-
公开(公告)号：US5681442A
公开(公告)日：1997-10-28
申请号：US565636
申请日：1995-11-29
申请人： Kazufumi Ogawa , Norihisa Mino
发明人： Kazufumi Ogawa , Norihisa Mino
CPC分类号： H01L51/0075 , H01L51/0094 , H01L51/0545 , H01L51/0036 , H01L51/0062 , Y10S428/901 , Y10T428/24917
摘要： A process for producing an organic device includes forming a first electrode and a second electrode on a substrate having an insulating film formed on a surface thereof, etching out the insulating film with the first electrode and the second electrode being used as masks, forming a monomolecular or built-up monomolecular film containing electrolytically polymerizable unsaturated groups directly or indirectly on the surface of the substrate by a chemical absorption method or the Langmuir-Blodgett method. The process further includes a procedure of spreading a surfactant containing the electrolytically polymerizable unsaturated groups on the surface of a water bath to form a monomolecular film, transferring at least one layer of the monomolecular film into the surface of the substrate, and chemically bonding molecules of the surfactant to form at least one layer of the monomolecular film of the surfactant containing electroconductive conjugated groups, applying a voltage between the first electrode and the second electrode to polymerize the electrolytically polymerizable unsaturated groups, and deriving a third electrode from the substrate such that the substrate acts as the third electrode.
摘要翻译： 一种制造有机器件的方法包括：在其表面上形成有绝缘膜的基板上形成第一电极和第二电极，用第一电极和第二电极作为掩模蚀刻绝缘膜，形成单分子 或通过化学吸收法或Langmuir-Blodgett法直接或间接地在基材表面上含有电解聚合性不饱和基团的单分子膜。 该方法还包括将含有电解可聚合不饱和基团的表面活性剂扩散到水浴表面以形成单分子膜，将至少一层单分子膜转移到基材表面的方法，以及化学键合 所述表面活性剂形成至少一层含有导电共轭基团的表面活性剂的单分子膜，在所述第一电极和所述第二电极之间施加电压以聚合所述电解聚合的不饱和基团，并从所述基板导出第三电极， 衬底作为第三电极。
-
公开(公告)号：US5578340A
公开(公告)日：1996-11-26
申请号：US485787
申请日：1995-06-07
申请人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
发明人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
CPC分类号： B82Y30/00 , A61L33/0088 , B05D1/185 , B82Y40/00 , B82Y5/00 , C09D4/00 , Y10S623/923
摘要： A medical member having active hydrogen groups such as hydroxyl, amino or imino groups at its surface, is dipped, either directly or after formation of an inner layer on its surface, into a solution. The solution is prepared by dissolving a surface active material, e.g., CF.sub.3 (CF.sub.2).sub.7 (CH.sub.2).sub.2 SiCl.sub.3 in a non-aqueous solvent. A dehydrochlorination reaction is brought about between active hydrogen groups at the surface of the member and SiCl groups of the surface active material, thus producing bonds ofCF.sub.3 (CF.sub.2).sub.7 (CH.sub.2).sub.2 Si(O--).sub.3over the entire surface. A fluorine-containing monomolecular film is formed, which is chemically (or covalently) bonded to the member surface and has a thickness at the nanometer level. Since the chemically adsorbed film is covalently bonded to the member or inner layer, it is chemically stable and difficult to separate. Medical members can be obtained when the invention is applied to an artificial tooth, a joint, a bone, a blood bag, a catheter, a blood transportation tool, a dialysis equipment part, an operation thread, a medical implant and an operation tool.
