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64 条记录 (耗时 0.027 秒)

    Method of producing nitrile compounds from ethylenically-unsaturated compounds
    52.
    发明授权
    Method of producing nitrile compounds from ethylenically-unsaturated compounds 有权
    由烯属不饱和化合物制备腈化合物的方法

    公开(公告)号：US07485741B2

    公开(公告)日：2009-02-03

    申请号：US10537260

    申请日：2003-11-25

    申请人： Damien Bourgeois ,  Jean-Christophe Galland ,  Blaise Didillon ,  Philippe Marion

    发明人： Damien Bourgeois ,  Jean-Christophe Galland ,  Blaise Didillon ,  Philippe Marion

    IPC分类号： C07C253/00

    CPC分类号： C07C253/10 ,  C07C255/04

    摘要： The present invention relates to a process for hydrocyanating a hydrocarbon-based compound containing at least one ethylenic unsaturation by reaction in liquid medium with hydrogen cyanide in the presence of a catalyst comprising a metal element chosen from transition metals and an organophosphorus ligand, characterized in that the organophosphorus ligand is a monodentate organophosphorus compound. The present invention is in particular useful for the synthesis of adiponitrile from butadiene.

    摘要翻译： 本发明涉及一种在含有选自过渡金属和有机磷配体的金属元素的催化剂存在下，在液体介质中与氰化氢反应，使含有至少一个烯属不饱和基团的烃类化合物氢氰化的方法，其特征在于： 有机磷配体是单齿有机磷化合物。 本发明特别适用于从丁二烯合成己二腈。

    Process for capturing mercury and arsenic comprising evaporation then condensation of a hydrocarbon-containing cut
    56.
    发明授权
    Process for capturing mercury and arsenic comprising evaporation then condensation of a hydrocarbon-containing cut 有权
    用于捕获汞和砷的方法，包括蒸发，然后使含烃切割物冷凝

    公开(公告)号：US06793805B2

    公开(公告)日：2004-09-21

    申请号：US09893602

    申请日：2001-06-29

    申请人： Blaise Didillon ,  Carine Petit-Clair ,  Laurent Savary

    发明人： Blaise Didillon ,  Carine Petit-Clair ,  Laurent Savary

    IPC分类号： C10G6700

    CPC分类号： C10G67/06 ,  C10G65/04

    摘要： A process for capturing mercury and possibly arsenic comprising at least: a) vaporising (or flashing, step a1) then condensing a hydrocarbon-containing feed (step a2) without separating said feed; b) treating the effluent from step a2 comprising at least one step for bringing said effluent into contact with hydrogen and a catalyst, and optionally capturing arsenic; c) a step consisting in passing the effluent from step b) over a mercury capture mass.

    摘要翻译： 一种用于捕获汞和可能的砷的方法，至少包括：a）蒸发（或闪蒸，步骤a1）然后冷凝含烃进料（步骤a2），而不分离所述进料; b）处理来自步骤a2的流出物，其包含至少一种 使所述流出物与氢气和催化剂接触并且任选地捕获砷的步骤; c）使来自步骤b）的流出物通过汞捕获物质的步骤。

    Process for eliminating arsenic in the presence of an absorption mass comprising partially pre-sulfurized lead oxide
    58.
    发明授权
    Process for eliminating arsenic in the presence of an absorption mass comprising partially pre-sulfurized lead oxide 失效
    在含有部分预硫化氧化铅的吸收物质存在下消除砷的方法

    公开(公告)号：US06623629B2

    公开(公告)日：2003-09-23

    申请号：US09800511

    申请日：2001-03-08

    申请人： Blaise Didillon ,  Laurent Savary

    发明人： Blaise Didillon ,  Laurent Savary

    IPC分类号： C10G2500

    CPC分类号： C10L3/12 ,  C10G25/003

    摘要： The invention concerns a process for eliminating arsenic from a hydrocarbon cut in which said cut is brought into contact with an absorption mass that is at least partially pre-sulfurized and comprises a support and lead oxide. The support, for example alumina, or said mass preferably has a specific surface area in the range 10 to 300 m2/g, a total pore volume in the range 0.2 to 1.2 cm3/g and a macroporous volume in the range 0.1 to 0.5 cm3/g. The lead content of said mass, expressed as lead oxide, is preferably in the range of 5% to 50% by weight. The fraction of the sulfurized mass preferably represents at least {fraction (1/20)}th of the total volume of the absorption mass.

