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51.发明授权Silver halide emulsion prepared in the presence of polymers and a photographic material using the same 失效在聚合物存在下制备的卤化银乳剂和使用其的照相材料
公开(公告)号：US5595863A
公开(公告)日：1997-01-21
申请号：US537225
申请日：1995-09-29
申请人： Junichi Yamanouchi , Yoichi Hosoya
发明人： Junichi Yamanouchi , Yoichi Hosoya
CPC分类号： G03C1/0051
摘要： There are disclosed a hexagonal silver halide tabular emulsion having an excellent monodispersibility and a silver halide photographic material which contains the above tabular silver halide emulsion and excels in a graininess, a sensitivity and a preservability. The above silver halide photographic emulsion is prepared in the presence of at least one of the polymers having a recurring unit represented by the Formula (1) and at least one of the polymers having a recurring unit represented by Formula (2):--(R--O).sub.n -- (1)--(CH.sub.2 CH.sub.2 O).sub.m -- (2)wherein R represents an alkylene group having 3 to 10 carbon atoms; and n and m each represents an average number of the recurring unit, respectively and each represents 4 to 200.
摘要翻译： 公开了具有优异的单分散性的六甲基卤化银片状乳液和含有上述片状卤化银乳剂的卤化银照相材料，并且颗粒度，灵敏度和保存性都优异。 上述卤化银照相乳剂在至少一种具有由式（1）表示的重复单元的聚合物和至少一种具有由式（2）表示的重复单元的聚合物的存在下制备： - （RO ）n-（1） - （CH 2 CH 2 O）m - （2）其中R表示具有3至10个碳原子的亚烷基; n和m分别表示重复单元的平均数，分别表示4〜200。
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公开(公告)号：US5302501A
公开(公告)日：1994-04-12
申请号：US966383
申请日：1992-10-26
CPC分类号： G03C1/7614 , G03C1/0051 , G03C1/053 , Y10S430/164
摘要： A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein the swelling ratio of the entire hydrophilic colloid layers on the acid polymer-containing layer side of the support of the silver halide photographic material having a hydrophilic colloid layer containing at least one acid polymer (having a carboxyl group-containing monomer unit content of at least 15 mol % or an acid value of at least 1.5 meq/g) on at least one silver halide emulsion layer-coated side thereof is at least 200% in distilled water, said acid polymer being dissolved in water and added to said hydrophilic colloid layer, and the swollen thickness of the above entire hydrophilic colloid layers at the time of the completion of the rinsing stage is not more than 8 .mu.m when said silver halide photographic material is processed (the swelling ratio in distilled water is a value obtained by incubating the photographic material at 40.degree. C. and 60% RH (percent relative humidity) for 16 hours, immersing it in distilled water at 21.degree. C. for 3 minutes and measuring the change of the thickness thereof).
摘要翻译： 一种卤化银照相材料，包括其上具有至少一个卤化银乳剂层的载体，其中具有亲水胶体层的卤化银照相材料的载体的含酸性聚合物层层上的整个亲水胶体层的溶胀比 含有至少一种酸性聚合物（具有含羧基的单体单元含量为至少15mol％或酸值至少为1.5meq / g）在至少一个卤化银乳剂层涂覆侧上为至少200 在蒸馏水中，所述酸性聚合物溶于水中并加入到所述亲水胶体层中，并且在漂洗阶段完成时上述整个亲水胶体层的溶胀厚度不大于8（m） 当所述卤化银照相材料被处理时（蒸馏水中的溶胀比是通过将照相材料在40℃和60％RH下温育获得的值 （相对湿度百分比）16小时，将其浸入21℃的蒸馏水中3分钟并测量其厚度变化）。
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公开(公告)号：US5300416A
公开(公告)日：1994-04-05
申请号：US910394
申请日：1992-07-08
申请人： Junichi Yamanouchi , Satoru Toda , Nobuaki Ohmori , Yuichi Ohashi
发明人： Junichi Yamanouchi , Satoru Toda , Nobuaki Ohmori , Yuichi Ohashi
CPC分类号： G03C1/89
摘要： There is disclosed a silver halide photographic light-sensitive material which is improved in an antistatic property, curling before and after processing, and surface status after processing. The light-sensitive material includes a support having provided thereon at least one light-sensitive silver halide emulsion layer, wherein the material contains an anionic crosslinked polymer dispersion containing a polymer represented by Formula (I), and the material further contains an anionic water soluble polymer represented by Formula (II): ##STR1## wherein A represents a repetitive unit formed by copolymerizing a crosslinking monomer having at least two copolymerizable ethylenically unsaturated groups; B and E each represent a monomer unit formed by copolymerizing copolymerizable ethylenically unsaturated monomers; R.sup.1 represents a hydrogen atom, a substituted or unsubstituted lower alkyl group, or a halogen atom; L represents a di- to tetravalent linkage group; M represents a hydrogen atom or a cation; m represents 0 or 1; n represents 1, 2 or 3; D represents a monomer unit formed by copolymerizing at least one monomer selected from the group consisting of N,N-dimethylacrylamide, N-acryloylmorpholine and N-acryloylpiperidine; x, y, z, x', y', and z' each represent a percentage of a monomer component, provided that x is from 1 to 70, y is from 0 to 50, z is from 25 to 90, x' is from 1 to 99, y' is from 0 to 50, and z' is from 1 to 99, wherein x+y+z= 100 and x'+y'+z'= 100.