摘要翻译： 在其表面具有羟基，氨基或亚氨基的活性氢基团的医学成分在其表面上直接或内层形成后溶解成溶液。 通过将表面活性物质例如CF 3（CF 2）7（CH 2）2 ClCl 3溶解在非水溶剂中来制备溶液。 在成员表面的活性氢基团和表面活性材料的SiCl基团之间产生脱氯化氢反应，从而在整个表面上产生CF 3（CF 2）7（CH 2）2 Si（O-）3的键。 形成化学（或共价）结合到构件表面并具有纳米级厚度的含氟单分子膜。 由于化学吸附的膜共价结合到构件或内层，因此化学稳定且难以分离。 当将本发明应用于人造牙齿，关节，骨骼，血袋，导管，血液输送工具，透析设备部件，手术线，医疗植入物和操作工具时，可获得医疗部件。
-
公开(公告)号：US5571622A
公开(公告)日：1996-11-05
申请号：US309545
申请日：1994-09-20
申请人： Kazufumi Ogawa , Mamoru Soga
发明人： Kazufumi Ogawa , Mamoru Soga
CPC分类号： B82Y30/00 , A61N1/36514 , B05D1/185 , B82Y40/00 , C09D4/00 , D06M15/657 , D06M23/005 , B05D5/08 , Y10S428/913 , Y10T428/2918 , Y10T428/2933 , Y10T428/2962 , Y10T428/31663
摘要： A durable and extremely water- and oil repellent ultra thin film is formed on the surface of a substates such as glass, ceramics, fabrics, fur and cloth by a dehydrochlorination reaction between a functional group such as a hydroxyl group or an imino group on the surface of the substrate. The coating film of the material comprises a plurality of chlorosilyl groups was formed on the surface of the substrate by dipping and holding the substrate comprising functional groups on its surface in a solution prepared by dissolving a material comprising fluorocarbon groups and a plurality of chlorosily groups in a non-aqueous solvent and drying the substrate which is then taken out from the solution in a substantially moistureless or low moisture atmosphere and removing the non-aqueous solvent remaining on the substrate. Further, when the coating film is left in an atmosphere comprising moisture, i.e., humid air, the coating film is polymerized by a dehydrochlorination reaction between the coating film and the moisture in the atmosphere. The film is formed on the surface of the substrate containing hydroxyl groups, imino groups or carboxyl groups through --SiO-- bonds or --SiN
摘要翻译： 通过在诸如羟基或亚氨基之类的官能团之间的脱氯化氢反应，在玻璃，陶瓷，织物，毛皮和布等基底的表面上形成耐久且极其防水和防油的超薄膜 基板的表面。 该材料的涂膜包括通过将包含官能团的基材在其表面上浸渍并保持在通过将包含氟碳基团和多个氯基团的材料溶解在其中而制备的溶液中而在基材表面上形成多个氯甲硅烷基 非水溶剂并干燥基材，然后将其从基本上无水或低湿气氛中从溶液中取出并除去留在基材上的非水溶剂。 此外，当涂膜保持在包含湿气的空气即潮湿的空气中时，通过涂膜和大气中的水分之间的脱氯化氢反应使涂膜聚合。 该薄膜通过-SiO键或-SiN <键在含有羟基，亚氨基或羧基的基材表面上形成。
-
公开(公告)号：US5536982A
公开(公告)日：1996-07-16
申请号：US507667
申请日：1995-07-25
摘要： The invention concerns an ultra thin polymer film electret comprising a polymer and a substrate having a surface electric charge, wherein a side chain of the polymer and the substrate are physically or chemically bonded. A method of manufacturing an ultra thin polymer film electret comprising: adsorbing a monomolecular film comprising a unsaturated group or a laminated film comprising the monomolecular film on to a substrate surface, irradiating the monomolecular film or the laminated film with an energy beam to polymerize the unsaturated groups and applying a high voltage to the film is also disclosed. Further, a method of manufacturing an ultra thin polymer film electret comprising: physically bonding a side chain of the polymer to a substrate surface to form a thin film and applying a high voltage to the thin film is also disclosed.
摘要翻译： 本发明涉及一种包含聚合物和具有表面电荷的基底的超薄聚合物膜驻极体，其中聚合物和基底的侧链物理或化学键合。 一种制造超薄聚合物膜驻极体的方法，包括：将包含不饱和基团的单分子膜或包含单分子膜的层压膜吸附到基材表面上，用能量束照射单分子膜或层压膜以聚合不饱和 并且还公开了向薄膜施加高电压的组。 此外，还公开了一种制造超薄聚合物膜驻极体的方法，其包括：将聚合物的侧链物理结合到基板表面以形成薄膜并向薄膜施加高电压。
-
公开(公告)号：US5500250A
公开(公告)日：1996-03-19
申请号：US511912
申请日：1995-08-07
申请人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
发明人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
CPC分类号： B82Y30/00 , A61L33/0088 , B05D1/185 , B82Y40/00 , B82Y5/00 , C09D4/00 , Y10T428/31544 , Y10T428/31612 , Y10T428/31699
摘要： Disclosed is an ornament with a thin film formed on the ornament surface. The thin film includes a fluorocarbon-based adsorbed monomolecular film, and the thin film is covalently bonded to the ornament. By contacting the ornament with the non-aqueous solution containing a chlorosilane group at one end and a fluorocarbon chain at the other end, a reaction occurs between hydroxyl groups at the ornament surface and the chlorosilyl groups of the material having a plurality of chlorosilyl grounds. A monomolecular film which is covalently bonded to the ornament surface is thereby obtained. A thin, fluorine-containing, monomolecular film thus can be formed on the ornament such that it is, chemically bonded to the ornament. The film is anti-contaminating, water-and oil-repelling, durable and does not spoil the intrinsic luster of the ornament.