    摘要翻译： 本发明涉及一种从烃馏分中消除砷的方法，其中所述切割与至少部分预硫化并包含载体和氧化铅的吸收物质接触。 载体例如氧化铝或所述物质优选具有10-300m 2 / g的比表面积，在0.2-1.2cm 3 / g范围内的总孔体积， 范围为0.1至0.5cm 3 / g。 表示为氧化铅的所述物质的铅含量优选在5重量％至50重量％的范围内。 硫化质量的分数优选至少代表（分数）（吸收质量的总体积的1/20）。

    Process for the preparation of an aliphatic alkylate with a high octane number from a C4 cracking fraction
    59.
    发明授权
    Process for the preparation of an aliphatic alkylate with a high octane number from a C4 cracking fraction 有权
    从C4裂解馏分制备具有高辛烷值的脂族烷基化物的方法

    公开(公告)号：US06333442B1

    公开(公告)日：2001-12-25

    申请号：US09256185

    申请日：1999-02-24

    申请人： Jean Cosyns ,  Blaise Didillon ,  Lionel Quicke

    发明人： Jean Cosyns ,  Blaise Didillon ,  Lionel Quicke

    IPC分类号： C07C258

    CPC分类号： C10G70/00 ,  C07C5/13 ,  C07C7/04 ,  C07C9/12 ,  C07C9/21 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/755 ,  C07C2527/054 ,  C07C2527/1206 ,  C07C11/08

    摘要： An aliphatic alkylate with a high octane number is prepared from a C4 catalytic cracking or steam-cracking fraction that contains mainly isobutane, isobutene, butene-1 and butenes-2 by: (a) hydro-isomerizing said C4 fraction, obtaining a mixture that contains for the most part butenes-2, isobutene and isobutane; (b) separating, by distillation of the hydro-isomerized fraction, of a butene-2-rich effluent that is collected at the bottom and an isobutane- and isobutene-rich effluent that is collected at the top; (c) sending said isobutene- and isobutane-rich effluent into a hydrogenation zone that produces an effluent that for the most part contains isobutane; (d) sending of said butenes-2-rich effluent that is derived from (b) and of said effluent that for the most part contains the isobutane that is derived from (c) into an alkylation zone producing, by addition of isobutane to butenes-2, an isooctane mixture that contains excess isobutane; (e) separating by distillation of excess isobutane, which comes out at the top, and alkylate with an improved octane number, which comes out at the bottom; and (f) recycling of the excess isobutane that is recovered in (e) upstream from hydrogenation (c) of the top effluent from the distillation of (b).

    摘要翻译： 具有高辛烷值的脂肪族烷基化物由主要包含异丁烷，异丁烯，丁烯-1和丁烯-2的C4催化裂化或蒸汽裂解馏分制备，通过以下步骤：（a）将所述C4馏分加氢异构化，得到 含有大部分丁烯-2，异丁烯和异丁烷;（b）通过蒸馏加氢异构化馏分，分离富含2-丁烯的流出物，其在底部收集，富含异丁烷和异丁烯的流出物 其收集在顶部;（c）将所述异丁烯和异丁烷富集的流出物送入氢化区，其产生大部分含有异丁烷的流出物;（d）送出所衍生的所述富含2-丁烯的流出物 （b）和所述流出物，其大部分含有从（c）衍生的异丁烷进入烷基化区，通过向丁烯-2中加入异丁烷，产生含有过量异丁烷的异辛烷混合物;（e）分离 通过蒸馏过量的异丁烷 ，其出现在顶部，烷基化物具有改善的辛烷值，其出现在底部; 和（f）在（e）从（b）的蒸馏的顶部流出物的氢化（c）上游回收的过量异丁烷的再循环。

    Selective hydrogenation catalysts containing palladium, also tin and/or lead, and the preparation and use thereof
    60.
    发明授权
    Selective hydrogenation catalysts containing palladium, also tin and/or lead, and the preparation and use thereof 有权
    含钯，还有锡和/或铅的选择性氢化催化剂及其制备和应用

    公开(公告)号：US06239322B1

    公开(公告)日：2001-05-29

    申请号：US09397958

    申请日：1999-09-17

    申请人： Blaise Didillon ,  Charles Cameron ,  Christophe Gautreau

    发明人： Blaise Didillon ,  Charles Cameron ,  Christophe Gautreau

    IPC分类号： C07C505

    CPC分类号： B01J23/44 ,  B01J23/622

    摘要： A particulate selective hydrogenation catalyst for hydrogenating unsaturated diolefinic hydrocarbons to &agr;-olefinic hydrocarbons at rates which are at least 1.5 times higher than the rate of hydrogenation of &agr;-olefinic hydrocarbons to saturated compounds contains palladium distributed at the periphery of particles (spherules or extrudates), and at least one element selected from tin and lead. Further, the tin and/or lead is advantageously distributed at the periphery of the spherules or extrudates.

    摘要翻译： 用于将不饱和二烯烃氢化为α-烯烃的颗粒选择性氢化催化剂的速率至少比α-烯烃氢化成饱和化合物的速率高1.5倍，其中包含分布在颗粒周围的颗粒（颗粒或挤出物） 和至少一种选自锡和铅的元素。 此外，锡和/或铅有利地分布在球体或挤出物的周边。