摘要翻译： 公开了一种改善了抗静电性能，加工前后的卷曲和加工后的表面状态的卤化银摄影感光材料。 感光材料包括在其上设置有至少一个感光卤化银乳剂层的载体，其中所述材料含有含有由式（I）表示的聚合物的阴离子交联聚合物分散体，并且所述材料还含有阴离子水溶性 式（II）表示的聚合物：（*化学结构*）式（I）（*化学结构*）式（II）其中A表示通过共聚具有至少两个可共聚的烯属不饱和基团的交联单体形成的重复单元; B和E各自表示通过使可共聚的烯属不饱和单体共聚形成的单体单元; R1表示氢原子，取代或未取代的低级烷基或卤素原子; L表示二价至四价连接基团; M表示氢原子或阳离子; m表示0或1; n表示1,2或3; D表示通过共聚合至少一种选自N，N-二甲基丙烯酰胺，N-丙烯酰基吗啉和N-丙烯酰基哌啶的单体形成的单体单元; x，y，z，x'，y'和z'各自表示单体组分的百分比，条件是x为1-70，y为0至50，z为25至90，x'为 1〜99，y'为0〜50，z'为1〜99，x + y + z = 100，x'+ y'+ z'= 100。
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公开(公告)号：US4874689A
公开(公告)日：1989-10-17
申请号：US52881
申请日：1987-05-22
申请人： Junichi Yamanouchi , Shigetoshi Ono , Tsumoru Hirano , Toshiyuki Watanabe , Nobuo Sakai , Keiji Mihayashi
发明人： Junichi Yamanouchi , Shigetoshi Ono , Tsumoru Hirano , Toshiyuki Watanabe , Nobuo Sakai , Keiji Mihayashi
CPC分类号： G03C7/3275
摘要： A silver halide color photographic material containing new dye image-forming couplers consisting of polymer couplers obtained by a polymerization reaction which employs a chain transfer agent having 8 or more carbon atoms. The silver halide color photographic material exhibits a high sensitivity and a high color-forming property.
