： 通过在温和条件下将氨基氰水溶液和至少一种多元醇的混合物脱水制备多元醇中氨基氰的均相储存稳定溶液。 氰氨水溶液含有10至55重量％的氰胺。 多元醇的分子量可以为62〜12000。 优选分子量为400至12,000的聚醚和/或聚酯多元醇。 高分子量和低分子量多元醇的混合物彼此不完全混溶也是优选的。 脱水通常在低于100毫巴的压力和低于130℃的温度下进行。产物溶液的氨酰胺含量为0.1至50重量％，残留水含量通常不大于1重量％。 多元醇溶液中这些均相和储存稳定的氰胺在聚氨酯的生产中特别有用。