摘要翻译： 公开了一种在装饰表面上形成有薄膜的装饰品。 薄膜包括氟碳基吸附单分子膜，并且该薄膜与装饰物共价键合。 通过将装饰物与其一端含有氯硅烷基的非水溶液和另一端的碳氟化合物链接触，在装饰表面的羟基和具有多个氯代甲硅烷基的材料的氯甲硅烷基之间发生反应。 由此获得共价键合到装饰表面的单分子膜。 因此，可以在装饰品上形成薄的含氟单分子膜，使其与装饰物化学结合。 该胶片具有防污，防水，防油，耐用，不会破坏装饰品的内在光泽。
-
公开(公告)号：US5474839A
公开(公告)日：1995-12-12
申请号：US165569
申请日：1993-12-13
申请人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
发明人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
IPC分类号： B05D1/18 , D06M15/657 , D06M23/00 , B32B7/00
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , D06M15/657 , D06M23/005 , Y10T428/2962 , Y10T428/2964 , Y10T428/31663 , Y10T442/2172 , Y10T442/2762 , Y10T442/2861 , Y10T442/2885 , Y10T442/2893
摘要： According to the invention, a chemically adsorbed film is formed on an apparel material which has a surface layer containing fluorocarbon groups and a stem which is chemically bonded by --Si-- bonds to the material. A high performance apparel material thus can be provided which retains intrinsic properties of material such as ventilation and aesthetic appearance and is excellently durable and highly water- and oil-repelling and anti-contaminating or excellently durable and highly hydrophilic. The chemically adsorbed film has a very thin surface layer containing fluorocarbon groups, and is thus excellently water- and oil-repelling and anti-contaminating. In addition, since its stem is chemically bonded via --Si-- bonds to the material, it does not separate and is excellently durable. Further, it is very thin and does not adversely effect intrinsic properties of material such as ventilation, color and aesthetic appearance.
摘要翻译： 根据本发明，在具有含氟碳基团的表面层和通过-Si-键与材料化学键合的茎的衣服材料上形成化学吸附的膜。 因此可以提供高性能的服装材料，其保持诸如通风和美观外观的材料的固有特性，并且具有优异的耐久性和高度防水和防油和防污染或优异的耐用和高亲水性。 化学吸附膜具有非常薄的含有氟碳基团的表面层，因此具有极好的防水和防油和防污染性。 此外，由于其茎通过-Si-键与材料化学键合，因此它不分离并且非常耐用。 此外，它非常薄，并且不会不利地影响诸如通风，颜色和美学外观的材料的固有性质。
-
公开(公告)号：US5473933A
公开(公告)日：1995-12-12
申请号：US287590
申请日：1994-08-08
申请人： Mamoru Soga , Shinji Ozaki , Shigeo Ikuta , Kazufumi Ogawa
发明人： Mamoru Soga , Shinji Ozaki , Shigeo Ikuta , Kazufumi Ogawa
CPC分类号： B82Y30/00 , B82Y15/00 , G01N27/121
摘要： A humidity sensor with an excellent water-repelling property is presented by covalently bonding a monomolecular film containing fluoroalkyl groups to the surface of a humidity sensing element, used for the sensor, via siloxane bonding. A chemically adsorbed monomolecular film containing fluoroalkyl groups is formed on the surface of a humidity sensing element via siloxane bonding after dipping and holding the element in a surface active solution such as heptadecafluorotridecyl trichlorosilane, and removing the unreacted material.
摘要翻译： 通过硅氧烷键合将含有氟代烷基的单分子膜通过硅氧烷键合共价结合到用于传感器的湿度感测元件的表面，提供了具有优异的防水性能的湿度传感器。 浸渍并将元件保持在表面活性剂如十九氟三癸基三氯硅烷中后，通过硅氧烷键合在湿度感测元件的表面上形成含氟烷基的化学吸附单分子膜，并除去未反应的物质。
-
公开(公告)号：US5466486A
公开(公告)日：1995-11-14
申请号：US316105
申请日：1994-09-30
申请人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
发明人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
IPC分类号： B05D1/18 , C08J7/04 , C09D4/00 , C09D183/08 , B05D3/02
CPC分类号： C04B41/52 , B05D1/185 , B82Y30/00 , B82Y40/00 , B82Y5/00 , C04B41/009 , C04B41/89 , C08J7/047 , C09D183/08 , C09D4/00 , C04B2111/00965 , C08J2483/00 , Y10T428/261 , Y10T428/31612 , Y10T428/31663 , Y10T428/31667
摘要： The invention to provide a chemically adsorbed monomolecular lamination film comprising a chemically adsorbed monomolecular film formed via a siloxane-based monomolecular or polymer film on a substrate surface. It also seeks to provide a method of forming a chemically adsorbed monomolecular film efficiently and with high density on a substrate surface with few hydroxyl groups, which method comprises a step of contacting a substrate containing hydroxyl groups present on the surface with a non-aqueous solution containing a material with plural chlorosilanol groups in molecule, a step of removing the material remaining on the substrate without reaction by washing the substrate with a non-aqueous organic solution (if this process is omitted, the siloxane-based polymer film is prepared on the substrate), a step of forming a monomolecular film constituted by a compound containing a silanol group in molecule on the substrate by exposing to the air containing moisture or washing with water, after the removal step, and a step of laminating a monomolecular adsorption film by adsorbing a chlorosilane-based surface active agent constituted by a straight hydrocarbon chain having a chlorosilane groups at one end onto the substrate after the monomolecular or polymer film formation step.