摘要翻译： 一种卤化银彩色照相材料，其含有由使用具有8个或更多碳原子的链转移剂的通过聚合反应获得的聚合物成色剂组成的新的染料成像成色剂。 卤化银彩色照相材料具有高灵敏度和高的成色性。
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公开(公告)号：US20100255249A1
公开(公告)日：2010-10-07
申请号：US12680643
申请日：2008-09-19
申请人： Junichi Yamanouchi , Machiko Yamanouchi , Masaki Noro , Hidekazu Yamazaki , Hideaki Naruse , Shintaro Washizo , Koju Ito
发明人： Junichi Yamanouchi , Machiko Yamanouchi , Masaki Noro , Hidekazu Yamazaki , Hideaki Naruse , Shintaro Washizo , Koju Ito
CPC分类号： B29C41/28 , B29K2001/00 , B29K2001/12 , B29K2105/04 , B29L2031/608 , C08J5/18 , C08J2305/04 , Y10T428/24149 , Y10T428/249921
摘要： A surfactant is added to a polymer solution (21) which is a coating fluid comprising an organic solvent and a polymer. The surfactant contains a fluorine atom and reduces the surface tension of the coating fluid. The coating fluid (21) is applied to a casting band (26) as a support. Dew condensation is caused to occur on the surface of the polymer film (40) formed by coating fluid application. The organic solvent and droplets are vaporized to thereby cause droplets to come into the film and form voids. By the use of the polymer solution (21), which comprises a mixture of an organic solvent, a polymer, and a fluorine-atom-containing surfactant for surface tension reduction, a structure having such fine pores is formed and a film (12) of a honeycomb structure is obtained. This film is reduced in the adhesion of dust, etc. and has an even micropore structure
摘要翻译： 向作为包含有机溶剂和聚合物的涂布液的聚合物溶液（21）中加入表面活性剂。 表面活性剂含有氟原子并降低涂布液的表面张力。 将涂布液（21）作为支撑体施加到铸造带（26）。 在通过涂布液施加形成的聚合物膜（40）的表面上产生露水冷凝。 有机溶剂和液滴蒸发，从而使液滴进入膜并形成空隙。 通过使用包含有机溶剂，聚合物和含氟原子的表面活性剂的混合物进行表面张力降低的聚合物溶液（21），形成具有这种细孔的结构，并且将膜（12） 的蜂窝结构体。 该膜减少了灰尘附着等，并具有均匀的微孔结构
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公开(公告)号：US20060266463A1
公开(公告)日：2006-11-30
申请号：US11441121
申请日：2006-05-26
IPC分类号： B29C47/00
CPC分类号： C08J5/18 , B29C39/148 , B29C41/28 , B29C55/06 , B29C55/12 , Y10T428/249953
摘要： The object of the present invention is to provide a honeycomb composite film which contains a film having a honeycomb structure, and a provisional substrate formed on at least one surface of the film having the honeycomb structure such that the provisional substrate is exfoliatable and to provide a method for producing the honeycomb composite film which includes forming an exfoliation layer on a provisional substrate, and forming a film, the forming a film includes casting a solution containing an organic solvent and a high-polymer compound on any one of the exfoliation layer and a substrate, forming droplets in the obtained film, and vaporizing the organic solvent and the droplets to thereby produce a honeycomb-like porous film having holes in the film.
摘要翻译： 本发明的目的是提供一种蜂窝复合膜，其包含具有蜂窝结构的膜和在具有蜂窝结构的膜的至少一个表面上形成的临时基板，使得临时基板是可剥离的并且提供 蜂窝复合膜的制造方法，其特征在于，在临时基板上形成剥离层，形成膜，形成膜包括将剥离层和高分子化合物的溶液浸渍在剥离层和 底物，在所得膜中形成液滴，并蒸发有机溶剂和液滴，从而制得在膜中具有孔的蜂窝状多孔膜。
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57.发明授权公开(公告)号：US06670410B2
公开(公告)日：2003-12-30
申请号：US09862423
申请日：2001-05-23
IPC分类号： C09D1110
摘要： An ink for ink-jet recording which comprises a color composition prepared by dispersing, in a water-based medium, coloring particulates that contain an oil-soluble dye and a vinyl polymer which is obtained through copolymerization of a monomer represented by general formula (I) as follows: in which general formula (I): R11 represents a hydrogen atom, a chlorine atom, or the like; L1 represents —O—, —COO—, or the like; X1 represents —CH2—, —CHR13—, or the like; q is 2 or more if L1 is —COO—, and q is 1 or more in other cases; L2 represents —O—, —CO—, or the like; r is 0 or 1; X2 represents —CH2—, —CH2CHR13—, or the like; s is from 0 to 18; R12 and R15 each independently represents a hydrogen atom, or the like; and R13 and R14 each independently represents a substituted or unsubstituted alkyl group, or the like.
摘要翻译： 一种喷墨记录用油墨，其特征在于，包括通过在水性介质中分散含有油溶性染料和乙烯基聚合物的着色颗粒而制备的着色组合物，所述着色颗粒是通过通式（I ）如下：其中通式（I）：R 11表示氢原子，氯原子等; L 1表示-O-，-COO-等; X 1表示-CH 2 - ， - CHR 13 - 等; 如果L 1为-COO-，q为2或更大，在其它情况下q为1或更大; L 2表示-O-，-CO-等; r为0或1; X 2表示-CH 2 - ， - CH 2 CHR 13 - 等; s为0至18; R 12和R 15各自独立地表示氢原子等; R 13和R 14各自独立地表示取代或未取代的烷基等。
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公开(公告)号：US06329120B1
公开(公告)日：2001-12-11
申请号：US09572839
申请日：2000-05-16
IPC分类号： G03C173
CPC分类号： C08F246/00 , B41M5/267 , B41M5/30 , B41M5/36 , Y10S430/115 , Y10S430/145 , Y10S430/146
摘要： An image recording medium is disclosed which comprising: an acid generating agent capable of generating an acid by the action of heat or an acid, which is represented by the following formula (1); and a compound of causing variation in the absorption region of from 360 to 900 nm by the intramolecular or intermolecular reaction triggered by the action of an acid: W1OP (1) wherein W1 represents a residue of an acid represented by W1OH, and P represents an acid-sensitive substituent capable of splitting off at a temperature of 150° C. or less due to catalysis by W1OH.
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公开(公告)号：US6129980A
公开(公告)日：2000-10-10
申请号：US114139
申请日：1998-07-13
IPC分类号： G02B1/11
CPC分类号： G02B1/111 , Y10T428/254
摘要： An anti-reflection film has a low refractive index layer and a high refractive index layer. The low refractive index layer is formed by coating a composition comprising (a) a hydrolysis product or a partial condensation product of an organosilane and (c) a vinyl resin. The organosilane is represented by the formula of R.sup.1 Si(OR.sup.2).sub.3 in which R.sup.1 is an alkyl group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms or an aryl group having 6 to 10 carbon atoms, and R.sup.2 is an alkyl group having 1 to 5 carbon atoms or an acyl group having 1 to 4 carbon atoms. The vinyl resin has at least one silyl group substituted with a hydrolyzable group or hydroxyl.
摘要翻译： 抗反射膜具有低折射率层和高折射率层。 通过涂布包含（a）有机硅烷的水解产物或部分缩合产物和（c）乙烯基树脂的组合物来形成低折射率层。 有机硅烷由R1Si（OR2）3的化学式表示，其中R1是具有1-10个碳原子的烷基，具有2-10个碳原子的链烯基或具有6-10个碳原子的芳基，R2是 具有1至5个碳原子的烷基或具有1至4个碳原子的酰基。 乙烯基树脂具有至少一个被可水解基团或羟基取代的甲硅烷基基团。
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公开(公告)号：US6020118A
公开(公告)日：2000-02-01
申请号：US949615
申请日：1997-10-14
CPC分类号： G03C1/043 , G03C1/0051 , G03C5/17 , G03C1/09 , G03C1/16 , G03C1/832 , Y10S430/167
摘要： A silver halide photographic material has at least one photosensitive silver halide emulsion layer and at least one non-photosensitive hydrophilic colloid layer on a support. The silver coverage per surface is 1.0-2.2 g/m.sup.2. The silver halide emulsion layer contains silver halide grains wherein tabular silver halide grains having an aspect ratio of at least 5 account for at least 50% of the entire projected area of silver halide grains. The silver halide grains have been grown on pure silver bromide or silver chlorobromide grains as nuclei so as to form silver iodobromide or silver chloroiodobromide having a silver iodide content of 0.1-3.20 mol % at the end of growth. This X-ray photosensitive material having high sensitivity and sharpness is used with a regular screen.
摘要翻译： 卤化银照相材料在载体上具有至少一个感光卤化银乳剂层和至少一个非感光亲水胶体层。 每个表面的银覆盖率为1.0-2.2g / m 2。 卤化银乳剂层包含卤化银颗粒，其中具有至少5的纵横比的片状卤化银颗粒占卤化银颗粒的整个投影面积的至少50％。 卤化银颗粒已经在纯溴化银或氯溴化银颗粒上生长成核，从而在生长结束时形成碘碘化银或氯碘碘化银，其碘化银含量为0.1-3.20mol％。 具有高灵敏度和清晰度的这种X射线感光材料与常规屏幕一起使用。
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