摘要翻译： 本发明提供一种化学吸附的单分子层叠膜，其包含在基材表面上通过基于硅氧烷的单分子或聚合物膜形成的化学吸附的单分子膜。 它还寻求提供一种在几乎没有羟基的基材表面上有效且高密度地形成化学吸附的单分子膜的方法，该方法包括使含有表面上存在的羟基的基材与非水溶液接触的步骤 含有分子中具有多个氯硅烷醇基团的材料，通过用非水有机溶液洗涤基材而除去残留在基材上的材料而不反应的步骤（如果省略该方法，则将硅氧烷基聚合物膜制备在 底物），在除去步骤之后，通过暴露于含有水分的空气或用水洗涤的方式，在基板上分子形成由分子中含有硅烷醇基的化合物构成的单分子膜的步骤，以及将单分子吸附膜层叠 吸附由o具有氯硅烷基的直链烃链构成的氯硅烷系表面活性剂 在单分子或聚合物膜形成步骤之后结束到基底上。
-
公开(公告)号：US5324543A
公开(公告)日：1994-06-28
申请号：US20534
申请日：1993-02-22
申请人： Kazufumi Ogawa , Tadashi Ootake , Mamoru Soga
发明人： Kazufumi Ogawa , Tadashi Ootake , Mamoru Soga
IPC分类号： B05D1/20 , B05D1/18 , B32B7/02 , B32B9/00 , C08J7/04 , C09D4/00 , C09K3/00 , C09K3/18 , B05D5/08
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , B82Y5/00 , C09D4/00 , Y10T428/261 , Y10T428/3154 , Y10T428/31663
摘要： The invention provides a method of forming a monomolecular film of fluorine-containing molecules on a substrate surface such that the film has a uniform thickness with minimal surface irregularities and is substantially pin hole free. The invention also provides for a substrate obtained by using the same method which has excellent water- and oil-repelling, anti-fogging, and anti-contaminating properties. The monomolecular film is formed on the substrate surface either directly or via a given protective film. The monomolecular film coating is characterized by a plurality of different chlorosilane-based surface active materials which are different in molecular length and have a fluorine group. The surface irregularities of the film are generally confined to the molecular level.
摘要翻译： 本发明提供了在基板表面上形成含氟分子的单分子膜的方法，使得该膜具有均匀的厚度，具有最小的表面不规则性并且基本上无针孔。 本发明还提供了通过使用具有优异的防水和防油，防雾和抗污染性能的相同方法获得的基材。 单分子膜直接或通过给定的保护膜形成在基板表面上。 单分子膜涂层的特征在于分子长度不同且具有氟基团的多种不同的氯硅烷系表面活性物质。 膜的表面不规则性通常限于分子水平。
-
公开(公告)号：US5302416A
公开(公告)日：1994-04-12
申请号：US807636
申请日：1991-12-13
申请人： Kazufumi Ogawa
发明人： Kazufumi Ogawa
CPC分类号： B82Y30/00 , B05D1/185 , B05D1/202 , B82Y10/00 , B82Y20/00 , B82Y40/00 , G02F1/3618 , H01B1/125
摘要： This invention relates to production of a super long conjugated polymer to be used for a molecular device, etc. According to this invention, an acetylene derivative is previously oriented and formed into a monomolecular film on the surface of a substrate and its acetylenic group is polymerized by a catalyst or by irradiation of an energy beam while keeping the orientation. Since the respective molecules are oriented and aligned on the substrate surface, the polymerization reaction readily proceeds, and after the polymerization the resulting polyacetylene molecules are prevented from the breakage of conjugated bonds caused by thermal agitation or twisting of the polyacetylene molecules. Accordingly, a polyacetylene or polyacene type polymer having long conjugated bonds can be obtained easily.
-
-
-
-
-
-
-
-
-
搜索结果
262 条记录 (耗时 0.027 秒)
